Normal-phase high performance liquid chromatography of estradiol derivatives on amino- and diol-columns
The retention behavior of estradiol derivatives was studied by HPLC on chemically bonded polar stationary phases: commercially available amino and diol- columns, as a function of the heptane-propan-1-ol as the mobile phase, when the volume fraction of propan-1-ol in the binary mobile phase was low,...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2003-01-01
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| Series: | Journal of the Serbian Chemical Society |
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| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2003/0352-51390312971A.pdf |
| _version_ | 1818884836424679424 |
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| author | Ačanski Marijana M. |
| author_facet | Ačanski Marijana M. |
| author_sort | Ačanski Marijana M. |
| collection | DOAJ |
| description | The retention behavior of estradiol derivatives was studied by HPLC on chemically bonded polar stationary phases: commercially available amino and diol- columns, as a function of the heptane-propan-1-ol as the mobile phase, when the volume fraction of propan-1-ol in the binary mobile phase was low, even less than 5 %. The relationship between the logarithm of the retention constant (log k) and the logarithm of the volume fraction of propan-1-ol (–log φ) in the eluent was linear for all solutes studied. The results are discussed in terms of the solute and stationary phase properties and compared with the results of the same derivatives obtained in earlier investigations. |
| first_indexed | 2024-12-19T15:55:52Z |
| format | Article |
| id | doaj.art-5804a01f5aa2431b8693fd809e68a94e |
| institution | Directory Open Access Journal |
| issn | 0352-5139 1820-7421 |
| language | English |
| last_indexed | 2024-12-19T15:55:52Z |
| publishDate | 2003-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-5804a01f5aa2431b8693fd809e68a94e2022-12-21T20:15:05ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212003-01-01681297197710.2298/JSC0312971A0352-51390312971ANormal-phase high performance liquid chromatography of estradiol derivatives on amino- and diol-columnsAčanski Marijana M.0Department of General and Inorganic Chemistry, Faculty of Technology, University of Novi Sad, Bulevar cara Lazara 1, 21000 Novi Sad, Serbia and MontenegroThe retention behavior of estradiol derivatives was studied by HPLC on chemically bonded polar stationary phases: commercially available amino and diol- columns, as a function of the heptane-propan-1-ol as the mobile phase, when the volume fraction of propan-1-ol in the binary mobile phase was low, even less than 5 %. The relationship between the logarithm of the retention constant (log k) and the logarithm of the volume fraction of propan-1-ol (–log φ) in the eluent was linear for all solutes studied. The results are discussed in terms of the solute and stationary phase properties and compared with the results of the same derivatives obtained in earlier investigations.http://www.doiserbia.nb.rs/img/doi/0352-5139/2003/0352-51390312971A.pdfhplcamino- and diol- columnsnon-aqueous eluentestradiol derivativesretention behaviour |
| spellingShingle | Ačanski Marijana M. Normal-phase high performance liquid chromatography of estradiol derivatives on amino- and diol-columns Journal of the Serbian Chemical Society hplc amino- and diol- columns non-aqueous eluent estradiol derivatives retention behaviour |
| title | Normal-phase high performance liquid chromatography of estradiol derivatives on amino- and diol-columns |
| title_full | Normal-phase high performance liquid chromatography of estradiol derivatives on amino- and diol-columns |
| title_fullStr | Normal-phase high performance liquid chromatography of estradiol derivatives on amino- and diol-columns |
| title_full_unstemmed | Normal-phase high performance liquid chromatography of estradiol derivatives on amino- and diol-columns |
| title_short | Normal-phase high performance liquid chromatography of estradiol derivatives on amino- and diol-columns |
| title_sort | normal phase high performance liquid chromatography of estradiol derivatives on amino and diol columns |
| topic | hplc amino- and diol- columns non-aqueous eluent estradiol derivatives retention behaviour |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2003/0352-51390312971A.pdf |
| work_keys_str_mv | AT acanskimarijanam normalphasehighperformanceliquidchromatographyofestradiolderivativesonaminoanddiolcolumns |