Alkynylation of Aldehydes Initiated by Cathodic Reduction

Abstract Alkynylation of aldehydes initiated by cathodic reduction was performed. The cathodic alkynylation required only a semi‐catalytic amount of electricity to consume the starting material completely. Cyclic voltammetry and some control experiments suggest that the electron‐generated base deriv...

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Bibliographic Details
Main Authors: Dr. Eisuke Sato, Mayu Fujii, Dr. Koichi Mitsudo, Prof. Dr. Seiji Suga
Format: Article
Language:English
Published: Wiley-VCH 2024-01-01
Series:ChemElectroChem
Subjects:
Online Access:https://doi.org/10.1002/celc.202300499
Description
Summary:Abstract Alkynylation of aldehydes initiated by cathodic reduction was performed. The cathodic alkynylation required only a semi‐catalytic amount of electricity to consume the starting material completely. Cyclic voltammetry and some control experiments suggest that the electron‐generated base derived from the cathodic reduction of benzaldehyde promotes alkynylation.
ISSN:2196-0216