The influence of the diacetylenic group on the properties of three-dimensional polymers
This paper describes the synthesis and the study of oligomers of bis(methacryloyl-oxy-1-hexamethylene-6-oxy)- ortho-phthaloyl (MHM-o-Ph) and its analog bis(methacryloyl-oxy-1-hexa-2,4-diyn-6-oxy)-ortho-phthaloyl (MHD-oPh) containing conjugated triple bonds in the oligomeric block. Besides the proper...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | Russian |
| Published: |
MIREA - Russian Technological University
2014-10-01
|
| Series: | Тонкие химические технологии |
| Subjects: | |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/442 |
| Summary: | This paper describes the synthesis and the study of oligomers of bis(methacryloyl-oxy-1-hexamethylene-6-oxy)- ortho-phthaloyl (MHM-o-Ph) and its analog bis(methacryloyl-oxy-1-hexa-2,4-diyn-6-oxy)-ortho-phthaloyl (MHD-oPh) containing conjugated triple bonds in the oligomeric block. Besides the properties of polymers based on these oligomers were investigated. The polymerization of MHD-o-Ph conditions the formation of a bi-three-dimensional polymer, the skeleton of which contains a three-dimensional network of polymethacrylate macrochains and a network with a system of conjugated bonds. This system significantly affects the complex of the polymeric properties. |
|---|---|
| ISSN: | 2410-6593 2686-7575 |