Diffusion Study by IR Micro-Imaging of Molecular Uptake and Release on Mesoporous Zeolites of Structure Type CHA and LTA
The presence of mesopores in the interior of microporous particles may significantly improve their transport properties. Complementing previous macroscopic transient sorption experiments and pulsed field gradient NMR self-diffusion studies with such materials, the present study is dedicated to an in...
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| Format: | Article |
| Language: | English |
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MDPI AG
2013-07-01
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| Series: | Materials |
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| Online Access: | http://www.mdpi.com/1996-1944/6/7/2662 |
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| author | Jörg Kärger Ryong Ryoo Suresh K. Bhatia Stefan Kaskel Rustem Valiullin Christian Chmelik Dirk Mehlhorn Tobias Titze Franz Schmidt Mauricio Rincon Bonilla |
| author_facet | Jörg Kärger Ryong Ryoo Suresh K. Bhatia Stefan Kaskel Rustem Valiullin Christian Chmelik Dirk Mehlhorn Tobias Titze Franz Schmidt Mauricio Rincon Bonilla |
| author_sort | Jörg Kärger |
| collection | DOAJ |
| description | The presence of mesopores in the interior of microporous particles may significantly improve their transport properties. Complementing previous macroscopic transient sorption experiments and pulsed field gradient NMR self-diffusion studies with such materials, the present study is dedicated to an in-depth study of molecular uptake and release on the individual particles of mesoporous zeolitic specimens, notably with samples of the narrow-pore structure types, CHA and LTA. The investigations are focused on determining the time constants and functional dependences of uptake and release. They include a systematic variation of the architecture of the mesopores and of the guest molecules under study as well as a comparison of transient uptake with blocked and un-blocked mesopores. In addition to accelerating intracrystalline mass transfer, transport enhancement by mesopores is found to be, possibly, also caused by a reduction of transport resistances on the particle surfaces. |
| first_indexed | 2024-04-13T08:10:14Z |
| format | Article |
| id | doaj.art-5714db0d68be49fa896f39b7571ce1e1 |
| institution | Directory Open Access Journal |
| issn | 1996-1944 |
| language | English |
| last_indexed | 2024-04-13T08:10:14Z |
| publishDate | 2013-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Materials |
| spelling | doaj.art-5714db0d68be49fa896f39b7571ce1e12022-12-22T02:55:00ZengMDPI AGMaterials1996-19442013-07-01672662268810.3390/ma6072662Diffusion Study by IR Micro-Imaging of Molecular Uptake and Release on Mesoporous Zeolites of Structure Type CHA and LTAJörg KärgerRyong RyooSuresh K. BhatiaStefan KaskelRustem ValiullinChristian ChmelikDirk MehlhornTobias TitzeFranz SchmidtMauricio Rincon BonillaThe presence of mesopores in the interior of microporous particles may significantly improve their transport properties. Complementing previous macroscopic transient sorption experiments and pulsed field gradient NMR self-diffusion studies with such materials, the present study is dedicated to an in-depth study of molecular uptake and release on the individual particles of mesoporous zeolitic specimens, notably with samples of the narrow-pore structure types, CHA and LTA. The investigations are focused on determining the time constants and functional dependences of uptake and release. They include a systematic variation of the architecture of the mesopores and of the guest molecules under study as well as a comparison of transient uptake with blocked and un-blocked mesopores. In addition to accelerating intracrystalline mass transfer, transport enhancement by mesopores is found to be, possibly, also caused by a reduction of transport resistances on the particle surfaces.http://www.mdpi.com/1996-1944/6/7/2662mesoporous zeolitesIR micro-imagingdiffusionsurface barriersNaCaASAPO-34paraffinsolefins |
| spellingShingle | Jörg Kärger Ryong Ryoo Suresh K. Bhatia Stefan Kaskel Rustem Valiullin Christian Chmelik Dirk Mehlhorn Tobias Titze Franz Schmidt Mauricio Rincon Bonilla Diffusion Study by IR Micro-Imaging of Molecular Uptake and Release on Mesoporous Zeolites of Structure Type CHA and LTA Materials mesoporous zeolites IR micro-imaging diffusion surface barriers NaCaA SAPO-34 paraffins olefins |
| title | Diffusion Study by IR Micro-Imaging of Molecular Uptake and Release on Mesoporous Zeolites of Structure Type CHA and LTA |
| title_full | Diffusion Study by IR Micro-Imaging of Molecular Uptake and Release on Mesoporous Zeolites of Structure Type CHA and LTA |
| title_fullStr | Diffusion Study by IR Micro-Imaging of Molecular Uptake and Release on Mesoporous Zeolites of Structure Type CHA and LTA |
| title_full_unstemmed | Diffusion Study by IR Micro-Imaging of Molecular Uptake and Release on Mesoporous Zeolites of Structure Type CHA and LTA |
| title_short | Diffusion Study by IR Micro-Imaging of Molecular Uptake and Release on Mesoporous Zeolites of Structure Type CHA and LTA |
| title_sort | diffusion study by ir micro imaging of molecular uptake and release on mesoporous zeolites of structure type cha and lta |
| topic | mesoporous zeolites IR micro-imaging diffusion surface barriers NaCaA SAPO-34 paraffins olefins |
| url | http://www.mdpi.com/1996-1944/6/7/2662 |
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