Tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-κ2O,O′)molybdenum(III)
In the title compound, [Mo(C5HF6O2)3], the unit cell is built up by three independent MoIII atoms located on two different threefold axes. The three independent molecules are roughly identical and each MoIII atom is surrounded by three chelating hexafluoroacetonate ligands in a three-bladed propelle...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810005489 |
| _version_ | 1819105982006951936 |
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| author | Jean-Claude Daran Rinaldo Poli Yohan Champouret |
| author_facet | Jean-Claude Daran Rinaldo Poli Yohan Champouret |
| author_sort | Jean-Claude Daran |
| collection | DOAJ |
| description | In the title compound, [Mo(C5HF6O2)3], the unit cell is built up by three independent MoIII atoms located on two different threefold axes. The three independent molecules are roughly identical and each MoIII atom is surrounded by three chelating hexafluoroacetonate ligands in a three-bladed propeller-like arrangement, as observed in related compounds with acetylacetonate-type ligands. The structure of the title compound is very similar to the trigonal form of the CrIII analogue. However, the latter crystallizes in a higher-symmetry space group, Poverline{3}c1. Both crystals are twinned by merohedry with the same twin law (overline1overline10/010/00overline1) in reciprocal space, but the symmetry of the Laue group in which it operates is different, overline{3} to overline{3}m for the title complex, and overline{3}m to 6/mmm for the CrIII complex. |
| first_indexed | 2024-12-22T02:30:53Z |
| format | Article |
| id | doaj.art-5648b32284fd4d579bfab482e3760258 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:30:53Z |
| publishDate | 2010-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-5648b32284fd4d579bfab482e37602582022-12-21T18:41:53ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-03-01663m299m30010.1107/S1600536810005489Tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-κ2O,O′)molybdenum(III)Jean-Claude DaranRinaldo PoliYohan ChampouretIn the title compound, [Mo(C5HF6O2)3], the unit cell is built up by three independent MoIII atoms located on two different threefold axes. The three independent molecules are roughly identical and each MoIII atom is surrounded by three chelating hexafluoroacetonate ligands in a three-bladed propeller-like arrangement, as observed in related compounds with acetylacetonate-type ligands. The structure of the title compound is very similar to the trigonal form of the CrIII analogue. However, the latter crystallizes in a higher-symmetry space group, Poverline{3}c1. Both crystals are twinned by merohedry with the same twin law (overline1overline10/010/00overline1) in reciprocal space, but the symmetry of the Laue group in which it operates is different, overline{3} to overline{3}m for the title complex, and overline{3}m to 6/mmm for the CrIII complex.http://scripts.iucr.org/cgi-bin/paper?S1600536810005489 |
| spellingShingle | Jean-Claude Daran Rinaldo Poli Yohan Champouret Tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-κ2O,O′)molybdenum(III) Acta Crystallographica Section E |
| title | Tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-κ2O,O′)molybdenum(III) |
| title_full | Tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-κ2O,O′)molybdenum(III) |
| title_fullStr | Tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-κ2O,O′)molybdenum(III) |
| title_full_unstemmed | Tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-κ2O,O′)molybdenum(III) |
| title_short | Tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-κ2O,O′)molybdenum(III) |
| title_sort | tris 1 1 1 5 5 5 hexafluoro 2 4 pentanedionato amp 954 2o o amp 8242 molybdenum iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810005489 |
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