[μ-Bis(diphenylphosphanyl)ethane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-(triphenylstibine-3κSb)-triangulo-triruthenium(0)
The asymmetric unit of the title triangulo-triruthenium compound, [Ru3(C26H24P2)(C18H15Sb)(CO)9], consists of two crystallographically independent molecules, A and B. The bis(diphenylphosphanyl)ethane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the third Ru...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810054218 |
| _version_ | 1818775495164035072 |
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| author | Omar bin Shawkataly Imthyaz Ahmed Khan Siti Syaida Sirat Chin Sing Yeap Hoong-Kun Fun |
| author_facet | Omar bin Shawkataly Imthyaz Ahmed Khan Siti Syaida Sirat Chin Sing Yeap Hoong-Kun Fun |
| author_sort | Omar bin Shawkataly |
| collection | DOAJ |
| description | The asymmetric unit of the title triangulo-triruthenium compound, [Ru3(C26H24P2)(C18H15Sb)(CO)9], consists of two crystallographically independent molecules, A and B. The bis(diphenylphosphanyl)ethane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the third Ru atom. Both the stibine and phosphine ligands are equatorial with respect to the Ru3 triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three stibine-substituted benzene rings make dihedral angles of 38.7 (3), 71.5 (3) and 70.0 (3)° with each other in molecule A whereas these angles are 83.9 (3), 88.2 (3) and 56.8 (3)° in molecule B. Similarly, the dihedral angles between the two benzene rings are 80.7 (3) and 87.6 (3)° for the two diphenylphosphanyl groups in molecule A and 84.0 (3) and 72.6 (4)° in molecule B. In the crystal, molecules are linked into tetramers via intermolecular C—H...O hydrogen bonds. Weak intermolecular C—H...π interactions further stabilize the crystal structure. |
| first_indexed | 2024-12-18T10:57:57Z |
| format | Article |
| id | doaj.art-5960c1f297814ad384d9e6d00ecb7d07 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T10:57:57Z |
| publishDate | 2011-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-5960c1f297814ad384d9e6d00ecb7d072022-12-21T21:10:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-02-01672m177m17810.1107/S1600536810054218[μ-Bis(diphenylphosphanyl)ethane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-(triphenylstibine-3κSb)-triangulo-triruthenium(0)Omar bin ShawkatalyImthyaz Ahmed KhanSiti Syaida SiratChin Sing YeapHoong-Kun FunThe asymmetric unit of the title triangulo-triruthenium compound, [Ru3(C26H24P2)(C18H15Sb)(CO)9], consists of two crystallographically independent molecules, A and B. The bis(diphenylphosphanyl)ethane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the third Ru atom. Both the stibine and phosphine ligands are equatorial with respect to the Ru3 triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three stibine-substituted benzene rings make dihedral angles of 38.7 (3), 71.5 (3) and 70.0 (3)° with each other in molecule A whereas these angles are 83.9 (3), 88.2 (3) and 56.8 (3)° in molecule B. Similarly, the dihedral angles between the two benzene rings are 80.7 (3) and 87.6 (3)° for the two diphenylphosphanyl groups in molecule A and 84.0 (3) and 72.6 (4)° in molecule B. In the crystal, molecules are linked into tetramers via intermolecular C—H...O hydrogen bonds. Weak intermolecular C—H...π interactions further stabilize the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536810054218 |
| spellingShingle | Omar bin Shawkataly Imthyaz Ahmed Khan Siti Syaida Sirat Chin Sing Yeap Hoong-Kun Fun [μ-Bis(diphenylphosphanyl)ethane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-(triphenylstibine-3κSb)-triangulo-triruthenium(0) Acta Crystallographica Section E |
| title | [μ-Bis(diphenylphosphanyl)ethane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-(triphenylstibine-3κSb)-triangulo-triruthenium(0) |
| title_full | [μ-Bis(diphenylphosphanyl)ethane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-(triphenylstibine-3κSb)-triangulo-triruthenium(0) |
| title_fullStr | [μ-Bis(diphenylphosphanyl)ethane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-(triphenylstibine-3κSb)-triangulo-triruthenium(0) |
| title_full_unstemmed | [μ-Bis(diphenylphosphanyl)ethane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-(triphenylstibine-3κSb)-triangulo-triruthenium(0) |
| title_short | [μ-Bis(diphenylphosphanyl)ethane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-(triphenylstibine-3κSb)-triangulo-triruthenium(0) |
| title_sort | amp 956 bis diphenylphosphanyl ethane 1 2 amp 954 2p p amp 8242 nonacarbonyl 1 amp 954 3c 2 amp 954 3c 3 amp 954 3c triphenylstibine 3 amp 954 sb triangulo triruthenium 0 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810054218 |
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