Chlorido-pentamethylcyclopentadienyl-[2-(2-pyridyl-к<i>N</i>)-ferrocenyl-к<i>C</i>]-iridium(III)
Treatment of 2-pyridyl-ferrocene wit [Cp*IrCl<sub>2</sub>]<sub>2</sub> in the presence of NaOAc produces the title compound Cp*ClIr[(C<sub>5</sub>H<sub>3</sub>C<sub>5</sub>H<sub>4</sub>N-кN,кC)Fe(C<sub>5</sub>H<su...
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| Format: | Article |
| Language: | English |
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MDPI AG
2024-02-01
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| Series: | Molbank |
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| Online Access: | https://www.mdpi.com/1422-8599/2024/1/M1770 |
| _version_ | 1797239923276775424 |
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| author | Stefan Weigand Karlheinz Sünkel |
| author_facet | Stefan Weigand Karlheinz Sünkel |
| author_sort | Stefan Weigand |
| collection | DOAJ |
| description | Treatment of 2-pyridyl-ferrocene wit [Cp*IrCl<sub>2</sub>]<sub>2</sub> in the presence of NaOAc produces the title compound Cp*ClIr[(C<sub>5</sub>H<sub>3</sub>C<sub>5</sub>H<sub>4</sub>N-кN,кC)Fe(C<sub>5</sub>H<sub>5</sub>)] (<b>2</b>) in low yield. A crystal structure determination shows the (<i>S<sub>p</sub>S<sub>Ir</sub></i>/<i>R<sub>p</sub>R<sub>Ir</sub></i>)-<b>2</b> enantiomeric pair of diastereomers. |
| first_indexed | 2024-04-24T17:59:15Z |
| format | Article |
| id | doaj.art-561a95e973694fd88d22f185cbe1b933 |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-04-24T17:59:15Z |
| publishDate | 2024-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-561a95e973694fd88d22f185cbe1b9332024-03-27T13:56:36ZengMDPI AGMolbank1422-85992024-02-0120241M177010.3390/M1770Chlorido-pentamethylcyclopentadienyl-[2-(2-pyridyl-к<i>N</i>)-ferrocenyl-к<i>C</i>]-iridium(III)Stefan Weigand0Karlheinz Sünkel1Department of Chemistry, Ludwig-Maximilians-University Munich, Butenandtstr. 5-13, 81377 Munich, GermanyDepartment of Chemistry, Ludwig-Maximilians-University Munich, Butenandtstr. 5-13, 81377 Munich, GermanyTreatment of 2-pyridyl-ferrocene wit [Cp*IrCl<sub>2</sub>]<sub>2</sub> in the presence of NaOAc produces the title compound Cp*ClIr[(C<sub>5</sub>H<sub>3</sub>C<sub>5</sub>H<sub>4</sub>N-кN,кC)Fe(C<sub>5</sub>H<sub>5</sub>)] (<b>2</b>) in low yield. A crystal structure determination shows the (<i>S<sub>p</sub>S<sub>Ir</sub></i>/<i>R<sub>p</sub>R<sub>Ir</sub></i>)-<b>2</b> enantiomeric pair of diastereomers.https://www.mdpi.com/1422-8599/2024/1/M17702-pyridylmetallocenesiridium half-sandwich complexescyclometallationcrystal structure determination |
| spellingShingle | Stefan Weigand Karlheinz Sünkel Chlorido-pentamethylcyclopentadienyl-[2-(2-pyridyl-к<i>N</i>)-ferrocenyl-к<i>C</i>]-iridium(III) Molbank 2-pyridylmetallocenes iridium half-sandwich complexes cyclometallation crystal structure determination |
| title | Chlorido-pentamethylcyclopentadienyl-[2-(2-pyridyl-к<i>N</i>)-ferrocenyl-к<i>C</i>]-iridium(III) |
| title_full | Chlorido-pentamethylcyclopentadienyl-[2-(2-pyridyl-к<i>N</i>)-ferrocenyl-к<i>C</i>]-iridium(III) |
| title_fullStr | Chlorido-pentamethylcyclopentadienyl-[2-(2-pyridyl-к<i>N</i>)-ferrocenyl-к<i>C</i>]-iridium(III) |
| title_full_unstemmed | Chlorido-pentamethylcyclopentadienyl-[2-(2-pyridyl-к<i>N</i>)-ferrocenyl-к<i>C</i>]-iridium(III) |
| title_short | Chlorido-pentamethylcyclopentadienyl-[2-(2-pyridyl-к<i>N</i>)-ferrocenyl-к<i>C</i>]-iridium(III) |
| title_sort | chlorido pentamethylcyclopentadienyl 2 2 pyridyl к i n i ferrocenyl к i c i iridium iii |
| topic | 2-pyridylmetallocenes iridium half-sandwich complexes cyclometallation crystal structure determination |
| url | https://www.mdpi.com/1422-8599/2024/1/M1770 |
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