Robust singlet fission in pentacene thin films with tuned charge transfer interactions

Singlet fission is desirable for highly efficient solar cells, yet the details of the process remain elusive. Here, Broch et al. show that the changes in bulk intermolecular interactions can have little effect on the singlet fission rate in a mixture of pentacene and weakly interacting spacer molecu...

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Main Authors: K. Broch, J. Dieterle, F. Branchi, N. J. Hestand, Y. Olivier, H. Tamura, C. Cruz, V. M. Nichols, A. Hinderhofer, D. Beljonne, F. C. Spano, G. Cerullo, C. J. Bardeen, F. Schreiber
Format: Article
Language:English
Published: Nature Portfolio 2018-03-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-018-03300-1
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author K. Broch
J. Dieterle
F. Branchi
N. J. Hestand
Y. Olivier
H. Tamura
C. Cruz
V. M. Nichols
A. Hinderhofer
D. Beljonne
F. C. Spano
G. Cerullo
C. J. Bardeen
F. Schreiber
author_facet K. Broch
J. Dieterle
F. Branchi
N. J. Hestand
Y. Olivier
H. Tamura
C. Cruz
V. M. Nichols
A. Hinderhofer
D. Beljonne
F. C. Spano
G. Cerullo
C. J. Bardeen
F. Schreiber
author_sort K. Broch
collection DOAJ
description Singlet fission is desirable for highly efficient solar cells, yet the details of the process remain elusive. Here, Broch et al. show that the changes in bulk intermolecular interactions can have little effect on the singlet fission rate in a mixture of pentacene and weakly interacting spacer molecules.
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spelling doaj.art-564e7a2454844890bae049854021d3392022-12-21T18:03:37ZengNature PortfolioNature Communications2041-17232018-03-01911910.1038/s41467-018-03300-1Robust singlet fission in pentacene thin films with tuned charge transfer interactionsK. Broch0J. Dieterle1F. Branchi2N. J. Hestand3Y. Olivier4H. Tamura5C. Cruz6V. M. Nichols7A. Hinderhofer8D. Beljonne9F. C. Spano10G. Cerullo11C. J. Bardeen12F. Schreiber13Institute of Applied Physics and Center for Light Matter Interactions, Sensors and Analytics, LISA+, University of TübingenInstitute of Applied Physics and Center for Light Matter Interactions, Sensors and Analytics, LISA+, University of TübingenIFN-CNR, Dipartimento di Fisica, Politecnico di MilanoDepartment of Chemistry, Temple UniversityLaboratory for Chemistry of Novel Materials, University of MonsDepartment of Chemical System Engineering, The University of TokyoDepartment of Chemistry, University of California at RiversideDepartment of Chemistry, University of California at RiversideInstitute of Applied Physics and Center for Light Matter Interactions, Sensors and Analytics, LISA+, University of TübingenLaboratory for Chemistry of Novel Materials, University of MonsDepartment of Chemistry, Temple UniversityIFN-CNR, Dipartimento di Fisica, Politecnico di MilanoDepartment of Chemistry, University of California at RiversideInstitute of Applied Physics and Center for Light Matter Interactions, Sensors and Analytics, LISA+, University of TübingenSinglet fission is desirable for highly efficient solar cells, yet the details of the process remain elusive. Here, Broch et al. show that the changes in bulk intermolecular interactions can have little effect on the singlet fission rate in a mixture of pentacene and weakly interacting spacer molecules.https://doi.org/10.1038/s41467-018-03300-1
spellingShingle K. Broch
J. Dieterle
F. Branchi
N. J. Hestand
Y. Olivier
H. Tamura
C. Cruz
V. M. Nichols
A. Hinderhofer
D. Beljonne
F. C. Spano
G. Cerullo
C. J. Bardeen
F. Schreiber
Robust singlet fission in pentacene thin films with tuned charge transfer interactions
Nature Communications
title Robust singlet fission in pentacene thin films with tuned charge transfer interactions
title_full Robust singlet fission in pentacene thin films with tuned charge transfer interactions
title_fullStr Robust singlet fission in pentacene thin films with tuned charge transfer interactions
title_full_unstemmed Robust singlet fission in pentacene thin films with tuned charge transfer interactions
title_short Robust singlet fission in pentacene thin films with tuned charge transfer interactions
title_sort robust singlet fission in pentacene thin films with tuned charge transfer interactions
url https://doi.org/10.1038/s41467-018-03300-1
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