Effect of Mineral-Generated Lithium Slag on the Properties of Magnesium Oxychloride Cement

A large amount of mineral-generated lithium slag will be produced after extracting lithium from spodumene. However, most lithium slag has not been well utilized. In this study, lithium slag was added to MOC, and its setting time, compressive strength, water resistance, phase composition, and microsc...

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Main Authors: Shitong Li, Siru Liu, Yongsheng Du, Qing Huang, Wenhui Qu, Weixin Zheng
Format: Article
Language:English
Published: MDPI AG 2023-03-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/13/3/513
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author Shitong Li
Siru Liu
Yongsheng Du
Qing Huang
Wenhui Qu
Weixin Zheng
author_facet Shitong Li
Siru Liu
Yongsheng Du
Qing Huang
Wenhui Qu
Weixin Zheng
author_sort Shitong Li
collection DOAJ
description A large amount of mineral-generated lithium slag will be produced after extracting lithium from spodumene. However, most lithium slag has not been well utilized. In this study, lithium slag was added to MOC, and its setting time, compressive strength, water resistance, phase composition, and microscopic morphology were studied. The results showed that although lithium slag prolonged the setting time and reduced the compressive strength of MOC, its water resistance improved. When the content of lithium slag was 20 wt%, the softening coefficient of the specimen reached a maximum value, and the softening coefficients at 3, 7, and 14 days were 1.47, 1.91, and 1.51 times that of MOC without lithium slag, respectively. A microscopic morphology analysis showed that the lithium slag transformed the MOC crystals from needle-like to column-like or block-like, the crystallization range expanded, and the binding force weakened. Magnesium oxychloride cement with excellent mechanical properties and good workability was combined with magnesium slag in this paper to provide the basis for the application of magnesium slag in building materials.
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spelling doaj.art-55fd3f8aa68343fea69d21dfa719dae62023-11-17T10:29:49ZengMDPI AGCrystals2073-43522023-03-0113351310.3390/cryst13030513Effect of Mineral-Generated Lithium Slag on the Properties of Magnesium Oxychloride CementShitong Li0Siru Liu1Yongsheng Du2Qing Huang3Wenhui Qu4Weixin Zheng5School of Materials Science and Engineering, Shaanxi University of Technology, Hanzhong 723000, ChinaSchool of Materials Science and Engineering, Shaanxi University of Technology, Hanzhong 723000, ChinaKey Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, ChinaSchool of Materials Science and Engineering, Shaanxi University of Technology, Hanzhong 723000, ChinaSchool of Materials Science and Engineering, Shaanxi University of Technology, Hanzhong 723000, ChinaKey Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, ChinaA large amount of mineral-generated lithium slag will be produced after extracting lithium from spodumene. However, most lithium slag has not been well utilized. In this study, lithium slag was added to MOC, and its setting time, compressive strength, water resistance, phase composition, and microscopic morphology were studied. The results showed that although lithium slag prolonged the setting time and reduced the compressive strength of MOC, its water resistance improved. When the content of lithium slag was 20 wt%, the softening coefficient of the specimen reached a maximum value, and the softening coefficients at 3, 7, and 14 days were 1.47, 1.91, and 1.51 times that of MOC without lithium slag, respectively. A microscopic morphology analysis showed that the lithium slag transformed the MOC crystals from needle-like to column-like or block-like, the crystallization range expanded, and the binding force weakened. Magnesium oxychloride cement with excellent mechanical properties and good workability was combined with magnesium slag in this paper to provide the basis for the application of magnesium slag in building materials.https://www.mdpi.com/2073-4352/13/3/513magnesium oxychloride cementlithium slagsetting timecompressive strengthwater resistance
spellingShingle Shitong Li
Siru Liu
Yongsheng Du
Qing Huang
Wenhui Qu
Weixin Zheng
Effect of Mineral-Generated Lithium Slag on the Properties of Magnesium Oxychloride Cement
Crystals
magnesium oxychloride cement
lithium slag
setting time
compressive strength
water resistance
title Effect of Mineral-Generated Lithium Slag on the Properties of Magnesium Oxychloride Cement
title_full Effect of Mineral-Generated Lithium Slag on the Properties of Magnesium Oxychloride Cement
title_fullStr Effect of Mineral-Generated Lithium Slag on the Properties of Magnesium Oxychloride Cement
title_full_unstemmed Effect of Mineral-Generated Lithium Slag on the Properties of Magnesium Oxychloride Cement
title_short Effect of Mineral-Generated Lithium Slag on the Properties of Magnesium Oxychloride Cement
title_sort effect of mineral generated lithium slag on the properties of magnesium oxychloride cement
topic magnesium oxychloride cement
lithium slag
setting time
compressive strength
water resistance
url https://www.mdpi.com/2073-4352/13/3/513
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