[N-Benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV) and [bis(2-methoxyethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV): crystal structures and Hirshfeld surface analysis
The crystal and molecular structures of two triphenyltin dithiocarbamates, [Sn(C6H5)3(C16H16NS2)], (I), and [Sn(C6H5)3(C7H14NO2S2)], (II), are described. In (I), the dithiocarbamate ligand coordinates the SnIV atom in an asymmetric manner, leading to a highly distorted trigonal–bipyramidal coordinat...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-10-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016014985 |
| _version_ | 1819003043112288256 |
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| author | Rapidah Mohamad Normah Awang Nurul Farahana Kamaludin Mukesh M. Jotani Edward R. T. Tiekink |
| author_facet | Rapidah Mohamad Normah Awang Nurul Farahana Kamaludin Mukesh M. Jotani Edward R. T. Tiekink |
| author_sort | Rapidah Mohamad |
| collection | DOAJ |
| description | The crystal and molecular structures of two triphenyltin dithiocarbamates, [Sn(C6H5)3(C16H16NS2)], (I), and [Sn(C6H5)3(C7H14NO2S2)], (II), are described. In (I), the dithiocarbamate ligand coordinates the SnIV atom in an asymmetric manner, leading to a highly distorted trigonal–bipyramidal coordination geometry defined by a C3S2 donor set with the weakly bound S atom approximately trans to one of the ipso-C atoms. A similar structure is found in (II), but the dithiocarbamate ligand coordinates in an even more asymmetric fashion. The packing in (I) features supramolecular chains along the c axis sustained by C—H...π interactions; chains pack with no directional interactions between them. In (II), supramolecular layers are formed, similarly sustained by C—H...π interactions; these stack along the b axis. An analysis of the Hirshfeld surfaces for (I) and (II) confirms the presence of the C—H...π interactions but also reveals the overall dominance of H...H contacts in the respective crystals. |
| first_indexed | 2024-12-20T23:14:43Z |
| format | Article |
| id | doaj.art-59457141e053443693bde03475d7eec8 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-20T23:14:43Z |
| publishDate | 2016-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-59457141e053443693bde03475d7eec82022-12-21T19:23:39ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-10-0172101480148710.1107/S2056989016014985hb7618[N-Benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV) and [bis(2-methoxyethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV): crystal structures and Hirshfeld surface analysisRapidah Mohamad0Normah Awang1Nurul Farahana Kamaludin2Mukesh M. Jotani3Edward R. T. Tiekink4Biomedical Science Programme, School of Diagnostic and Applied Health Sciences, Faculty of Health Sciences, Universiti Kebangsaan Malaysia, Jalan Raja Muda Abdul Aziz, 50300 Kuala Lumpur, MalaysiaEnvironmental Health and Industrial Safety Programme, School of Diagnostic and Applied Health Sciences, Faculty of Health Sciences, Universiti Kebangsaan Malaysia, Jalan Raja Muda Abdul Aziz, 50300 Kuala Lumpur, MalaysiaEnvironmental Health and Industrial Safety Programme, School of Diagnostic and Applied Health Sciences, Faculty of Health Sciences, Universiti Kebangsaan Malaysia, Jalan Raja Muda Abdul Aziz, 50300 Kuala Lumpur, MalaysiaDepartment of Physics, Bhavan's Sheth R. A. College of Science, Ahmedabad, Gujarat 380001, IndiaResearch Centre for Chemical Crystallography, Faculty of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, MalaysiaThe crystal and molecular structures of two triphenyltin dithiocarbamates, [Sn(C6H5)3(C16H16NS2)], (I), and [Sn(C6H5)3(C7H14NO2S2)], (II), are described. In (I), the dithiocarbamate ligand coordinates the SnIV atom in an asymmetric manner, leading to a highly distorted trigonal–bipyramidal coordination geometry defined by a C3S2 donor set with the weakly bound S atom approximately trans to one of the ipso-C atoms. A similar structure is found in (II), but the dithiocarbamate ligand coordinates in an even more asymmetric fashion. The packing in (I) features supramolecular chains along the c axis sustained by C—H...π interactions; chains pack with no directional interactions between them. In (II), supramolecular layers are formed, similarly sustained by C—H...π interactions; these stack along the b axis. An analysis of the Hirshfeld surfaces for (I) and (II) confirms the presence of the C—H...π interactions but also reveals the overall dominance of H...H contacts in the respective crystals.http://scripts.iucr.org/cgi-bin/paper?S2056989016014985crystal structureorganotindithiocarbamateHirshfeld surface analysis |
| spellingShingle | Rapidah Mohamad Normah Awang Nurul Farahana Kamaludin Mukesh M. Jotani Edward R. T. Tiekink [N-Benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV) and [bis(2-methoxyethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV): crystal structures and Hirshfeld surface analysis Acta Crystallographica Section E: Crystallographic Communications crystal structure organotin dithiocarbamate Hirshfeld surface analysis |
| title | [N-Benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV) and [bis(2-methoxyethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV): crystal structures and Hirshfeld surface analysis |
| title_full | [N-Benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV) and [bis(2-methoxyethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV): crystal structures and Hirshfeld surface analysis |
| title_fullStr | [N-Benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV) and [bis(2-methoxyethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV): crystal structures and Hirshfeld surface analysis |
| title_full_unstemmed | [N-Benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV) and [bis(2-methoxyethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV): crystal structures and Hirshfeld surface analysis |
| title_short | [N-Benzyl-N-(2-phenylethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV) and [bis(2-methoxyethyl)dithiocarbamato-κ2S,S′]triphenyltin(IV): crystal structures and Hirshfeld surface analysis |
| title_sort | n benzyl n 2 phenylethyl dithiocarbamato κ2s s triphenyltin iv and bis 2 methoxyethyl dithiocarbamato κ2s s triphenyltin iv crystal structures and hirshfeld surface analysis |
| topic | crystal structure organotin dithiocarbamate Hirshfeld surface analysis |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989016014985 |
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