Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram
A new Bi-rich part of Bi2O3–PbO phase diagram was determined using differential thermal analysis and X-ray powder diffraction techniques. Four solid solutions, α-Bi2O3, γ-Bi2O3, δ-Bi2O3 and βss-Bi8Pb5O17, can be distinguished below 37.5 mol % of PbO and one compound, β2-Bi8Pb5O17. Two of them, δ-Bi2...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Serbian Chemical Society
2017-01-01
|
| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2017/0352-51391700111D.pdf |
| _version_ | 1824019933232627712 |
|---|---|
| author | Dapčević Aleksandra Poleti Dejan Karanović Ljiljana Miladinović Jelena |
| author_facet | Dapčević Aleksandra Poleti Dejan Karanović Ljiljana Miladinović Jelena |
| author_sort | Dapčević Aleksandra |
| collection | DOAJ |
| description | A new Bi-rich part of Bi2O3–PbO phase diagram was determined using differential thermal analysis and X-ray powder diffraction techniques. Four solid solutions, α-Bi2O3, γ-Bi2O3, δ-Bi2O3 and βss-Bi8Pb5O17, can be distinguished below 37.5 mol % of PbO and one compound, β2-Bi8Pb5O17. Two of them, δ-Bi2O3 and βss-Bi8Pb5O17 are high-temperature phases. The large field of γ-Bi2O3 stability was implemented making the crucial difference comparing to phase diagrams from the Bi2O3–PbO system published so far. [Project of
the Serbian Ministry of Education, Science and Technological Development,
Grant no. III 45007] |
| first_indexed | 2024-12-19T01:25:37Z |
| format | Article |
| id | doaj.art-573a3b069b0646a28f3d3304bf0c5f83 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 1820-7421 |
| language | English |
| last_indexed | 2024-12-19T01:25:37Z |
| publishDate | 2017-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-573a3b069b0646a28f3d3304bf0c5f832022-12-21T20:42:15ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212017-01-0182121433144410.2298/JSC170711111D0352-51391700111DInvestigation of Bi2O3-rich part of Bi2O3-PbO phase diagramDapčević Aleksandra0Poleti Dejan1Karanović Ljiljana2Miladinović Jelena3Faculty of Technology and Metallurgy, Department of General and Inorganic Chemistry, BelgradeFaculty of Technology and Metallurgy, Department of General and Inorganic Chemistry, BelgradeFaculty of Mining and Geology, Laboratory of Crystallography, BelgradeFaculty of Technology and Metallurgy, Department of Inorganic Chemical Technology, BelgradeA new Bi-rich part of Bi2O3–PbO phase diagram was determined using differential thermal analysis and X-ray powder diffraction techniques. Four solid solutions, α-Bi2O3, γ-Bi2O3, δ-Bi2O3 and βss-Bi8Pb5O17, can be distinguished below 37.5 mol % of PbO and one compound, β2-Bi8Pb5O17. Two of them, δ-Bi2O3 and βss-Bi8Pb5O17 are high-temperature phases. The large field of γ-Bi2O3 stability was implemented making the crucial difference comparing to phase diagrams from the Bi2O3–PbO system published so far. [Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. III 45007]http://www.doiserbia.nb.rs/img/doi/0352-5139/2017/0352-51391700111D.pdfBi2O3PbOphase diagram |
| spellingShingle | Dapčević Aleksandra Poleti Dejan Karanović Ljiljana Miladinović Jelena Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram Journal of the Serbian Chemical Society Bi2O3 PbO phase diagram |
| title | Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram |
| title_full | Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram |
| title_fullStr | Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram |
| title_full_unstemmed | Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram |
| title_short | Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram |
| title_sort | investigation of bi2o3 rich part of bi2o3 pbo phase diagram |
| topic | Bi2O3 PbO phase diagram |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2017/0352-51391700111D.pdf |
| work_keys_str_mv | AT dapcevicaleksandra investigationofbi2o3richpartofbi2o3pbophasediagram AT poletidejan investigationofbi2o3richpartofbi2o3pbophasediagram AT karanovicljiljana investigationofbi2o3richpartofbi2o3pbophasediagram AT miladinovicjelena investigationofbi2o3richpartofbi2o3pbophasediagram |