Study of Microwave-Active Composite Materials to Improve the Polyethylene Rotomolding Process
The present paper reports on the formulation and characterization of composite coating materials susceptible to microwave (MW) heating to investigate their application in making the rotomolding process (RM) more energy efficient. SiC, Fe<sub>2</sub>SiO<sub>4</sub>, Fe<sub&...
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Format: | Article |
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MDPI AG
2023-02-01
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Series: | Polymers |
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Online Access: | https://www.mdpi.com/2073-4360/15/5/1061 |
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author | Giorgio Luciano Maurizio Vignolo Elisabetta Brunengo Roberto Utzeri Paola Stagnaro |
author_facet | Giorgio Luciano Maurizio Vignolo Elisabetta Brunengo Roberto Utzeri Paola Stagnaro |
author_sort | Giorgio Luciano |
collection | DOAJ |
description | The present paper reports on the formulation and characterization of composite coating materials susceptible to microwave (MW) heating to investigate their application in making the rotomolding process (RM) more energy efficient. SiC, Fe<sub>2</sub>SiO<sub>4</sub>, Fe<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub> and BaTiO<sub>3</sub> and a methyl phenyl silicone resin (MPS) were employed for their formulations. Experimental results showed that the coatings with a ratio of 2:1 <i>w</i>/<i>w</i> of inorganic/MPS are the most MW-susceptible materials. To test the coatings in working mimicking conditions, they were applied to molds, and polyethylene samples were manufactured by MW-assisted laboratory uni-axial RM and then characterized by calorimetry, infrared spectroscopy and tensile tests. The results obtained suggest that the coatings developed can be successfully applied to convert molds employed for classical RM process to MW-assisted RM processes. |
first_indexed | 2024-03-11T07:13:35Z |
format | Article |
id | doaj.art-59d1e1cefa5c4f4b84e645cbe3b1f4da |
institution | Directory Open Access Journal |
issn | 2073-4360 |
language | English |
last_indexed | 2024-03-11T07:13:35Z |
publishDate | 2023-02-01 |
publisher | MDPI AG |
record_format | Article |
series | Polymers |
spelling | doaj.art-59d1e1cefa5c4f4b84e645cbe3b1f4da2023-11-17T08:25:34ZengMDPI AGPolymers2073-43602023-02-01155106110.3390/polym15051061Study of Microwave-Active Composite Materials to Improve the Polyethylene Rotomolding ProcessGiorgio Luciano0Maurizio Vignolo1Elisabetta Brunengo2Roberto Utzeri3Paola Stagnaro4Istituto di Scienze e Tecnologie Chimiche “Giulio Natta”—SCITEC, National Research Council of Italy, Via de Marini 6, 16149 Genova, ItalyIstituto di Scienze e Tecnologie Chimiche “Giulio Natta”—SCITEC, National Research Council of Italy, Via de Marini 6, 16149 Genova, ItalyIstituto di Scienze e Tecnologie Chimiche “Giulio Natta”—SCITEC, National Research Council of Italy, Via de Marini 6, 16149 Genova, ItalyIstituto di Scienze e Tecnologie Chimiche “Giulio Natta”—SCITEC, National Research Council of Italy, Via de Marini 6, 16149 Genova, ItalyIstituto di Scienze e Tecnologie Chimiche “Giulio Natta”—SCITEC, National Research Council of Italy, Via de Marini 6, 16149 Genova, ItalyThe present paper reports on the formulation and characterization of composite coating materials susceptible to microwave (MW) heating to investigate their application in making the rotomolding process (RM) more energy efficient. SiC, Fe<sub>2</sub>SiO<sub>4</sub>, Fe<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub> and BaTiO<sub>3</sub> and a methyl phenyl silicone resin (MPS) were employed for their formulations. Experimental results showed that the coatings with a ratio of 2:1 <i>w</i>/<i>w</i> of inorganic/MPS are the most MW-susceptible materials. To test the coatings in working mimicking conditions, they were applied to molds, and polyethylene samples were manufactured by MW-assisted laboratory uni-axial RM and then characterized by calorimetry, infrared spectroscopy and tensile tests. The results obtained suggest that the coatings developed can be successfully applied to convert molds employed for classical RM process to MW-assisted RM processes.https://www.mdpi.com/2073-4360/15/5/1061rotomoldingmicrowave heatingmicrowave-active materialspolyethylene processing |
spellingShingle | Giorgio Luciano Maurizio Vignolo Elisabetta Brunengo Roberto Utzeri Paola Stagnaro Study of Microwave-Active Composite Materials to Improve the Polyethylene Rotomolding Process Polymers rotomolding microwave heating microwave-active materials polyethylene processing |
title | Study of Microwave-Active Composite Materials to Improve the Polyethylene Rotomolding Process |
title_full | Study of Microwave-Active Composite Materials to Improve the Polyethylene Rotomolding Process |
title_fullStr | Study of Microwave-Active Composite Materials to Improve the Polyethylene Rotomolding Process |
title_full_unstemmed | Study of Microwave-Active Composite Materials to Improve the Polyethylene Rotomolding Process |
title_short | Study of Microwave-Active Composite Materials to Improve the Polyethylene Rotomolding Process |
title_sort | study of microwave active composite materials to improve the polyethylene rotomolding process |
topic | rotomolding microwave heating microwave-active materials polyethylene processing |
url | https://www.mdpi.com/2073-4360/15/5/1061 |
work_keys_str_mv | AT giorgioluciano studyofmicrowaveactivecompositematerialstoimprovethepolyethylenerotomoldingprocess AT mauriziovignolo studyofmicrowaveactivecompositematerialstoimprovethepolyethylenerotomoldingprocess AT elisabettabrunengo studyofmicrowaveactivecompositematerialstoimprovethepolyethylenerotomoldingprocess AT robertoutzeri studyofmicrowaveactivecompositematerialstoimprovethepolyethylenerotomoldingprocess AT paolastagnaro studyofmicrowaveactivecompositematerialstoimprovethepolyethylenerotomoldingprocess |