Oxidants Emergence under Dual-Frequency Sonication within Single Acoustic Bubble: Effects of Frequency Combinations

The sonochemical activity of an oxygen bubble formed in an aqueous medium and oscillating under a dual-frequency excitation is studied in this paper. Several couples of frequencies are formed amongst 35, 140, 300, and 515 kHz, with a maximum acoustic amplitude of 1.5 atm. The molar yields of the eme...

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Main Authors: Kaouther Kerboua, Oualid Hamdaoui
Format: Article
Language:English
Published: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 2021-02-01
Series:Iranian Journal of Chemistry & Chemical Engineering
Subjects:
Online Access:http://www.ijcce.ac.ir/article_36705_95340ebbebcb35800ef1b1efaee2c08b.pdf
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author Kaouther Kerboua
Oualid Hamdaoui
author_facet Kaouther Kerboua
Oualid Hamdaoui
author_sort Kaouther Kerboua
collection DOAJ
description The sonochemical activity of an oxygen bubble formed in an aqueous medium and oscillating under a dual-frequency excitation is studied in this paper. Several couples of frequencies are formed amongst 35, 140, 300, and 515 kHz, with a maximum acoustic amplitude of 1.5 atm. The molar yields of the emerging oxidants are analyzed in accordance with the combined frequencies and compared to the cases of mono-frequency excitations of similar maximum amplitude, i.e., 1.5 atm. Qualitatively, passing from a mono to a dual-frequency excitation demonstrated to be with no effect on the predominant species which remain, and. However, the results exhibited a very selective quantitative evolution depending on the combined frequencies. Some couples proved to induce a negative effect and reduce the production at the single bubble level, particularly with basic frequencies of 140 and 300 kHz, while some others demonstrated a noticeable enhancement such as the couples (35, 140 kHz) and (515, 35 kHz), as compared to mono-frequency fields.
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spelling doaj.art-58ed25bb397b4e3caf014d413dca82442022-12-21T20:11:31ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering1021-99861021-99862021-02-0140132333210.30492/ijcce.2019.3670536705Oxidants Emergence under Dual-Frequency Sonication within Single Acoustic Bubble: Effects of Frequency CombinationsKaouther Kerboua0Oualid Hamdaoui1Laboratory of Environmental Engineering, Department of Process Engineering, Faculty of Engineering, Badji Mokhtar - Annaba University, P.O. Box 12, 23000 Annaba, ALGERIALaboratory of Environmental Engineering, Department of Process Engineering, Faculty of Engineering, Badji Mokhtar - Annaba University, P.O. Box 12, 23000 Annaba, ALGERIAThe sonochemical activity of an oxygen bubble formed in an aqueous medium and oscillating under a dual-frequency excitation is studied in this paper. Several couples of frequencies are formed amongst 35, 140, 300, and 515 kHz, with a maximum acoustic amplitude of 1.5 atm. The molar yields of the emerging oxidants are analyzed in accordance with the combined frequencies and compared to the cases of mono-frequency excitations of similar maximum amplitude, i.e., 1.5 atm. Qualitatively, passing from a mono to a dual-frequency excitation demonstrated to be with no effect on the predominant species which remain, and. However, the results exhibited a very selective quantitative evolution depending on the combined frequencies. Some couples proved to induce a negative effect and reduce the production at the single bubble level, particularly with basic frequencies of 140 and 300 kHz, while some others demonstrated a noticeable enhancement such as the couples (35, 140 kHz) and (515, 35 kHz), as compared to mono-frequency fields.http://www.ijcce.ac.ir/article_36705_95340ebbebcb35800ef1b1efaee2c08b.pdfdual-frequencyoxidantssonochemical activityacoustic cavitation bubblekinetics
spellingShingle Kaouther Kerboua
Oualid Hamdaoui
Oxidants Emergence under Dual-Frequency Sonication within Single Acoustic Bubble: Effects of Frequency Combinations
Iranian Journal of Chemistry & Chemical Engineering
dual-frequency
oxidants
sonochemical activity
acoustic cavitation bubble
kinetics
title Oxidants Emergence under Dual-Frequency Sonication within Single Acoustic Bubble: Effects of Frequency Combinations
title_full Oxidants Emergence under Dual-Frequency Sonication within Single Acoustic Bubble: Effects of Frequency Combinations
title_fullStr Oxidants Emergence under Dual-Frequency Sonication within Single Acoustic Bubble: Effects of Frequency Combinations
title_full_unstemmed Oxidants Emergence under Dual-Frequency Sonication within Single Acoustic Bubble: Effects of Frequency Combinations
title_short Oxidants Emergence under Dual-Frequency Sonication within Single Acoustic Bubble: Effects of Frequency Combinations
title_sort oxidants emergence under dual frequency sonication within single acoustic bubble effects of frequency combinations
topic dual-frequency
oxidants
sonochemical activity
acoustic cavitation bubble
kinetics
url http://www.ijcce.ac.ir/article_36705_95340ebbebcb35800ef1b1efaee2c08b.pdf
work_keys_str_mv AT kaoutherkerboua oxidantsemergenceunderdualfrequencysonicationwithinsingleacousticbubbleeffectsoffrequencycombinations
AT oualidhamdaoui oxidantsemergenceunderdualfrequencysonicationwithinsingleacousticbubbleeffectsoffrequencycombinations