Chlorido-pentamethylcyclopentadienyl-[2-(2-pyridyl-к<i>N</i>)-ferrocenyl-к<i>C</i>]-iridium(III)
Treatment of 2-pyridyl-ferrocene wit [Cp*IrCl<sub>2</sub>]<sub>2</sub> in the presence of NaOAc produces the title compound Cp*ClIr[(C<sub>5</sub>H<sub>3</sub>C<sub>5</sub>H<sub>4</sub>N-кN,кC)Fe(C<sub>5</sub>H<su...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
MDPI AG
2024-02-01
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Series: | Molbank |
Subjects: | |
Online Access: | https://www.mdpi.com/1422-8599/2024/1/M1770 |
Summary: | Treatment of 2-pyridyl-ferrocene wit [Cp*IrCl<sub>2</sub>]<sub>2</sub> in the presence of NaOAc produces the title compound Cp*ClIr[(C<sub>5</sub>H<sub>3</sub>C<sub>5</sub>H<sub>4</sub>N-кN,кC)Fe(C<sub>5</sub>H<sub>5</sub>)] (<b>2</b>) in low yield. A crystal structure determination shows the (<i>S<sub>p</sub>S<sub>Ir</sub></i>/<i>R<sub>p</sub>R<sub>Ir</sub></i>)-<b>2</b> enantiomeric pair of diastereomers. |
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ISSN: | 1422-8599 |