The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)2P(=N-t-Bu)—C(=CH2)CH(p-CH3O—C6H4)-P(O)[(OCH2C(CH3)2CH2O)]}
The title compound, 2-{2-[1,3-di-tert-butyl-4-(tert-butylamino)-2-(tert-butylimino)-1,3,2λ5,4-diazadiphosphetidin-2-yl]-1-(4-methoxyphenyl)prop-2-en-1-yl}-5,5-dimethyl-1,3,2λ5-dioxaphosphinan-2-one, C31H57N4O4P3, was synthesized from the Phospha–Michael additi...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811014127 |
| _version_ | 1798018599689912320 |
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| author | G. Gangadhararao Srinivas Venu |
| author_facet | G. Gangadhararao Srinivas Venu |
| author_sort | G. Gangadhararao |
| collection | DOAJ |
| description | The title compound, 2-{2-[1,3-di-tert-butyl-4-(tert-butylamino)-2-(tert-butylimino)-1,3,2λ5,4-diazadiphosphetidin-2-yl]-1-(4-methoxyphenyl)prop-2-en-1-yl}-5,5-dimethyl-1,3,2λ5-dioxaphosphinan-2-one, C31H57N4O4P3, was synthesized from the Phospha–Michael addition reaction of cyclodiphosphazane [(t-BuNH)P(μ-Nt-Bu)]2 and allenylphosphonate [(OCH2C(CH3)2CH2O)P(O)C(p-CH3O—C6H4)=C=CH2]. In the crystal, N—H...O and C—H...O hydrogen bonds link the molecules. The structure exhibits pseudosymmetry but attempts to solve it in a higher (monoclinic) space group were unsuccessful. |
| first_indexed | 2024-04-11T16:25:34Z |
| format | Article |
| id | doaj.art-56a586dfcd73427aa5b1820cf24bda24 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:25:34Z |
| publishDate | 2011-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-56a586dfcd73427aa5b1820cf24bda242022-12-22T04:14:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-05-01675o1212o121310.1107/S1600536811014127The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)2P(=N-t-Bu)—C(=CH2)CH(p-CH3O—C6H4)-P(O)[(OCH2C(CH3)2CH2O)]}G. GangadhararaoSrinivas VenuThe title compound, 2-{2-[1,3-di-tert-butyl-4-(tert-butylamino)-2-(tert-butylimino)-1,3,2λ5,4-diazadiphosphetidin-2-yl]-1-(4-methoxyphenyl)prop-2-en-1-yl}-5,5-dimethyl-1,3,2λ5-dioxaphosphinan-2-one, C31H57N4O4P3, was synthesized from the Phospha–Michael addition reaction of cyclodiphosphazane [(t-BuNH)P(μ-Nt-Bu)]2 and allenylphosphonate [(OCH2C(CH3)2CH2O)P(O)C(p-CH3O—C6H4)=C=CH2]. In the crystal, N—H...O and C—H...O hydrogen bonds link the molecules. The structure exhibits pseudosymmetry but attempts to solve it in a higher (monoclinic) space group were unsuccessful.http://scripts.iucr.org/cgi-bin/paper?S1600536811014127 |
| spellingShingle | G. Gangadhararao Srinivas Venu The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)2P(=N-t-Bu)—C(=CH2)CH(p-CH3O—C6H4)-P(O)[(OCH2C(CH3)2CH2O)]} Acta Crystallographica Section E |
| title | The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)2P(=N-t-Bu)—C(=CH2)CH(p-CH3O—C6H4)-P(O)[(OCH2C(CH3)2CH2O)]} |
| title_full | The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)2P(=N-t-Bu)—C(=CH2)CH(p-CH3O—C6H4)-P(O)[(OCH2C(CH3)2CH2O)]} |
| title_fullStr | The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)2P(=N-t-Bu)—C(=CH2)CH(p-CH3O—C6H4)-P(O)[(OCH2C(CH3)2CH2O)]} |
| title_full_unstemmed | The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)2P(=N-t-Bu)—C(=CH2)CH(p-CH3O—C6H4)-P(O)[(OCH2C(CH3)2CH2O)]} |
| title_short | The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)2P(=N-t-Bu)—C(=CH2)CH(p-CH3O—C6H4)-P(O)[(OCH2C(CH3)2CH2O)]} |
| title_sort | phospha amp 8211 michael addition product t bunh p amp 956 n t bu 2p n t bu amp 8212 c ch2 ch p ch3o amp 8212 c6h4 p o och2c ch3 2ch2o |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811014127 |
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