High-Contrast Visualization Chemiluminescence Based on AIE-Active and Base-Sensitive Emitters

Peroxyoxalate chemiluminescence (PO-CL) is one of the most popular cold light sources, yet the drawback of aggregation-caused quenching limits their use. Here, we report a new kind of efficient bifunctional emitter derived from salicylic acid, which not only exhibits typical aggregation-induced emis...

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Main Authors: Xiao-Wen Zhang, Xu-Lin Chen, Can-Zhong Lu
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/28/9/3976
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author Xiao-Wen Zhang
Xu-Lin Chen
Can-Zhong Lu
author_facet Xiao-Wen Zhang
Xu-Lin Chen
Can-Zhong Lu
author_sort Xiao-Wen Zhang
collection DOAJ
description Peroxyoxalate chemiluminescence (PO-CL) is one of the most popular cold light sources, yet the drawback of aggregation-caused quenching limits their use. Here, we report a new kind of efficient bifunctional emitter derived from salicylic acid, which not only exhibits typical aggregation-induced emission (AIE) character but also has the ability to catalyze the CL process under basic conditions based on base sensitivity. By taking advantage of these unique features, we successfully confine the CL process on the surface of solid bases and provide a high-contrast visualization of CL emission. This method allows most of the common basic salts like sodium carbonate to be invisible encryption information ink and PO-CL solution to be a decryption tool to visualize the hidden information. The current study opens up an appealing way for the development of multifunction CL emitters for information encryption and decryption applications.
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spelling doaj.art-5797b78340d24d00906218253f3fe8d92023-11-17T23:25:59ZengMDPI AGMolecules1420-30492023-05-01289397610.3390/molecules28093976High-Contrast Visualization Chemiluminescence Based on AIE-Active and Base-Sensitive EmittersXiao-Wen Zhang0Xu-Lin Chen1Can-Zhong Lu2State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, ChinaState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, ChinaState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, ChinaPeroxyoxalate chemiluminescence (PO-CL) is one of the most popular cold light sources, yet the drawback of aggregation-caused quenching limits their use. Here, we report a new kind of efficient bifunctional emitter derived from salicylic acid, which not only exhibits typical aggregation-induced emission (AIE) character but also has the ability to catalyze the CL process under basic conditions based on base sensitivity. By taking advantage of these unique features, we successfully confine the CL process on the surface of solid bases and provide a high-contrast visualization of CL emission. This method allows most of the common basic salts like sodium carbonate to be invisible encryption information ink and PO-CL solution to be a decryption tool to visualize the hidden information. The current study opens up an appealing way for the development of multifunction CL emitters for information encryption and decryption applications.https://www.mdpi.com/1420-3049/28/9/3976chemiluminescenceaggregation-induced emissionbase-sensitivehigh-contrast visualizationencryption and decryption
spellingShingle Xiao-Wen Zhang
Xu-Lin Chen
Can-Zhong Lu
High-Contrast Visualization Chemiluminescence Based on AIE-Active and Base-Sensitive Emitters
Molecules
chemiluminescence
aggregation-induced emission
base-sensitive
high-contrast visualization
encryption and decryption
title High-Contrast Visualization Chemiluminescence Based on AIE-Active and Base-Sensitive Emitters
title_full High-Contrast Visualization Chemiluminescence Based on AIE-Active and Base-Sensitive Emitters
title_fullStr High-Contrast Visualization Chemiluminescence Based on AIE-Active and Base-Sensitive Emitters
title_full_unstemmed High-Contrast Visualization Chemiluminescence Based on AIE-Active and Base-Sensitive Emitters
title_short High-Contrast Visualization Chemiluminescence Based on AIE-Active and Base-Sensitive Emitters
title_sort high contrast visualization chemiluminescence based on aie active and base sensitive emitters
topic chemiluminescence
aggregation-induced emission
base-sensitive
high-contrast visualization
encryption and decryption
url https://www.mdpi.com/1420-3049/28/9/3976
work_keys_str_mv AT xiaowenzhang highcontrastvisualizationchemiluminescencebasedonaieactiveandbasesensitiveemitters
AT xulinchen highcontrastvisualizationchemiluminescencebasedonaieactiveandbasesensitiveemitters
AT canzhonglu highcontrastvisualizationchemiluminescencebasedonaieactiveandbasesensitiveemitters