Electrocoagulation removal of Pb, Cd, and Cu ions from wastewater using a new configuration of electrodes
A new configuration of aluminum electrodes has been performed in an electrocoagulation reactor (ECR) to remove toxic metals from synthetic wastewater. The ECR contains four concentric-cubic electrodes that were connected to the DC power supply with a bipolar mode. The ability of this reactor to elim...
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| Format: | Article |
| Language: | English |
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Elsevier
2023-01-01
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| Series: | MethodsX |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2215016122003272 |
| _version_ | 1797796454860849152 |
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| author | Forat Yasir AlJaberi Zahraa Alaa Hawaas |
| author_facet | Forat Yasir AlJaberi Zahraa Alaa Hawaas |
| author_sort | Forat Yasir AlJaberi |
| collection | DOAJ |
| description | A new configuration of aluminum electrodes has been performed in an electrocoagulation reactor (ECR) to remove toxic metals from synthetic wastewater. The ECR contains four concentric-cubic electrodes that were connected to the DC power supply with a bipolar mode. The ability of this reactor to eliminate 200 ppm Pb, 200 ppm Cd and 200 ppm Cu from wastewater was investigated under the effect of pH (4–10), applied current (0.2–2.6 A), and the reaction time of (4–60 min). Two grams of NaCl were added to each experiment to enhance the electrical conductivity and minimize the passivation of cathode surfaces. The experiments, analysis, and optimization were conducted using response surface methodology type Box-Behnken design (RSM-BBD) and the Minitab-statistical software program. The highest elimination of heavy metals was: Pb-99.73%, Cd-98.54%, and Cu-98.92% at pH 10, 1.4 A of the applied current, and 60 min of the reaction time. The total real consumption of anodes under these conditions was 0.55 g, and the energy consumption was 12.71 kWh/m3. All reactions of metal removal that occurred in the present EC reactor obey the kinetic of a first-order reaction. Thermodynamics parameters of present electrocoagulation removal of heavy metals indicate an endothermic, spontaneous nature, and random irregularity at the liquid-solid interaction. The highest values of removal efficiencies and the considerably lowest values of energy and electrode consumption proved that the electrocoagulation technology applies in wastewater treatment containing toxic metals. • The anode electrodes were perforated to decrease the amount of electrode consumption, while the cathode electrodes were not perforated. • The new EC reactor eliminated Pb-99.73%, Cd-98.54%, and Cu-98.92% of 200 mg/l of each metal at pH 10, applied current of 1.4 A, and reaction time of 60 min. Moreover, the consumption of energy and electrodes was significantly low. • The performance indicator (R2) of the studied responses was higher than 0.95. |
| first_indexed | 2024-03-13T03:33:19Z |
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| id | doaj.art-5768a4bdb655497dbd70e05874f475d8 |
| institution | Directory Open Access Journal |
| issn | 2215-0161 |
| language | English |
| last_indexed | 2024-03-13T03:33:19Z |
| publishDate | 2023-01-01 |
| publisher | Elsevier |
| record_format | Article |
| series | MethodsX |
| spelling | doaj.art-5768a4bdb655497dbd70e05874f475d82023-06-24T05:16:46ZengElsevierMethodsX2215-01612023-01-0110101951Electrocoagulation removal of Pb, Cd, and Cu ions from wastewater using a new configuration of electrodesForat Yasir AlJaberi0Zahraa Alaa Hawaas1Corresponding author.; Chemical Engineering Department, College of Engineering, Al- Muthanna University, Al- Muthanna, IraqChemical Engineering Department, College of Engineering, Al- Muthanna University, Al- Muthanna, IraqA new configuration of aluminum electrodes has been performed in an electrocoagulation reactor (ECR) to remove toxic metals from synthetic wastewater. The ECR contains four concentric-cubic electrodes that were connected to the DC power supply with a bipolar mode. The ability of this reactor to eliminate 200 ppm Pb, 200 ppm Cd and 200 ppm Cu from wastewater was investigated under the effect of pH (4–10), applied current (0.2–2.6 A), and the reaction time of (4–60 min). Two grams of NaCl were added to each experiment to enhance the electrical conductivity and minimize the passivation of cathode surfaces. The experiments, analysis, and optimization were conducted using response surface methodology type Box-Behnken design (RSM-BBD) and the Minitab-statistical software program. The highest elimination of heavy metals was: Pb-99.73%, Cd-98.54%, and Cu-98.92% at pH 10, 1.4 A of the applied current, and 60 min of the reaction time. The total real consumption of anodes under these conditions was 0.55 g, and the energy consumption was 12.71 kWh/m3. All reactions of metal removal that occurred in the present EC reactor obey the kinetic of a first-order reaction. Thermodynamics parameters of present electrocoagulation removal of heavy metals indicate an endothermic, spontaneous nature, and random irregularity at the liquid-solid interaction. The highest values of removal efficiencies and the considerably lowest values of energy and electrode consumption proved that the electrocoagulation technology applies in wastewater treatment containing toxic metals. • The anode electrodes were perforated to decrease the amount of electrode consumption, while the cathode electrodes were not perforated. • The new EC reactor eliminated Pb-99.73%, Cd-98.54%, and Cu-98.92% of 200 mg/l of each metal at pH 10, applied current of 1.4 A, and reaction time of 60 min. Moreover, the consumption of energy and electrodes was significantly low. • The performance indicator (R2) of the studied responses was higher than 0.95.http://www.sciencedirect.com/science/article/pii/S2215016122003272Electrocoagulation removal of Pb, Cd, and Cu ions from wastewater using a new configuration of electrodes |
| spellingShingle | Forat Yasir AlJaberi Zahraa Alaa Hawaas Electrocoagulation removal of Pb, Cd, and Cu ions from wastewater using a new configuration of electrodes MethodsX Electrocoagulation removal of Pb, Cd, and Cu ions from wastewater using a new configuration of electrodes |
| title | Electrocoagulation removal of Pb, Cd, and Cu ions from wastewater using a new configuration of electrodes |
| title_full | Electrocoagulation removal of Pb, Cd, and Cu ions from wastewater using a new configuration of electrodes |
| title_fullStr | Electrocoagulation removal of Pb, Cd, and Cu ions from wastewater using a new configuration of electrodes |
| title_full_unstemmed | Electrocoagulation removal of Pb, Cd, and Cu ions from wastewater using a new configuration of electrodes |
| title_short | Electrocoagulation removal of Pb, Cd, and Cu ions from wastewater using a new configuration of electrodes |
| title_sort | electrocoagulation removal of pb cd and cu ions from wastewater using a new configuration of electrodes |
| topic | Electrocoagulation removal of Pb, Cd, and Cu ions from wastewater using a new configuration of electrodes |
| url | http://www.sciencedirect.com/science/article/pii/S2215016122003272 |
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