Digold Phosphinine Complexes Are Stable with a Bis(Phosphinine) Ligand but Not with a 2-Phosphinophosphinine

Digold Phosphinine Complexes Are Stable with a Bis(Phosphinine) Ligand but Not with a 2-Phosphinophosphinine

The reaction of [bis{3-methyl-6-(trimethylsilyl)phosphinine-2-yl}dimethylsilane] (<b>19</b>) with one and two equivalents of [AuCl(tht)] was attempted in order to selectively form the mono and digold species, respectively. The digold species [(AuCl)<sub>2</sub>(<b>19<...

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Bibliographic Details
Main Authors: Peter A. Cleaves, Ben Gourlay, Margot Marseglia, Daniel J. Ward, Stephen M. Mansell
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Inorganics
Subjects:
phosphinine
phosphorus ligands
gold complexes
ligand properties
Online Access:https://www.mdpi.com/2304-6740/10/11/203

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