Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodophenyl)imino]methyl}-4-nitrophenol
The title compound, C13H9IN2O3, was synthesized by a condensation reaction between 2-hydroxy-5-nitrobenzaldehyde and 4-iodoaniline, and crystallizes in the orthorhombic space group Pna21. The 4-iodobenzene ring is inclined to the phenol ring by a dihedral angle of 39.1 (2)°. The configuration about...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2020-07-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989020008191 |
| _version_ | 1819291593236021248 |
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| author | Md. Serajul Haque Faizi Tenzile Alagöz Ruby Ahmed Emine Berrin Cinar Erbil Agar Necmi Dege Ashraf Mashrai |
| author_facet | Md. Serajul Haque Faizi Tenzile Alagöz Ruby Ahmed Emine Berrin Cinar Erbil Agar Necmi Dege Ashraf Mashrai |
| author_sort | Md. Serajul Haque Faizi |
| collection | DOAJ |
| description | The title compound, C13H9IN2O3, was synthesized by a condensation reaction between 2-hydroxy-5-nitrobenzaldehyde and 4-iodoaniline, and crystallizes in the orthorhombic space group Pna21. The 4-iodobenzene ring is inclined to the phenol ring by a dihedral angle of 39.1 (2)°. The configuration about the C=N double bond is E. The crystal structure features C—H...O hydrogen-bonding interactions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the packing arrangement are O...H/H...O (26.9%) and H...H (22.0%) interactions. |
| first_indexed | 2024-12-24T03:41:06Z |
| format | Article |
| id | doaj.art-58e2612710344e99ab1ac7aaee5931fd |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-24T03:41:06Z |
| publishDate | 2020-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-58e2612710344e99ab1ac7aaee5931fd2022-12-21T17:16:53ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902020-07-017671146114910.1107/S2056989020008191pk2635Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodophenyl)imino]methyl}-4-nitrophenolMd. Serajul Haque Faizi0Tenzile Alagöz1Ruby Ahmed2Emine Berrin Cinar3Erbil Agar4Necmi Dege5Ashraf Mashrai6PG Department of Chemistry, Langat Singh College, B. R. A. Bihar University, Muzaffarpur, Bihar 842001, IndiaOndokuz Mayıs University, Faculty of Arts and Sciences, Department of Chemistry, Samsun, TurkeyDepartment of Applied Chemistry, ZHCET, Aligarh Muslim University, Aligarh, 202002, UP, IndiaOndokuz Mayıs University, Faculty of Arts and Sciences, Department of Physics, Samsun, TurkeyOndokuz Mayıs University, Faculty of Arts and Sciences, Department of Chemistry, Samsun, TurkeyOndokuz Mayıs University, Faculty of Arts and Sciences, Department of Physics, Samsun, TurkeyDepartment of Pharmacy, University of Science and Technology, Ibb Branch, Ibb, YemenThe title compound, C13H9IN2O3, was synthesized by a condensation reaction between 2-hydroxy-5-nitrobenzaldehyde and 4-iodoaniline, and crystallizes in the orthorhombic space group Pna21. The 4-iodobenzene ring is inclined to the phenol ring by a dihedral angle of 39.1 (2)°. The configuration about the C=N double bond is E. The crystal structure features C—H...O hydrogen-bonding interactions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the packing arrangement are O...H/H...O (26.9%) and H...H (22.0%) interactions.http://scripts.iucr.org/cgi-bin/paper?S2056989020008191crystal structuresalicylaldehyde derivative4-iodoaniline2-hydroxy-5-nitrobenzaldehydehydrogen bonding |
| spellingShingle | Md. Serajul Haque Faizi Tenzile Alagöz Ruby Ahmed Emine Berrin Cinar Erbil Agar Necmi Dege Ashraf Mashrai Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodophenyl)imino]methyl}-4-nitrophenol Acta Crystallographica Section E: Crystallographic Communications crystal structure salicylaldehyde derivative 4-iodoaniline 2-hydroxy-5-nitrobenzaldehyde hydrogen bonding |
| title | Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodophenyl)imino]methyl}-4-nitrophenol |
| title_full | Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodophenyl)imino]methyl}-4-nitrophenol |
| title_fullStr | Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodophenyl)imino]methyl}-4-nitrophenol |
| title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodophenyl)imino]methyl}-4-nitrophenol |
| title_short | Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodophenyl)imino]methyl}-4-nitrophenol |
| title_sort | crystal structure and hirshfeld surface analysis of 2 4 iodophenyl imino methyl 4 nitrophenol |
| topic | crystal structure salicylaldehyde derivative 4-iodoaniline 2-hydroxy-5-nitrobenzaldehyde hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989020008191 |
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