Mineral Chemistry of Low-Temperature Phyllosilicates in Early Paleozoic Metaclastic Rocks, Eastern Tauride Belt, Türkiye

The mineral chemistry of illite/mica and chlorites, together with the evaluation of textural data of low-temperature metaclastic rocks, plays an important role in determining their origin and metamorphic grade. This study aimed to investigate the chemical properties of phyllosilicates in early Paleo...

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Main Authors: Ömer Bozkaya, Hüseyin Yalçın
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/12/9/1088
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author Ömer Bozkaya
Hüseyin Yalçın
author_facet Ömer Bozkaya
Hüseyin Yalçın
author_sort Ömer Bozkaya
collection DOAJ
description The mineral chemistry of illite/mica and chlorites, together with the evaluation of textural data of low-temperature metaclastic rocks, plays an important role in determining their origin and metamorphic grade. This study aimed to investigate the chemical properties of phyllosilicates in early Paleozoic metaclastic rocks in the Eastern Tauride Belt, Türkiye. The textural (electron microscopy) and chemical (mineral chemistry analysis) analyses were performed on the samples representing different grades of metamorphism. The illites/micas and chlorites are observed as detrital (chlorite–mica stacks) and neoformation origin. Trioctahedral chlorites (chamosite) exhibit different chemistry for detrital and neoformed origin as well as the metamorphic grade. Tetrahedral Al and octahedral Fe + Mg increase, whereas octahedral Al decreases together with the increasing grade of metamorphism. The detrital chlorites have higher tetrahedral Al and Fe contents than their neoformed counterparts. Chlorite geothermometry data (detrital: 241–≥350 °C; neoformed: 201–268 °C) are compatible with the texture and illite Kübler index data. Illite/white-mica compositions display muscovite and Na-K mica. Tetrahedral Al and interlayer K + Na contents of illites/micas increase with metamorphic grade. Na-K mica and paragonite are observed as replacement-type developments within the detrital CMS. The obtained data indicate that phyllosilicate chemistry can be used effectively for determining the geological evolution of low-grade metamorphic sequences.
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spelling doaj.art-5735ced577a04e91bac8bb03f377cc3f2023-11-23T17:55:16ZengMDPI AGMinerals2075-163X2022-08-01129108810.3390/min12091088Mineral Chemistry of Low-Temperature Phyllosilicates in Early Paleozoic Metaclastic Rocks, Eastern Tauride Belt, TürkiyeÖmer Bozkaya0Hüseyin Yalçın1Department of Geological Engineering, Pamukkale University, 20160 Denizli, TurkeyDepartment of Geological Engineering, Sivas Cumhuriyet University, 58140 Sivas, TurkeyThe mineral chemistry of illite/mica and chlorites, together with the evaluation of textural data of low-temperature metaclastic rocks, plays an important role in determining their origin and metamorphic grade. This study aimed to investigate the chemical properties of phyllosilicates in early Paleozoic metaclastic rocks in the Eastern Tauride Belt, Türkiye. The textural (electron microscopy) and chemical (mineral chemistry analysis) analyses were performed on the samples representing different grades of metamorphism. The illites/micas and chlorites are observed as detrital (chlorite–mica stacks) and neoformation origin. Trioctahedral chlorites (chamosite) exhibit different chemistry for detrital and neoformed origin as well as the metamorphic grade. Tetrahedral Al and octahedral Fe + Mg increase, whereas octahedral Al decreases together with the increasing grade of metamorphism. The detrital chlorites have higher tetrahedral Al and Fe contents than their neoformed counterparts. Chlorite geothermometry data (detrital: 241–≥350 °C; neoformed: 201–268 °C) are compatible with the texture and illite Kübler index data. Illite/white-mica compositions display muscovite and Na-K mica. Tetrahedral Al and interlayer K + Na contents of illites/micas increase with metamorphic grade. Na-K mica and paragonite are observed as replacement-type developments within the detrital CMS. The obtained data indicate that phyllosilicate chemistry can be used effectively for determining the geological evolution of low-grade metamorphic sequences.https://www.mdpi.com/2075-163X/12/9/1088phyllosilicatemineral chemistrymetaclastic rockslow-grade metamorphism
spellingShingle Ömer Bozkaya
Hüseyin Yalçın
Mineral Chemistry of Low-Temperature Phyllosilicates in Early Paleozoic Metaclastic Rocks, Eastern Tauride Belt, Türkiye
Minerals
phyllosilicate
mineral chemistry
metaclastic rocks
low-grade metamorphism
title Mineral Chemistry of Low-Temperature Phyllosilicates in Early Paleozoic Metaclastic Rocks, Eastern Tauride Belt, Türkiye
title_full Mineral Chemistry of Low-Temperature Phyllosilicates in Early Paleozoic Metaclastic Rocks, Eastern Tauride Belt, Türkiye
title_fullStr Mineral Chemistry of Low-Temperature Phyllosilicates in Early Paleozoic Metaclastic Rocks, Eastern Tauride Belt, Türkiye
title_full_unstemmed Mineral Chemistry of Low-Temperature Phyllosilicates in Early Paleozoic Metaclastic Rocks, Eastern Tauride Belt, Türkiye
title_short Mineral Chemistry of Low-Temperature Phyllosilicates in Early Paleozoic Metaclastic Rocks, Eastern Tauride Belt, Türkiye
title_sort mineral chemistry of low temperature phyllosilicates in early paleozoic metaclastic rocks eastern tauride belt turkiye
topic phyllosilicate
mineral chemistry
metaclastic rocks
low-grade metamorphism
url https://www.mdpi.com/2075-163X/12/9/1088
work_keys_str_mv AT omerbozkaya mineralchemistryoflowtemperaturephyllosilicatesinearlypaleozoicmetaclasticrockseasterntauridebeltturkiye
AT huseyinyalcın mineralchemistryoflowtemperaturephyllosilicatesinearlypaleozoicmetaclasticrockseasterntauridebeltturkiye