BiVO<sub>4</sub>-Based Magnetic Heterostructures as Photocatalysts for Degradation of Antibiotics in Water

Bismuth vanadate (BiVO<sub>4</sub>) has been investigated as a photocatalyst of great interest due to its ability to harvest photons efficiently in the visible spectral region. In addition, powdered BiVO<sub>4</sub> shows high photochemical stability, good dispersibility, and...

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Main Authors: Ana C. Estrada, Filipa Pinto, Cláudia B. Lopes, Tito Trindade
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Materials Proceedings
Subjects:
Online Access:https://www.mdpi.com/2673-4605/14/1/49
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author Ana C. Estrada
Filipa Pinto
Cláudia B. Lopes
Tito Trindade
author_facet Ana C. Estrada
Filipa Pinto
Cláudia B. Lopes
Tito Trindade
author_sort Ana C. Estrada
collection DOAJ
description Bismuth vanadate (BiVO<sub>4</sub>) has been investigated as a photocatalyst of great interest due to its ability to harvest photons efficiently in the visible spectral region. In addition, powdered BiVO<sub>4</sub> shows high photochemical stability, good dispersibility, and resistance to corrosion in oxidative conditions. Herein, we report the synthesis of monoclinic or tetragonal BiVO<sub>4</sub> particles using different methods, as well as the synthesis of hybrids materials through the combination of cobalt ferrite (CoFe<sub>2</sub>O<sub>4</sub>) and BiVO<sub>4</sub>, and their application in the photodegradation of aqueous solutions of sulfamethoxazole (SMX) under simulated solar radiation. We demonstrate that high-crystallinity single-phase monoclinic BiVO<sub>4</sub> was synthesized fast and efficiently using a solid-state method and, in combination with magnetic CoFe<sub>2</sub>O<sub>4</sub> particles, gives rise to a hybrid material that can be easily separated from the reaction medium, by applying an external magnetic field, without the need for further downstream treatments.
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spelling doaj.art-59317936530043c4a7ed3d4e1a1f26612023-11-19T11:46:59ZengMDPI AGMaterials Proceedings2673-46052023-05-011414910.3390/IOCN2023-14532BiVO<sub>4</sub>-Based Magnetic Heterostructures as Photocatalysts for Degradation of Antibiotics in WaterAna C. Estrada0Filipa Pinto1Cláudia B. Lopes2Tito Trindade3CICECO-Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalCICECO-Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalCICECO-Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalCICECO-Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalBismuth vanadate (BiVO<sub>4</sub>) has been investigated as a photocatalyst of great interest due to its ability to harvest photons efficiently in the visible spectral region. In addition, powdered BiVO<sub>4</sub> shows high photochemical stability, good dispersibility, and resistance to corrosion in oxidative conditions. Herein, we report the synthesis of monoclinic or tetragonal BiVO<sub>4</sub> particles using different methods, as well as the synthesis of hybrids materials through the combination of cobalt ferrite (CoFe<sub>2</sub>O<sub>4</sub>) and BiVO<sub>4</sub>, and their application in the photodegradation of aqueous solutions of sulfamethoxazole (SMX) under simulated solar radiation. We demonstrate that high-crystallinity single-phase monoclinic BiVO<sub>4</sub> was synthesized fast and efficiently using a solid-state method and, in combination with magnetic CoFe<sub>2</sub>O<sub>4</sub> particles, gives rise to a hybrid material that can be easily separated from the reaction medium, by applying an external magnetic field, without the need for further downstream treatments.https://www.mdpi.com/2673-4605/14/1/49bismuth vanadatemagnetic photocatalystssolar lightwater remediation
spellingShingle Ana C. Estrada
Filipa Pinto
Cláudia B. Lopes
Tito Trindade
BiVO<sub>4</sub>-Based Magnetic Heterostructures as Photocatalysts for Degradation of Antibiotics in Water
Materials Proceedings
bismuth vanadate
magnetic photocatalysts
solar light
water remediation
title BiVO<sub>4</sub>-Based Magnetic Heterostructures as Photocatalysts for Degradation of Antibiotics in Water
title_full BiVO<sub>4</sub>-Based Magnetic Heterostructures as Photocatalysts for Degradation of Antibiotics in Water
title_fullStr BiVO<sub>4</sub>-Based Magnetic Heterostructures as Photocatalysts for Degradation of Antibiotics in Water
title_full_unstemmed BiVO<sub>4</sub>-Based Magnetic Heterostructures as Photocatalysts for Degradation of Antibiotics in Water
title_short BiVO<sub>4</sub>-Based Magnetic Heterostructures as Photocatalysts for Degradation of Antibiotics in Water
title_sort bivo sub 4 sub based magnetic heterostructures as photocatalysts for degradation of antibiotics in water
topic bismuth vanadate
magnetic photocatalysts
solar light
water remediation
url https://www.mdpi.com/2673-4605/14/1/49
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AT filipapinto bivosub4subbasedmagneticheterostructuresasphotocatalystsfordegradationofantibioticsinwater
AT claudiablopes bivosub4subbasedmagneticheterostructuresasphotocatalystsfordegradationofantibioticsinwater
AT titotrindade bivosub4subbasedmagneticheterostructuresasphotocatalystsfordegradationofantibioticsinwater