DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY
Five new oxalato, hydrogenoxalato and hydrogenocarbonato adducts (three) and complexes (two) obtained on allowing (Et3NH)HC2O4 or (Et3NH)2C2O4 to react with SnPh3Cl have been studied by infrared spectroscopy, then discrete structures suggested on the basis of spectroscopic data. The anions behave a...
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| Format: | Article |
| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2017-06-01
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| Series: | Journal of Engineering Studies and Research |
| Subjects: | |
| Online Access: | https://jesr.ub.ro/1/article/view/84 |
| _version_ | 1797202249816997888 |
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| author | GORGUI AWA SECK LIBASSE DIOP ABOUBACARY SENE |
| author_facet | GORGUI AWA SECK LIBASSE DIOP ABOUBACARY SENE |
| author_sort | GORGUI AWA SECK |
| collection | DOAJ |
| description |
Five new oxalato, hydrogenoxalato and hydrogenocarbonato adducts (three) and complexes (two) obtained on allowing (Et3NH)HC2O4 or (Et3NH)2C2O4 to react with SnPh3Cl have been studied by infrared spectroscopy, then discrete structures suggested on the basis of spectroscopic data. The anions behave as monochelating ligands, the environments around the metallic centres being octahedral. In two of the compounds, the benzene molecules obtained in situ are lattice. In all these structures when considering the cation involved in extra hydrogen bonds, a supramolecular architecture may be obtained.
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| first_indexed | 2024-03-07T17:27:06Z |
| format | Article |
| id | doaj.art-58d7eb556c93446a96dfe35856a88ac5 |
| institution | Directory Open Access Journal |
| issn | 2068-7559 2344-4932 |
| language | English |
| last_indexed | 2024-04-24T08:00:27Z |
| publishDate | 2017-06-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Journal of Engineering Studies and Research |
| spelling | doaj.art-58d7eb556c93446a96dfe35856a88ac52024-04-17T19:35:41ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauJournal of Engineering Studies and Research2068-75592344-49322017-06-01232DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDYGORGUI AWA SECK0LIBASSE DIOP1ABOUBACARY SENE2Universite Cheikh Anta Diop, Faculté des Sciences et Techniques- Département de Chimie, Laboratoire de Chimie Minérale et Analytique, DAKAR, SénégalUniversite Cheikh Anta Diop, Faculté des Sciences et Techniques- Département de Chimie, Laboratoire de Chimie Minérale et Analytique, DAKAR, SénégalUniversite Cheikh Anta Diop, Faculté des Sciences et Techniques- Département de Chimie, Laboratoire de Chimie Minérale et Analytique, DAKAR, Sénégal Five new oxalato, hydrogenoxalato and hydrogenocarbonato adducts (three) and complexes (two) obtained on allowing (Et3NH)HC2O4 or (Et3NH)2C2O4 to react with SnPh3Cl have been studied by infrared spectroscopy, then discrete structures suggested on the basis of spectroscopic data. The anions behave as monochelating ligands, the environments around the metallic centres being octahedral. In two of the compounds, the benzene molecules obtained in situ are lattice. In all these structures when considering the cation involved in extra hydrogen bonds, a supramolecular architecture may be obtained. https://jesr.ub.ro/1/article/view/84discrete structureshydrogen bondsIR techniclattice benzene moleculesmonochelating oxoanionsoctahedral environments |
| spellingShingle | GORGUI AWA SECK LIBASSE DIOP ABOUBACARY SENE DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY Journal of Engineering Studies and Research discrete structures hydrogen bonds IR technic lattice benzene molecules monochelating oxoanions octahedral environments |
| title | DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY |
| title_full | DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY |
| title_fullStr | DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY |
| title_full_unstemmed | DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY |
| title_short | DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY |
| title_sort | dearylation in the interactions between et3nh hc2o4 or et3nh 2c2o4 and snph3cl infrared study |
| topic | discrete structures hydrogen bonds IR technic lattice benzene molecules monochelating oxoanions octahedral environments |
| url | https://jesr.ub.ro/1/article/view/84 |
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