Geochemical and reflectance spectroscopy data integration to characterize emerald deposits: the case of the Paraná deposit, Brazil

Abstract The Paraná emerald deposit is one of the few occurrences of emerald, a rare beryl variety, in Borborema Province, northeastern Brazil. We characterized the Paraná deposit by combining field geology, petrography, whole-rock geochemistry, mineral chemistry, and reflectance spectroscopy. The m...

Full description

Bibliographic Details
Main Authors: JOSÉ F. ARAÚJO NETO, SANDRA B. BARRETO, THAIS A. CARRINO, IGOR M.B.A. SOUZA, GLENDA L. SANTOS
Format: Article
Language:English
Published: Academia Brasileira de Ciências 2021-03-01
Series:Anais da Academia Brasileira de Ciências
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652021000101218&tlng=en
_version_ 1798019690360995840
author JOSÉ F. ARAÚJO NETO
SANDRA B. BARRETO
THAIS A. CARRINO
IGOR M.B.A. SOUZA
GLENDA L. SANTOS
author_facet JOSÉ F. ARAÚJO NETO
SANDRA B. BARRETO
THAIS A. CARRINO
IGOR M.B.A. SOUZA
GLENDA L. SANTOS
author_sort JOSÉ F. ARAÚJO NETO
collection DOAJ
description Abstract The Paraná emerald deposit is one of the few occurrences of emerald, a rare beryl variety, in Borborema Province, northeastern Brazil. We characterized the Paraná deposit by combining field geology, petrography, whole-rock geochemistry, mineral chemistry, and reflectance spectroscopy. The mineralization is associated with phlogopite-, actinolite-phlogopite-, and phlogopite-phengite schists, mylonitic gneisses, and several acidic rocks (e.g. granitic pegmatites/aplites, quartz ± feldspar veins) along the Portalegre Shear Zone. Emerald can be found in quartz-feldspar and aplite veins and veinlets interleaved with phlogopite- or actinolite-phlogopite schists, or within the foliation of the schists. The presence of albitites and the compositional variation of the schists suggest a metasomatic origin for emerald with variations of the metasomatic process. All these different lithotypes can be readily identified through reflectance spectroscopy especially in the range of 2,150-2,450 nm, where the main mafic minerals show absorption features related to Al-OH (phengite), and Fe-OH and Mg-OH bonds (phlogopite/actinolite). Our study shows that possible mineralized phlogopite schists can be distinguished from other sterile rocks, although point spectral analysis does not separate emerald-bearing phlogopite schists from schists without emerald due to the dominance of major phlogopite absorption features rather than emerald features.
first_indexed 2024-04-11T16:44:58Z
format Article
id doaj.art-57872f2223a04cf0921f6bca0d3b9d3f
institution Directory Open Access Journal
issn 1678-2690
language English
last_indexed 2024-04-11T16:44:58Z
publishDate 2021-03-01
publisher Academia Brasileira de Ciências
record_format Article
series Anais da Academia Brasileira de Ciências
spelling doaj.art-57872f2223a04cf0921f6bca0d3b9d3f2022-12-22T04:13:36ZengAcademia Brasileira de CiênciasAnais da Academia Brasileira de Ciências1678-26902021-03-0193110.1590/0001-3765202120200236Geochemical and reflectance spectroscopy data integration to characterize emerald deposits: the case of the Paraná deposit, BrazilJOSÉ F. ARAÚJO NETOhttps://orcid.org/0000-0002-1780-9469SANDRA B. BARRETOhttps://orcid.org/0000-0001-8464-7087THAIS A. CARRINOhttps://orcid.org/0000-0001-8528-5225IGOR M.B.A. SOUZAhttps://orcid.org/0000-0002-2235-5668GLENDA L. SANTOShttps://orcid.org/0000-0002-6271-950XAbstract The Paraná emerald deposit is one of the few occurrences of emerald, a rare beryl variety, in Borborema Province, northeastern Brazil. We characterized the Paraná deposit by combining field geology, petrography, whole-rock geochemistry, mineral chemistry, and reflectance spectroscopy. The mineralization is associated with phlogopite-, actinolite-phlogopite-, and phlogopite-phengite schists, mylonitic gneisses, and several acidic rocks (e.g. granitic pegmatites/aplites, quartz ± feldspar veins) along the Portalegre Shear Zone. Emerald can be found in quartz-feldspar and aplite veins and veinlets interleaved with phlogopite- or actinolite-phlogopite schists, or within the foliation of the schists. The presence of albitites and the compositional variation of the schists suggest a metasomatic origin for emerald with variations of the metasomatic process. All these different lithotypes can be readily identified through reflectance spectroscopy especially in the range of 2,150-2,450 nm, where the main mafic minerals show absorption features related to Al-OH (phengite), and Fe-OH and Mg-OH bonds (phlogopite/actinolite). Our study shows that possible mineralized phlogopite schists can be distinguished from other sterile rocks, although point spectral analysis does not separate emerald-bearing phlogopite schists from schists without emerald due to the dominance of major phlogopite absorption features rather than emerald features.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652021000101218&tlng=enGeochemistrymineral chemistryParaná emerald depositpetrographyreflectance spectroscopy
spellingShingle JOSÉ F. ARAÚJO NETO
SANDRA B. BARRETO
THAIS A. CARRINO
IGOR M.B.A. SOUZA
GLENDA L. SANTOS
Geochemical and reflectance spectroscopy data integration to characterize emerald deposits: the case of the Paraná deposit, Brazil
Anais da Academia Brasileira de Ciências
Geochemistry
mineral chemistry
Paraná emerald deposit
petrography
reflectance spectroscopy
title Geochemical and reflectance spectroscopy data integration to characterize emerald deposits: the case of the Paraná deposit, Brazil
title_full Geochemical and reflectance spectroscopy data integration to characterize emerald deposits: the case of the Paraná deposit, Brazil
title_fullStr Geochemical and reflectance spectroscopy data integration to characterize emerald deposits: the case of the Paraná deposit, Brazil
title_full_unstemmed Geochemical and reflectance spectroscopy data integration to characterize emerald deposits: the case of the Paraná deposit, Brazil
title_short Geochemical and reflectance spectroscopy data integration to characterize emerald deposits: the case of the Paraná deposit, Brazil
title_sort geochemical and reflectance spectroscopy data integration to characterize emerald deposits the case of the parana deposit brazil
topic Geochemistry
mineral chemistry
Paraná emerald deposit
petrography
reflectance spectroscopy
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652021000101218&tlng=en
work_keys_str_mv AT josefaraujoneto geochemicalandreflectancespectroscopydataintegrationtocharacterizeemeralddepositsthecaseoftheparanadepositbrazil
AT sandrabbarreto geochemicalandreflectancespectroscopydataintegrationtocharacterizeemeralddepositsthecaseoftheparanadepositbrazil
AT thaisacarrino geochemicalandreflectancespectroscopydataintegrationtocharacterizeemeralddepositsthecaseoftheparanadepositbrazil
AT igormbasouza geochemicalandreflectancespectroscopydataintegrationtocharacterizeemeralddepositsthecaseoftheparanadepositbrazil
AT glendalsantos geochemicalandreflectancespectroscopydataintegrationtocharacterizeemeralddepositsthecaseoftheparanadepositbrazil