A Multifunctional Dual-Luminescent Polyoxometalate@Metal-Organic Framework EuW10@UiO-67 Composite as Chemical Probe and Temperature Sensor
The luminescent [EuW10O36]9− polyoxometalate has been introduced into the cavities of the highly porous zirconium luminescent metal-organic framework UiO-67 via a direct synthesis approach, affording the EuW10@UiO-67 hybrid. Using a combination of techniques (TGA, BET, elemental analysis, EDX mappin...
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Frontiers Media S.A.
2018-09-01
|
| Series: | Frontiers in Chemistry |
| Subjects: | |
| Online Access: | https://www.frontiersin.org/article/10.3389/fchem.2018.00425/full |
| _version_ | 1818808431717384192 |
|---|---|
| author | William Salomon Anne Dolbecq Catherine Roch-Marchal Grégoire Paille Grégoire Paille Rémi Dessapt Pierre Mialane Hélène Serier-Brault |
| author_facet | William Salomon Anne Dolbecq Catherine Roch-Marchal Grégoire Paille Grégoire Paille Rémi Dessapt Pierre Mialane Hélène Serier-Brault |
| author_sort | William Salomon |
| collection | DOAJ |
| description | The luminescent [EuW10O36]9− polyoxometalate has been introduced into the cavities of the highly porous zirconium luminescent metal-organic framework UiO-67 via a direct synthesis approach, affording the EuW10@UiO-67 hybrid. Using a combination of techniques (TGA, BET, elemental analysis, EDX mapping,…) this new material has been fully characterized, evidencing that it contains only 0.25% in europium and that the polyoxometalate units are located inside the octahedral cavities and not at the surface of the UiO-67 crystallites. Despite the low amount of europium, it is shown that EuW10@UiO-67 acts as a solid-state luminescent sensor for the detection of amino-acids, the growth of the emission intensity globally following the growth of the amino-acid pKa. In addition, EuW10@UiO-67 acts as a sensor for the detection of metallic cations, with a high sensitivity for Fe3+. Noticeably, the recyclability of the reported material has been established. Finally, it is shown that the dual-luminescent EuW10@UiO-67 material behave as a self-calibrated-ratiometric thermometer in the physiological range. |
| first_indexed | 2024-12-18T19:41:27Z |
| format | Article |
| id | doaj.art-58faa83debbf44609468332a589f1494 |
| institution | Directory Open Access Journal |
| issn | 2296-2646 |
| language | English |
| last_indexed | 2024-12-18T19:41:27Z |
| publishDate | 2018-09-01 |
| publisher | Frontiers Media S.A. |
| record_format | Article |
| series | Frontiers in Chemistry |
| spelling | doaj.art-58faa83debbf44609468332a589f14942022-12-21T20:55:25ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462018-09-01610.3389/fchem.2018.00425410815A Multifunctional Dual-Luminescent Polyoxometalate@Metal-Organic Framework EuW10@UiO-67 Composite as Chemical Probe and Temperature SensorWilliam Salomon0Anne Dolbecq1Catherine Roch-Marchal2Grégoire Paille3Grégoire Paille4Rémi Dessapt5Pierre Mialane6Hélène Serier-Brault7Institut Lavoisier de Versailles, UMR CNRS 8180, Université Paris-Saclay, Université de Versailles Saint-Quentin, Versailles, FranceInstitut Lavoisier de Versailles, UMR CNRS 8180, Université Paris-Saclay, Université de Versailles Saint-Quentin, Versailles, FranceInstitut Lavoisier de Versailles, UMR CNRS 8180, Université Paris-Saclay, Université de Versailles Saint-Quentin, Versailles, FranceInstitut Lavoisier de Versailles, UMR CNRS 8180, Université Paris-Saclay, Université de Versailles Saint-Quentin, Versailles, FranceLaboratoire de Chimie des Processus Biologiques, UMR CNRS 8229, Collège de France, Université Pierre et Marie Curie, PSL Research University, Paris, FranceInstitut des Matériaux Jean Rouxel, CNRS, Université de Nantes, Nantes, FranceInstitut Lavoisier de Versailles, UMR CNRS 8180, Université Paris-Saclay, Université de Versailles Saint-Quentin, Versailles, FranceInstitut des Matériaux Jean Rouxel, CNRS, Université de Nantes, Nantes, FranceThe luminescent [EuW10O36]9− polyoxometalate has been introduced into the cavities of the highly porous zirconium luminescent metal-organic framework UiO-67 via a direct synthesis approach, affording the EuW10@UiO-67 hybrid. Using a combination of techniques (TGA, BET, elemental analysis, EDX mapping,…) this new material has been fully characterized, evidencing that it contains only 0.25% in europium and that the polyoxometalate units are located inside the octahedral cavities and not at the surface of the UiO-67 crystallites. Despite