Alkynylation of Aldehydes Initiated by Cathodic Reduction
Abstract Alkynylation of aldehydes initiated by cathodic reduction was performed. The cathodic alkynylation required only a semi‐catalytic amount of electricity to consume the starting material completely. Cyclic voltammetry and some control experiments suggest that the electron‐generated base deriv...
| Main Authors: | , , , |
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| פורמט: | Article |
| שפה: | English |
| יצא לאור: |
Wiley-VCH
2024-01-01
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| סדרה: | ChemElectroChem |
| נושאים: | |
| גישה מקוונת: | https://doi.org/10.1002/celc.202300499 |
| _version_ | 1827383978995220480 |
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| author | Dr. Eisuke Sato Mayu Fujii Dr. Koichi Mitsudo Prof. Dr. Seiji Suga |
| author_facet | Dr. Eisuke Sato Mayu Fujii Dr. Koichi Mitsudo Prof. Dr. Seiji Suga |
| author_sort | Dr. Eisuke Sato |
| collection | DOAJ |
| description | Abstract Alkynylation of aldehydes initiated by cathodic reduction was performed. The cathodic alkynylation required only a semi‐catalytic amount of electricity to consume the starting material completely. Cyclic voltammetry and some control experiments suggest that the electron‐generated base derived from the cathodic reduction of benzaldehyde promotes alkynylation. |
| first_indexed | 2024-03-08T14:48:55Z |
| format | Article |
| id | doaj.art-56de7e2dd7fa43a09191d5f66c307dd8 |
| institution | Directory Open Access Journal |
| issn | 2196-0216 |
| language | English |
| last_indexed | 2024-03-08T14:48:55Z |
| publishDate | 2024-01-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | ChemElectroChem |
| spelling | doaj.art-56de7e2dd7fa43a09191d5f66c307dd82024-01-11T04:41:33ZengWiley-VCHChemElectroChem2196-02162024-01-01111n/an/a10.1002/celc.202300499Alkynylation of Aldehydes Initiated by Cathodic ReductionDr. Eisuke Sato0Mayu Fujii1Dr. Koichi Mitsudo2Prof. Dr. Seiji Suga3Division of Applied Chemistry Graduate School of Environmental, Life Natural Science and Technology Okayama University 3-1-1, Tsushima-naka, Kita-ku Okayama 700-8530 JapanDivision of Applied Chemistry Graduate School of Environmental, Life Natural Science and Technology Okayama University 3-1-1, Tsushima-naka, Kita-ku Okayama 700-8530 JapanDivision of Applied Chemistry Graduate School of Environmental, Life Natural Science and Technology Okayama University 3-1-1, Tsushima-naka, Kita-ku Okayama 700-8530 JapanDivision of Applied Chemistry Graduate School of Environmental, Life Natural Science and Technology Okayama University 3-1-1, Tsushima-naka, Kita-ku Okayama 700-8530 JapanAbstract Alkynylation of aldehydes initiated by cathodic reduction was performed. The cathodic alkynylation required only a semi‐catalytic amount of electricity to consume the starting material completely. Cyclic voltammetry and some control experiments suggest that the electron‐generated base derived from the cathodic reduction of benzaldehyde promotes alkynylation.https://doi.org/10.1002/celc.202300499AlkynylationCatalytic electrolysisCathodic reductionElectrochemical synthesisTrimethylsilylacetylene |
| spellingShingle | Dr. Eisuke Sato Mayu Fujii Dr. Koichi Mitsudo Prof. Dr. Seiji Suga Alkynylation of Aldehydes Initiated by Cathodic Reduction ChemElectroChem Alkynylation Catalytic electrolysis Cathodic reduction Electrochemical synthesis Trimethylsilylacetylene |
| title | Alkynylation of Aldehydes Initiated by Cathodic Reduction |
| title_full | Alkynylation of Aldehydes Initiated by Cathodic Reduction |
| title_fullStr | Alkynylation of Aldehydes Initiated by Cathodic Reduction |
| title_full_unstemmed | Alkynylation of Aldehydes Initiated by Cathodic Reduction |
| title_short | Alkynylation of Aldehydes Initiated by Cathodic Reduction |
| title_sort | alkynylation of aldehydes initiated by cathodic reduction |
| topic | Alkynylation Catalytic electrolysis Cathodic reduction Electrochemical synthesis Trimethylsilylacetylene |
| url | https://doi.org/10.1002/celc.202300499 |
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