2-Amino-4-methylpyridinium 3-chlorobenzoate
In the title salt, C6H9N2+·C7H4ClO2−, the 2-amino-4-methylpyridinium cation is almost planar, with a maximum deviation of 0.010 (1) Å. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681002444X |
| _version_ | 1831686726750306304 |
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| author | Madhukar Hemamalini Hoong-Kun Fun |
| author_facet | Madhukar Hemamalini Hoong-Kun Fun |
| author_sort | Madhukar Hemamalini |
| collection | DOAJ |
| description | In the title salt, C6H9N2+·C7H4ClO2−, the 2-amino-4-methylpyridinium cation is almost planar, with a maximum deviation of 0.010 (1) Å. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms of the anion via a pair of N—H...O hydrogen bonds, forming an R22(8) ring motif. The ion pairs are further connected via N—H...O and C—H...O hydrogen bonds, forming a two-dimensional network parallel to the bc plane. |
| first_indexed | 2024-12-20T08:45:50Z |
| format | Article |
| id | doaj.art-58c77da5aae3485194f08fec8f6578b1 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T08:45:50Z |
| publishDate | 2010-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-58c77da5aae3485194f08fec8f6578b12022-12-21T19:46:16ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667o1843o184410.1107/S160053681002444X2-Amino-4-methylpyridinium 3-chlorobenzoateMadhukar HemamaliniHoong-Kun FunIn the title salt, C6H9N2+·C7H4ClO2−, the 2-amino-4-methylpyridinium cation is almost planar, with a maximum deviation of 0.010 (1) Å. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms of the anion via a pair of N—H...O hydrogen bonds, forming an R22(8) ring motif. The ion pairs are further connected via N—H...O and C—H...O hydrogen bonds, forming a two-dimensional network parallel to the bc plane.http://scripts.iucr.org/cgi-bin/paper?S160053681002444X |
| spellingShingle | Madhukar Hemamalini Hoong-Kun Fun 2-Amino-4-methylpyridinium 3-chlorobenzoate Acta Crystallographica Section E |
| title | 2-Amino-4-methylpyridinium 3-chlorobenzoate |
| title_full | 2-Amino-4-methylpyridinium 3-chlorobenzoate |
| title_fullStr | 2-Amino-4-methylpyridinium 3-chlorobenzoate |
| title_full_unstemmed | 2-Amino-4-methylpyridinium 3-chlorobenzoate |
| title_short | 2-Amino-4-methylpyridinium 3-chlorobenzoate |
| title_sort | 2 amino 4 methylpyridinium 3 chlorobenzoate |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681002444X |
| work_keys_str_mv | AT madhukarhemamalini 2amino4methylpyridinium3chlorobenzoate AT hoongkunfun 2amino4methylpyridinium3chlorobenzoate |