| Summary: | Subclasses of analytic and bi-univalent functions have been extensively improved and utilized for estimating the Taylor–Maclaurin coefficients and the Fekete–Szegö functional. In this paper, we consider a certain subclass of normalized analytic and bi-univalent functions. These functions have inverses that possess a bi-univalent analytic continuation to an open unit disk and are associated with orthogonal polynomials; namely, Gegenbauer polynomials that satisfy subordination conditions on the open unit disk. We use this subclass to derive new approximations for the second and third Taylor–Maclaurin coefficients and the Fekete–Szegö functional. Furthermore, we discuss several new results that arise when we specialize the parameters used in our fundamental findings.
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