Metal-organic framework nanocrystal-derived hollow porous materials: Synthetic strategies and emerging applications
Metal-organic frameworks (MOFs) have garnered multidisciplinary attention due to their structural tailorability, controlled pore size, and physicochemical functions, and their inherent properties can be exploited by applying them as precursors and/or templates for fabricating derived hollow porous n...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2022-09-01
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| Series: | The Innovation |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666675822000777 |
| _version_ | 1811294740626276352 |
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| author | Xiaolu Liu Gaurav Verma Zhongshan Chen Baowei Hu Qifei Huang Hui Yang Shengqian Ma Xiangke Wang |
| author_facet | Xiaolu Liu Gaurav Verma Zhongshan Chen Baowei Hu Qifei Huang Hui Yang Shengqian Ma Xiangke Wang |
| author_sort | Xiaolu Liu |
| collection | DOAJ |
| description | Metal-organic frameworks (MOFs) have garnered multidisciplinary attention due to their structural tailorability, controlled pore size, and physicochemical functions, and their inherent properties can be exploited by applying them as precursors and/or templates for fabricating derived hollow porous nanomaterials. The fascinating, functional properties and applications of MOF-derived hollow porous materials primarily lie in their chemical composition, hollow character, and unique porous structure. Herein, a comprehensive overview of the synthetic strategies and emerging applications of hollow porous materials derived from MOF-based templates and/or precursors is given. Based on the role of MOFs in the preparation of hollow porous materials, the synthetic strategies are described in detail, including (1) MOFs as removable templates, (2) MOF nanocrystals as both self-sacrificing templates and precursors, (3) MOF@secondary-component core-shell composites as precursors, and (4) hollow MOF nanocrystals and their composites as precursors. Subsequently, the applications of these hollow porous materials for chemical catalysis, electrocatalysis, energy storage and conversion, and environmental management are presented. Finally, a perspective on the research challenges and future opportunities and prospects for MOF-derived hollow materials is provided. Public summary: • MOFs have garnered multi-disciplinary attention due to their unique inherent properties • Various synthetic strategies of MOFs-derived hollow porous materials are summarized • Emerging applications of MOFs-derived hollow porous materials are reviewed |
| first_indexed | 2024-04-13T05:22:50Z |
| format | Article |
| id | doaj.art-57d05406add84a7bb27fab54691ea163 |
| institution | Directory Open Access Journal |
| issn | 2666-6758 |
| language | English |
| last_indexed | 2024-04-13T05:22:50Z |
| publishDate | 2022-09-01 |
| publisher | Elsevier |
| record_format | Article |
| series | The Innovation |
| spelling | doaj.art-57d05406add84a7bb27fab54691ea1632022-12-22T03:00:42ZengElsevierThe Innovation2666-67582022-09-0135100281Metal-organic framework nanocrystal-derived hollow porous materials: Synthetic strategies and emerging applicationsXiaolu Liu0Gaurav Verma1Zhongshan Chen2Baowei Hu3Qifei Huang4Hui Yang5Shengqian Ma6Xiangke Wang7College of Environmental Science and Engineering, North China Electric Power University, Beijing 102206, China; School of Life Science, Shaoxing University, Huancheng West Road 508, Shaoxing 312000, ChinaDepartment of Chemistry, University of North Texas, 1508 W Mulberry Street, Denton, TX 76201, USACollege of Environmental Science and Engineering, North China Electric Power University, Beijing 102206, ChinaSchool of Life Science, Shaoxing University, Huancheng West Road 508, Shaoxing 312000, ChinaState Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, ChinaCollege of Environmental Science and Engineering, North China Electric Power University, Beijing 102206, China; Corresponding authorDepartment of Chemistry, University of North Texas, 1508 W Mulberry Street, Denton, TX 76201, USA; Corresponding authorCollege of Environmental Science and Engineering, North China Electric Power University, Beijing 102206, China; School of Life Science, Shaoxing University, Huancheng West Road 508, Shaoxing 312000, China; Corresponding authorMetal-organic frameworks (MOFs) have garnered multidisciplinary attention due to their structural tailorability, controlled pore size, and physicochemical functions, and their inherent properties can be exploited by applying them as precursors and/or templates for fabricating derived hollow porous nanomaterials. The fascinating, functional properties and applications of MOF-derived hollow porous materials primarily lie in their chemical composition, hollow character, and unique porous structure. Herein, a comprehensive overview of the synthetic strategies and emerging applications of hollow porous materials derived from MOF-based templates and/or precursors is given. Based on the role of MOFs in the preparation of hollow porous materials, the synthetic strategies are described in detail, including (1) MOFs as removable templates, (2) MOF nanocrystals as both self-sacrificing templates and precursors, (3) MOF@secondary-component core-shell composites as precursors, and (4) hollow MOF nanocrystals and their composites as precursors. Subsequently, the applications of these hollow porous materials for chemical catalysis, electrocatalysis, energy storage and conversion, and environmental management are presented. Finally, a perspective on the research challenges and future opportunities and prospects for MOF-derived hollow materials is provided. Public summary: • MOFs have garnered multi-disciplinary attention due to their unique inherent properties • Various synthetic strategies of MOFs-derived hollow porous materials are summarized • Emerging applications of MOFs-derived hollow porous materials are reviewedhttp://www.sciencedirect.com/science/article/pii/S2666675822000777 |
| spellingShingle | Xiaolu Liu Gaurav Verma Zhongshan Chen Baowei Hu Qifei Huang Hui Yang Shengqian Ma Xiangke Wang Metal-organic framework nanocrystal-derived hollow porous materials: Synthetic strategies and emerging applications The Innovation |
| title | Metal-organic framework nanocrystal-derived hollow porous materials: Synthetic strategies and emerging applications |
| title_full | Metal-organic framework nanocrystal-derived hollow porous materials: Synthetic strategies and emerging applications |
| title_fullStr | Metal-organic framework nanocrystal-derived hollow porous materials: Synthetic strategies and emerging applications |
| title_full_unstemmed | Metal-organic framework nanocrystal-derived hollow porous materials: Synthetic strategies and emerging applications |
| title_short | Metal-organic framework nanocrystal-derived hollow porous materials: Synthetic strategies and emerging applications |
| title_sort | metal organic framework nanocrystal derived hollow porous materials synthetic strategies and emerging applications |
| url | http://www.sciencedirect.com/science/article/pii/S2666675822000777 |
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