Optimization and Modeling the Processes of Green Magnetite Nanoparticle: Synthesis, Photo Catalysis Tendency and Kinetics of Removing Organic Dye from Aqueous Solutions

Green magnetite nanoparticles (NPs) are synthesized, characterized and employed for degradation Methylene Blue (MB) from aqueous solutions. The effect of the concentrations of the NPs and MB on NPs yield and removal efficiency is optimized and modeled using two factorial central composite experiment...

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Main Authors: Avan Kareem, Ibtisam Kamal
Format: Article
Language:English
Published: Tishk International University 2023-02-01
Series:Eurasian Journal of Science and Engineering
Subjects:
Online Access:https://eajse.tiu.edu.iq/index.php/volume-9-issue-1-article-6/
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author Avan Kareem
Ibtisam Kamal
author_facet Avan Kareem
Ibtisam Kamal
author_sort Avan Kareem
collection DOAJ
description Green magnetite nanoparticles (NPs) are synthesized, characterized and employed for degradation Methylene Blue (MB) from aqueous solutions. The effect of the concentrations of the NPs and MB on NPs yield and removal efficiency is optimized and modeled using two factorial central composite experimental design. The analysis of variance confirmed that the concentration of iron metal salts seemed more significant than plant extract. The developed mathematical model is estimated with high R2 reflecting its accuracy. The results proved that the removal efficiency of MB increases up to an optimum of 82.07 % when using 0.17 g of the nano photo catalyst versus 10.8 ppm of MB with sunlight irradiation time of 200 min. The dye degradation kinetic results revealed that photo catalytic degradation follow pseudo-first-order model. Response Surface Methodology proved as an efficient tool for optimization and modeling the processes of NPs production and removing of organic pollutants from aqueous solutions.
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spelling doaj.art-59391f97f7984dbaa4ba921f391be33b2023-02-27T08:51:13ZengTishk International UniversityEurasian Journal of Science and Engineering2414-56292414-56022023-02-0191718810.23918/eajse.v9i1p71Optimization and Modeling the Processes of Green Magnetite Nanoparticle: Synthesis, Photo Catalysis Tendency and Kinetics of Removing Organic Dye from Aqueous SolutionsAvan Kareem0Ibtisam Kamal1Chemical Engineering Department, Faculty of Engineering, Soran University, Kurdistan Region, IraqChemical Engineering Department, Faculty of Engineering, Soran University, Kurdistan Region, IraqGreen magnetite nanoparticles (NPs) are synthesized, characterized and employed for degradation Methylene Blue (MB) from aqueous solutions. The effect of the concentrations of the NPs and MB on NPs yield and removal efficiency is optimized and modeled using two factorial central composite experimental design. The analysis of variance confirmed that the concentration of iron metal salts seemed more significant than plant extract. The developed mathematical model is estimated with high R2 reflecting its accuracy. The results proved that the removal efficiency of MB increases up to an optimum of 82.07 % when using 0.17 g of the nano photo catalyst versus 10.8 ppm of MB with sunlight irradiation time of 200 min. The dye degradation kinetic results revealed that photo catalytic degradation follow pseudo-first-order model. Response Surface Methodology proved as an efficient tool for optimization and modeling the processes of NPs production and removing of organic pollutants from aqueous solutions.https://eajse.tiu.edu.iq/index.php/volume-9-issue-1-article-6/green magnetite nanoparticlesmethylene blueremoval efficiencyoptimizationmodelingmetheylen blue degradation rate
spellingShingle Avan Kareem
Ibtisam Kamal
Optimization and Modeling the Processes of Green Magnetite Nanoparticle: Synthesis, Photo Catalysis Tendency and Kinetics of Removing Organic Dye from Aqueous Solutions
Eurasian Journal of Science and Engineering
green magnetite nanoparticles
methylene blue
removal efficiency
optimization
modeling
metheylen blue degradation rate
title Optimization and Modeling the Processes of Green Magnetite Nanoparticle: Synthesis, Photo Catalysis Tendency and Kinetics of Removing Organic Dye from Aqueous Solutions
title_full Optimization and Modeling the Processes of Green Magnetite Nanoparticle: Synthesis, Photo Catalysis Tendency and Kinetics of Removing Organic Dye from Aqueous Solutions
title_fullStr Optimization and Modeling the Processes of Green Magnetite Nanoparticle: Synthesis, Photo Catalysis Tendency and Kinetics of Removing Organic Dye from Aqueous Solutions
title_full_unstemmed Optimization and Modeling the Processes of Green Magnetite Nanoparticle: Synthesis, Photo Catalysis Tendency and Kinetics of Removing Organic Dye from Aqueous Solutions
title_short Optimization and Modeling the Processes of Green Magnetite Nanoparticle: Synthesis, Photo Catalysis Tendency and Kinetics of Removing Organic Dye from Aqueous Solutions
title_sort optimization and modeling the processes of green magnetite nanoparticle synthesis photo catalysis tendency and kinetics of removing organic dye from aqueous solutions
topic green magnetite nanoparticles
methylene blue
removal efficiency
optimization
modeling
metheylen blue degradation rate
url https://eajse.tiu.edu.iq/index.php/volume-9-issue-1-article-6/
work_keys_str_mv AT avankareem optimizationandmodelingtheprocessesofgreenmagnetitenanoparticlesynthesisphotocatalysistendencyandkineticsofremovingorganicdyefromaqueoussolutions
AT ibtisamkamal optimizationandmodelingtheprocessesofgreenmagnetitenanoparticlesynthesisphotocatalysistendencyandkineticsofremovingorganicdyefromaqueoussolutions