Study of Microwave-Active Composite Materials to Improve the Polyethylene Rotomolding Process

The present paper reports on the formulation and characterization of composite coating materials susceptible to microwave (MW) heating to investigate their application in making the rotomolding process (RM) more energy efficient. SiC, Fe<sub>2</sub>SiO<sub>4</sub>, Fe<sub&...

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Main Authors: Giorgio Luciano, Maurizio Vignolo, Elisabetta Brunengo, Roberto Utzeri, Paola Stagnaro
Format: Article
Language:English
Published: MDPI AG 2023-02-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/15/5/1061
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author Giorgio Luciano
Maurizio Vignolo
Elisabetta Brunengo
Roberto Utzeri
Paola Stagnaro
author_facet Giorgio Luciano
Maurizio Vignolo
Elisabetta Brunengo
Roberto Utzeri
Paola Stagnaro
author_sort Giorgio Luciano
collection DOAJ
description The present paper reports on the formulation and characterization of composite coating materials susceptible to microwave (MW) heating to investigate their application in making the rotomolding process (RM) more energy efficient. SiC, Fe<sub>2</sub>SiO<sub>4</sub>, Fe<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub> and BaTiO<sub>3</sub> and a methyl phenyl silicone resin (MPS) were employed for their formulations. Experimental results showed that the coatings with a ratio of 2:1 <i>w</i>/<i>w</i> of inorganic/MPS are the most MW-susceptible materials. To test the coatings in working mimicking conditions, they were applied to molds, and polyethylene samples were manufactured by MW-assisted laboratory uni-axial RM and then characterized by calorimetry, infrared spectroscopy and tensile tests. The results obtained suggest that the coatings developed can be successfully applied to convert molds employed for classical RM process to MW-assisted RM processes.
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spelling doaj.art-59d1e1cefa5c4f4b84e645cbe3b1f4da2023-11-17T08:25:34ZengMDPI AGPolymers2073-43602023-02-01155106110.3390/polym15051061Study of Microwave-Active Composite Materials to Improve the Polyethylene Rotomolding ProcessGiorgio Luciano0Maurizio Vignolo1Elisabetta Brunengo2Roberto Utzeri3Paola Stagnaro4Istituto di Scienze e Tecnologie Chimiche “Giulio Natta”—SCITEC, National Research Council of Italy, Via de Marini 6, 16149 Genova, ItalyIstituto di Scienze e Tecnologie Chimiche “Giulio Natta”—SCITEC, National Research Council of Italy, Via de Marini 6, 16149 Genova, ItalyIstituto di Scienze e Tecnologie Chimiche “Giulio Natta”—SCITEC, National Research Council of Italy, Via de Marini 6, 16149 Genova, ItalyIstituto di Scienze e Tecnologie Chimiche “Giulio Natta”—SCITEC, National Research Council of Italy, Via de Marini 6, 16149 Genova, ItalyIstituto di Scienze e Tecnologie Chimiche “Giulio Natta”—SCITEC, National Research Council of Italy, Via de Marini 6, 16149 Genova, ItalyThe present paper reports on the formulation and characterization of composite coating materials susceptible to microwave (MW) heating to investigate their application in making the rotomolding process (RM) more energy efficient. SiC, Fe<sub>2</sub>SiO<sub>4</sub>, Fe<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub> and BaTiO<sub>3</sub> and a methyl phenyl silicone resin (MPS) were employed for their formulations. Experimental results showed that the coatings with a ratio of 2:1 <i>w</i>/<i>w</i> of inorganic/MPS are the most MW-susceptible materials. To test the coatings in working mimicking conditions, they were applied to molds, and polyethylene samples were manufactured by MW-assisted laboratory uni-axial RM and then characterized by calorimetry, infrared spectroscopy and tensile tests. The results obtained suggest that the coatings developed can be successfully applied to convert molds employed for classical RM process to MW-assisted RM processes.https://www.mdpi.com/2073-4360/15/5/1061rotomoldingmicrowave heatingmicrowave-active materialspolyethylene processing
spellingShingle Giorgio Luciano
Maurizio Vignolo
Elisabetta Brunengo
Roberto Utzeri
Paola Stagnaro
Study of Microwave-Active Composite Materials to Improve the Polyethylene Rotomolding Process
Polymers
rotomolding
microwave heating
microwave-active materials
polyethylene processing
title Study of Microwave-Active Composite Materials to Improve the Polyethylene Rotomolding Process
title_full Study of Microwave-Active Composite Materials to Improve the Polyethylene Rotomolding Process
title_fullStr Study of Microwave-Active Composite Materials to Improve the Polyethylene Rotomolding Process
title_full_unstemmed Study of Microwave-Active Composite Materials to Improve the Polyethylene Rotomolding Process
title_short Study of Microwave-Active Composite Materials to Improve the Polyethylene Rotomolding Process
title_sort study of microwave active composite materials to improve the polyethylene rotomolding process
topic rotomolding
microwave heating
microwave-active materials
polyethylene processing
url https://www.mdpi.com/2073-4360/15/5/1061
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AT mauriziovignolo studyofmicrowaveactivecompositematerialstoimprovethepolyethylenerotomoldingprocess
AT elisabettabrunengo studyofmicrowaveactivecompositematerialstoimprovethepolyethylenerotomoldingprocess
AT robertoutzeri studyofmicrowaveactivecompositematerialstoimprovethepolyethylenerotomoldingprocess
AT paolastagnaro studyofmicrowaveactivecompositematerialstoimprovethepolyethylenerotomoldingprocess