Transfer Hydrogenation Employing Ethylene Diamine Bisborane in Water and Pd- and Ru-Nanoparticles in Ionic Liquids
Herein we demonstrate the use of ethylenediamine bisborane (EDAB) as a suitable hydrogen source for transfer hydrogenation reactions on C-C double bonds mediated by metal nanoparticles. Moreover, EDAB also acts as a reducing agent for carbonyl functionalities in water under metal-free conditions.
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2015-09-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/20/9/17058 |
| _version_ | 1818310945153220608 |
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| author | Sebastian Sahler Martin Scott Christian Gedig Martin H. G. Prechtl |
| author_facet | Sebastian Sahler Martin Scott Christian Gedig Martin H. G. Prechtl |
| author_sort | Sebastian Sahler |
| collection | DOAJ |
| description | Herein we demonstrate the use of ethylenediamine bisborane (EDAB) as a suitable hydrogen source for transfer hydrogenation reactions on C-C double bonds mediated by metal nanoparticles. Moreover, EDAB also acts as a reducing agent for carbonyl functionalities in water under metal-free conditions. |
| first_indexed | 2024-12-13T07:54:07Z |
| format | Article |
| id | doaj.art-56cf78e31b434e93b8e11da9c6a7a530 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-13T07:54:07Z |
| publishDate | 2015-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-56cf78e31b434e93b8e11da9c6a7a5302022-12-21T23:54:35ZengMDPI AGMolecules1420-30492015-09-01209170581706910.3390/molecules200917058molecules200917058Transfer Hydrogenation Employing Ethylene Diamine Bisborane in Water and Pd- and Ru-Nanoparticles in Ionic LiquidsSebastian Sahler0Martin Scott1Christian Gedig2Martin H. G. Prechtl3Department of Chemistry, University of Cologne, Greinstrasse 6, 50939 Cologne, GermanyDepartment of Chemistry, University of Cologne, Greinstrasse 6, 50939 Cologne, GermanyDepartment of Chemistry, University of Cologne, Greinstrasse 6, 50939 Cologne, GermanyDepartment of Chemistry, University of Cologne, Greinstrasse 6, 50939 Cologne, GermanyHerein we demonstrate the use of ethylenediamine bisborane (EDAB) as a suitable hydrogen source for transfer hydrogenation reactions on C-C double bonds mediated by metal nanoparticles. Moreover, EDAB also acts as a reducing agent for carbonyl functionalities in water under metal-free conditions.http://www.mdpi.com/1420-3049/20/9/17058rutheniumpalladiumtransfer-hydrogenationethylene diamine bisboraneammonia borane, EDAB, reducing, carbonyl |
| spellingShingle | Sebastian Sahler Martin Scott Christian Gedig Martin H. G. Prechtl Transfer Hydrogenation Employing Ethylene Diamine Bisborane in Water and Pd- and Ru-Nanoparticles in Ionic Liquids Molecules ruthenium palladium transfer-hydrogenation ethylene diamine bisborane ammonia borane, EDAB, reducing, carbonyl |
| title | Transfer Hydrogenation Employing Ethylene Diamine Bisborane in Water and Pd- and Ru-Nanoparticles in Ionic Liquids |
| title_full | Transfer Hydrogenation Employing Ethylene Diamine Bisborane in Water and Pd- and Ru-Nanoparticles in Ionic Liquids |
| title_fullStr | Transfer Hydrogenation Employing Ethylene Diamine Bisborane in Water and Pd- and Ru-Nanoparticles in Ionic Liquids |
| title_full_unstemmed | Transfer Hydrogenation Employing Ethylene Diamine Bisborane in Water and Pd- and Ru-Nanoparticles in Ionic Liquids |
| title_short | Transfer Hydrogenation Employing Ethylene Diamine Bisborane in Water and Pd- and Ru-Nanoparticles in Ionic Liquids |
| title_sort | transfer hydrogenation employing ethylene diamine bisborane in water and pd and ru nanoparticles in ionic liquids |
| topic | ruthenium palladium transfer-hydrogenation ethylene diamine bisborane ammonia borane, EDAB, reducing, carbonyl |
| url | http://www.mdpi.com/1420-3049/20/9/17058 |
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