Phase relations in the Si–Sn–As system
The goal of this work was to study phase relations in the ternary Si–Sn–As system: to establish cross sections, to construct a scheme of phase equilibria, and to identify the temperature of non-variant transformations. Ternary alloys were obtained through direct synthesis from simple substanc...
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| Format: | Article |
| Language: | English |
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Voronezh State University
2023-06-01
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| Series: | Конденсированные среды и межфазные границы |
| Subjects: | |
| Online Access: | https://journals.vsu.ru/kcmf/article/view/11110 |
| _version_ | 1797754716954820608 |
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| author | Tatiana P. Sushkova Galina V. Semenova Elena Yu. Proskurina |
| author_facet | Tatiana P. Sushkova Galina V. Semenova Elena Yu. Proskurina |
| author_sort | Tatiana P. Sushkova |
| collection | DOAJ |
| description | The goal of this work was to study phase relations in the ternary Si–Sn–As system: to establish cross sections, to construct a scheme of phase equilibria, and to identify the temperature of non-variant transformations.
Ternary alloys were obtained through direct synthesis from simple substances and subjected to long-term solid-phase annealing. Alloys of four polythermal sections of the Si–Sn–As system were examined using X-ray phase and differential thermal analysis. The results of X-ray powder diffraction allowed establishing that the phase subsolidus demarcations was performed by the SnAs–SiAs2, SnAs–SiAs, Sn4As3–SiAs, and Sn4As3–Si sections.
As a result of the experiment, taking into account the theoretical analysis, we suggested a scheme of phase equilibria in the system that involved the implementation of eutectic and four peritectic invariant equilibria, and we used differential thermal analysis to determine the temperature of these four-phase transformations.
It was found that extended solid solutions were not formed in the system, and only a substitutional solid solution at least 3 mol % wide was formed based along the SnAs–SiAs2 section based on tin monoarsenide |
| first_indexed | 2024-03-12T17:36:38Z |
| format | Article |
| id | doaj.art-56c7c22cd32c42dea728e96af475067f |
| institution | Directory Open Access Journal |
| issn | 1606-867X |
| language | English |
| last_indexed | 2024-03-12T17:36:38Z |
| publishDate | 2023-06-01 |
| publisher | Voronezh State University |
| record_format | Article |
| series | Конденсированные среды и межфазные границы |
| spelling | doaj.art-56c7c22cd32c42dea728e96af475067f2023-08-04T09:56:39ZengVoronezh State UniversityКонденсированные среды и межфазные границы1606-867X2023-06-0125210.17308/kcmf.2023.25/11110Phase relations in the Si–Sn–As systemTatiana P. Sushkova0https://orcid.org/0000-0003-1969-7082Galina V. Semenova1https://orcid.org/0000-0003-3877-985XElena Yu. Proskurina2https://orcid.org/0000-0002-6149-1398 Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation Cand. Sci. (Chem.), Associate Professor, Department of General and Inorganic Chemistry, Voronezh State University (Voronezh, Russian Federation).Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation Dr. Sc. (Chem.), Full Professor, Department of General and Inorganic Chemistry, Voronezh State University (Voronezh, Russian Federation).Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation Cand. Sci. (Chem.), Assistant Lecturer, Department of General and Inorganic Chemistry, Voronezh State University (Voronezh, Russian Federation). The goal of this work was to study phase relations in the ternary Si–Sn–As system: to establish cross sections, to construct a scheme of phase equilibria, and to identify the temperature of non-variant transformations. Ternary alloys were obtained through direct synthesis from simple substances and subjected to long-term solid-phase annealing. Alloys of four polythermal sections of the Si–Sn–As system were examined using X-ray phase and differential thermal analysis. The results of X-ray powder diffraction allowed establishing that the phase subsolidus demarcations was performed by the SnAs–SiAs2, SnAs–SiAs, Sn4As3–SiAs, and Sn4As3–Si sections. As a result of the experiment, taking into account the theoretical analysis, we suggested a scheme of phase equilibria in the system that involved the implementation of eutectic and four peritectic invariant equilibria, and we used differential thermal analysis to determine the temperature of these four-phase transformations. It was found that extended solid solutions were not formed in the system, and only a substitutional solid solution at least 3 mol % wide was formed based along the SnAs–SiAs2 section based on tin monoarsenidehttps://journals.vsu.ru/kcmf/article/view/11110phase diagrampolythermal sectionsi–sn–as ternary system |
| spellingShingle | Tatiana P. Sushkova Galina V. Semenova Elena Yu. Proskurina Phase relations in the Si–Sn–As system Конденсированные среды и межфазные границы phase diagram polythermal section si–sn–as ternary system |
| title | Phase relations in the Si–Sn–As system |
| title_full | Phase relations in the Si–Sn–As system |
| title_fullStr | Phase relations in the Si–Sn–As system |
| title_full_unstemmed | Phase relations in the Si–Sn–As system |
| title_short | Phase relations in the Si–Sn–As system |
| title_sort | phase relations in the si sn as system |
| topic | phase diagram polythermal section si–sn–as ternary system |
| url | https://journals.vsu.ru/kcmf/article/view/11110 |
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