Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria
Precise control over the energy of atomic metal sites is key to unlocking novel reaction pathways. Here, the authors achieve selective oxygen activation by the isolated copper site on ceria, due to its reduced 3d orbital energy via cerium induced electron withdrawing effect.
| Main Authors: | , , , , , , , , , , , , , , , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2020-08-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-020-17852-8 |
| _version_ | 1830208000131858432 |
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| author | Liqun Kang Bolun Wang Qiming Bing Michal Zalibera Robert Büchel Ruoyu Xu Qiming Wang Yiyun Liu Diego Gianolio Chiu C. Tang Emma K. Gibson Mohsen Danaie Christopher Allen Ke Wu Sushila Marlow Ling-dong Sun Qian He Shaoliang Guan Anton Savitsky Juan J. Velasco-Vélez June Callison Christopher W. M. Kay Sotiris E. Pratsinis Wolfgang Lubitz Jing-yao Liu Feng Ryan Wang |
| author_facet | Liqun Kang Bolun Wang Qiming Bing Michal Zalibera Robert Büchel Ruoyu Xu Qiming Wang Yiyun Liu Diego Gianolio Chiu C. Tang Emma K. Gibson Mohsen Danaie Christopher Allen Ke Wu Sushila Marlow Ling-dong Sun Qian He Shaoliang Guan Anton Savitsky Juan J. Velasco-Vélez June Callison Christopher W. M. Kay Sotiris E. Pratsinis Wolfgang Lubitz Jing-yao Liu Feng Ryan Wang |
| author_sort | Liqun Kang |
| collection | DOAJ |
| description | Precise control over the energy of atomic metal sites is key to unlocking novel reaction pathways. Here, the authors achieve selective oxygen activation by the isolated copper site on ceria, due to its reduced 3d orbital energy via cerium induced electron withdrawing effect. |
| first_indexed | 2024-12-18T04:40:35Z |
| format | Article |
| id | doaj.art-593891f1285948d782bf697a7f1d964b |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-18T04:40:35Z |
| publishDate | 2020-08-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-593891f1285948d782bf697a7f1d964b2022-12-21T21:20:43ZengNature PortfolioNature Communications2041-17232020-08-0111111110.1038/s41467-020-17852-8Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceriaLiqun Kang0Bolun Wang1Qiming Bing2Michal Zalibera3Robert Büchel4Ruoyu Xu5Qiming Wang6Yiyun Liu7Diego Gianolio8Chiu C. Tang9Emma K. Gibson10Mohsen Danaie11Christopher Allen12Ke Wu13Sushila Marlow14Ling-dong Sun15Qian He16Shaoliang Guan17Anton Savitsky18Juan J. Velasco-Vélez19June Callison20Christopher W. M. Kay21Sotiris E. Pratsinis22Wolfgang Lubitz23Jing-yao Liu24Feng Ryan Wang25Department of Chemical Engineering, University College London, Roberts Building, Torrington PlaceDepartment of Chemical Engineering, University College London, Roberts Building, Torrington PlaceLaboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, Jilin UniversityInstitute of Physical Chemistry and Chemical Physics, Slovak University of Technology in Bratislava, Faculty of Chemical and Food Technology, Radlinského 9Particle Technology Laboratory, Institute of Process Engineering, Department of Mechanical and Process Engineering, ETH Zürich, 8092Department of Chemical Engineering, University College London, Roberts Building, Torrington PlaceDepartment of Chemical Engineering, University College London, Roberts Building, Torrington PlaceDepartment of Chemical Engineering, University College London, Roberts Building, Torrington PlaceDiamond Light Source Ltd., Harwell Science and Innovation Campus, ChiltonDiamond Light Source Ltd., Harwell Science and Innovation Campus, ChiltonSchool of Chemistry, University of Glasgow, Joseph Black Building. University AvenueElectron Physical Science Imaging Center, Diamond Light Source Ltd.Electron Physical Science Imaging Center, Diamond Light Source Ltd.College of Chemistry and Molecular Engineering, Peking UniversityDepartment of Chemical Engineering, University College London, Roberts Building, Torrington PlaceCollege of Chemistry and Molecular Engineering, Peking UniversityDepartment of Materials Science and Engineering, National University of SingaporeDiamond Light Source Ltd., Harwell Science and Innovation Campus, ChiltonMax-Planck-Institut Für Chemische Energiekonversion, Stiftstrasse 34-36Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6UK Catalysis Hub, Research Complex at Harwell (RCaH), Rutherford Appleton LaboratoryLondon Centre for Nanotechnology, University College LondonParticle Technology Laboratory, Institute of Process Engineering, Department of Mechanical and Process Engineering, ETH Zürich, 8092Max-Planck-Institut Für Chemische Energiekonversion, Stiftstrasse 34-36Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, Jilin UniversityDepartment of Chemical Engineering, University College London, Roberts Building, Torrington PlacePrecise control over the energy of atomic metal sites is key to unlocking novel reaction pathways. Here, the authors achieve selective oxygen activation by the isolated copper site on ceria, due to its reduced 3d orbital energy via cerium induced electron withdrawing effect.https://doi.org/10.1038/s41467-020-17852-8 |
| spellingShingle | Liqun Kang Bolun Wang Qiming Bing Michal Zalibera Robert Büchel Ruoyu Xu Qiming Wang Yiyun Liu Diego Gianolio Chiu C. Tang Emma K. Gibson Mohsen Danaie Christopher Allen Ke Wu Sushila Marlow Ling-dong Sun Qian He Shaoliang Guan Anton Savitsky Juan J. Velasco-Vélez June Callison Christopher W. M. Kay Sotiris E. Pratsinis Wolfgang Lubitz Jing-yao Liu Feng Ryan Wang Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria Nature Communications |
| title | Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria |
| title_full | Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria |
| title_fullStr | Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria |
| title_full_unstemmed | Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria |
| title_short | Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria |
| title_sort | adsorption and activation of molecular oxygen over atomic copper i ii site on ceria |
| url | https://doi.org/10.1038/s41467-020-17852-8 |
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