the low amount of europium, it is shown that EuW10@UiO-67 acts as a solid-state luminescent sensor for the detection of amino-acids, the growth of the emission intensity globally following the growth of the amino-acid pKa. In addition, EuW10@UiO-67 acts as a sensor for the detection of metallic cations, with a high sensitivity for Fe3+. Noticeably, the recyclability of the reported material has been established. Finally, it is shown that the dual-luminescent EuW10@UiO-67 material behave as a self-calibrated-ratiometric thermometer in the physiological range.https://www.frontiersin.org/article/10.3389/fchem.2018.00425/fullpolyoxometalatemetal-organic frameworksensorratiometric luminescent thermometereuropium |
| spellingShingle | William Salomon Anne Dolbecq Catherine Roch-Marchal Grégoire Paille Grégoire Paille Rémi Dessapt Pierre Mialane Hélène Serier-Brault A Multifunctional Dual-Luminescent Polyoxometalate@Metal-Organic Framework EuW10@UiO-67 Composite as Chemical Probe and Temperature Sensor Frontiers in Chemistry polyoxometalate metal-organic framework sensor ratiometric luminescent thermometer europium |
| title | A Multifunctional Dual-Luminescent Polyoxometalate@Metal-Organic Framework EuW10@UiO-67 Composite as Chemical Probe and Temperature Sensor |
| title_full | A Multifunctional Dual-Luminescent Polyoxometalate@Metal-Organic Framework EuW10@UiO-67 Composite as Chemical Probe and Temperature Sensor |
| title_fullStr | A Multifunctional Dual-Luminescent Polyoxometalate@Metal-Organic Framework EuW10@UiO-67 Composite as Chemical Probe and Temperature Sensor |
| title_full_unstemmed | A Multifunctional Dual-Luminescent Polyoxometalate@Metal-Organic Framework EuW10@UiO-67 Composite as Chemical Probe and Temperature Sensor |
| title_short | A Multifunctional Dual-Luminescent Polyoxometalate@Metal-Organic Framework EuW10@UiO-67 Composite as Chemical Probe and Temperature Sensor |
| title_sort | multifunctional dual luminescent polyoxometalate metal organic framework euw10 uio 67 composite as chemical probe and temperature sensor |
| topic | polyoxometalate metal-organic framework sensor ratiometric luminescent thermometer europium |
| url | https://www.frontiersin.org/article/10.3389/fchem.2018.00425/full |
| work_keys_str_mv | AT williamsalomon amultifunctionaldualluminescentpolyoxometalatemetalorganicframeworkeuw10uio67compositeaschemicalprobeandtemperaturesensor AT annedolbecq amultifunctionaldualluminescentpolyoxometalatemetalorganicframeworkeuw10uio67compositeaschemicalprobeandtemperaturesensor AT catherinerochmarchal amultifunctionaldualluminescentpolyoxometalatemetalorganicframeworkeuw10uio67compositeaschemicalprobeandtemperaturesensor AT gregoirepaille amultifunctionaldualluminescentpolyoxometalatemetalorganicframeworkeuw10uio67compositeaschemicalprobeandtemperaturesensor AT gregoirepaille amultifunctionaldualluminescentpolyoxometalatemetalorganicframeworkeuw10uio67compositeaschemicalprobeandtemperaturesensor AT remidessapt amultifunctionaldualluminescentpolyoxometalatemetalorganicframeworkeuw10uio67compositeaschemicalprobeandtemperaturesensor AT pierremialane amultifunctionaldualluminescentpolyoxometalatemetalorganicframeworkeuw10uio67compositeaschemicalprobeandtemperaturesensor AT heleneserierbrault amultifunctionaldualluminescentpolyoxometalatemetalorganicframeworkeuw10uio67compositeaschemicalprobeandtemperaturesensor AT williamsalomon multifunctionaldualluminescentpolyoxometalatemetalorganicframeworkeuw10uio67compositeaschemicalprobeandtemperaturesensor AT annedolbecq multifunctionaldualluminescentpolyoxometalatemetalorganicframeworkeuw10uio67compositeaschemicalprobeandtemperaturesensor AT catherinerochmarchal multifunctionaldualluminescentpolyoxometalatemetalorganicframeworkeuw10uio67compositeaschemicalprobeandtemperaturesensor AT gregoirepaille multifunctionaldualluminescentpolyoxometalatemetalorganicframeworkeuw10uio67compositeaschemicalprobeandtemperaturesensor AT gregoirepaille multifunctionaldualluminescentpolyoxometalatemetalorganicframeworkeuw10uio67compositeaschemicalprobeandtemperaturesensor AT remidessapt multifunctionaldualluminescentpolyoxometalatemetalorganicframeworkeuw10uio67compositeaschemicalprobeandtemperaturesensor AT pierremialane multifunctionaldualluminescentpolyoxometalatemetalorganicframeworkeuw10uio67compositeaschemicalprobeandtemperaturesensor AT heleneserierbrault multifunctionaldualluminescentpolyoxometalatemetalorganicframeworkeuw10uio67compositeaschemicalprobeandtemperaturesensor |