Water and dissolved gas geochemistry of the monomictic Paterno sinkhole (central Italy)

This paper describes the chemical and isotope features of water and dissolved gases from lake Paterno (max. depth 54 m), a sinkhole located in the NE sector of the S. Vittorino plain (Rieti, Central Italy), where evidences of past and present hydrothermal activity exists. In winter (February 2011) l...

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Main Authors: Matteo Nocentini, Marco Quartararo, Franco Tassi, Orlando Vaselli, Francesco Capecchiacci, Massimiliano Marcelli, Roberto Palozzi, Dmitri Rouwet, Jacopo Cabassi
Format: Article
Language:English
Published: PAGEPress Publications 2012-07-01
Series:Journal of Limnology
Subjects:
Online Access:http://www.jlimnol.it/index.php/jlimnol/article/view/479
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author Matteo Nocentini
Marco Quartararo
Franco Tassi
Orlando Vaselli
Francesco Capecchiacci
Massimiliano Marcelli
Roberto Palozzi
Dmitri Rouwet
Jacopo Cabassi
author_facet Matteo Nocentini
Marco Quartararo
Franco Tassi
Orlando Vaselli
Francesco Capecchiacci
Massimiliano Marcelli
Roberto Palozzi
Dmitri Rouwet
Jacopo Cabassi
author_sort Matteo Nocentini
collection DOAJ
description This paper describes the chemical and isotope features of water and dissolved gases from lake Paterno (max. depth 54 m), a sinkhole located in the NE sector of the S. Vittorino plain (Rieti, Central Italy), where evidences of past and present hydrothermal activity exists. In winter (February 2011) lake Paterno waters were almost completely mixed, whereas in summer time (July 2011) thermal and chemical stratifications established. During the stratification period, water and dissolved gas chemistry along the vertical water column were mainly controlled by biological processes, such as methanogenesis, sulfate-reduction, calcite precipitation, denitrification, and NH4 and H2 production. Reducing conditions at the interface between the bottom sediments and the anoxic waters are responsible for the relatively high concentrations of dissolved iron (Fe) and manganese (Mn), likely present in their reduced oxidation state. Minerogenic and biogenic products were recognized at the lake bottom even during the winter sampling. At relatively shallow depth the distribution of CH4 and CO2 was controlled by methanotrophic bacteria and photosynthesis, respectively. The carbon isotope signature of CO2 indicates a significant contribution of deep-originated inorganic CO2 that is related to the hydrothermal system feeding the CO2-rich mineralized springs discharging in the surrounding areas of lake Paterno. The seasonal lake stratification likely controls the vertical and horizontal distribution of fish populations in the different periods of the year.
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spelling doaj.art-59cf2ff7c23b49b0bce926c8a5e9ae582022-12-22T00:07:50ZengPAGEPress PublicationsJournal of Limnology1129-57671723-86332012-07-01712e27e2710.4081/jlimnol.2012.e27Water and dissolved gas geochemistry of the monomictic Paterno sinkhole (central Italy)Matteo NocentiniMarco QuartararoFranco TassiOrlando VaselliFrancesco CapecchiacciMassimiliano MarcelliRoberto PalozziDmitri RouwetJacopo CabassiThis paper describes the chemical and isotope features of water and dissolved gases from lake Paterno (max. depth 54 m), a sinkhole located in the NE sector of the S. Vittorino plain (Rieti, Central Italy), where evidences of past and present hydrothermal activity exists. In winter (February 2011) lake Paterno waters were almost completely mixed, whereas in summer time (July 2011) thermal and chemical stratifications established. During the stratification period, water and dissolved gas chemistry along the vertical water column were mainly controlled by biological processes, such as methanogenesis, sulfate-reduction, calcite precipitation, denitrification, and NH4 and H2 production. Reducing conditions at the interface between the bottom sediments and the anoxic waters are responsible for the relatively high concentrations of dissolved iron (Fe) and manganese (Mn), likely present in their reduced oxidation state. Minerogenic and biogenic products were recognized at the lake bottom even during the winter sampling. At relatively shallow depth the distribution of CH4 and CO2 was controlled by methanotrophic bacteria and photosynthesis, respectively. The carbon isotope signature of CO2 indicates a significant contribution of deep-originated inorganic CO2 that is related to the hydrothermal system feeding the CO2-rich mineralized springs discharging in the surrounding areas of lake Paterno. The seasonal lake stratification likely controls the vertical and horizontal distribution of fish populations in the different periods of the year.http://www.jlimnol.it/index.php/jlimnol/article/view/479monomictic lake, sinkhole, lake Paterno, water lake chemistry, dissolved gas chemistry.
spellingShingle Matteo Nocentini
Marco Quartararo
Franco Tassi
Orlando Vaselli
Francesco Capecchiacci
Massimiliano Marcelli
Roberto Palozzi
Dmitri Rouwet
Jacopo Cabassi
Water and dissolved gas geochemistry of the monomictic Paterno sinkhole (central Italy)
Journal of Limnology
monomictic lake, sinkhole, lake Paterno, water lake chemistry, dissolved gas chemistry.
title Water and dissolved gas geochemistry of the monomictic Paterno sinkhole (central Italy)
title_full Water and dissolved gas geochemistry of the monomictic Paterno sinkhole (central Italy)
title_fullStr Water and dissolved gas geochemistry of the monomictic Paterno sinkhole (central Italy)
title_full_unstemmed Water and dissolved gas geochemistry of the monomictic Paterno sinkhole (central Italy)
title_short Water and dissolved gas geochemistry of the monomictic Paterno sinkhole (central Italy)
title_sort water and dissolved gas geochemistry of the monomictic paterno sinkhole central italy
topic monomictic lake, sinkhole, lake Paterno, water lake chemistry, dissolved gas chemistry.
url http://www.jlimnol.it/index.php/jlimnol/article/view/479
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