Manipulating intermolecular interactions for ultralong organic phosphorescence

Abstract Ultralong organic phosphorescence (UOP) materials have received considerable attention in the field of organic optoelectronics due to their long lifetime, high exciton utilization, large Stokes shift, and so on. Great advancements have been achieved through manipulating intermolecular inter...

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Main Authors: Suzhi Cai, Xiaokang Yao, Huili Ma, Huifang Shi, Zhongfu An
Format: Article
Language:English
Published: Wiley 2023-06-01
Series:Aggregate
Subjects:
Online Access:https://doi.org/10.1002/agt2.320
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author Suzhi Cai
Xiaokang Yao
Huili Ma
Huifang Shi
Zhongfu An
author_facet Suzhi Cai
Xiaokang Yao
Huili Ma
Huifang Shi
Zhongfu An
author_sort Suzhi Cai
collection DOAJ
description Abstract Ultralong organic phosphorescence (UOP) materials have received considerable attention in the field of organic optoelectronics due to their long lifetime, high exciton utilization, large Stokes shift, and so on. Great advancements have been achieved through manipulating intermolecular interactions for high‐performance UOP materials in recent years. This review will discuss the influence of various intermolecular interactions, including π‐π interactions, n‐π interactions, halogen bonding, hydrogen bonding, coordinative bonding, and ionic bonding on phosphorescent properties at room temperature, respectively. We summarize the rule of manipulating intermolecular interactions for UOP materials with superior phosphorescent properties. This review will provide a guideline for developing new UOP materials with superior phosphorescent properties for potential applications in organic electronics and bioelectronics.
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spelling doaj.art-59d7799ef3644e618abb436bec1fbe062023-06-22T06:24:45ZengWileyAggregate2692-45602023-06-0143n/an/a10.1002/agt2.320Manipulating intermolecular interactions for ultralong organic phosphorescenceSuzhi Cai0Xiaokang Yao1Huili Ma2Huifang Shi3Zhongfu An4School of Flexible Electronics (Future Technologies) and Institute of Advanced Materials (IAM) Nanjing Tech University Nanjing ChinaSchool of Flexible Electronics (Future Technologies) and Institute of Advanced Materials (IAM) Nanjing Tech University Nanjing ChinaSchool of Flexible Electronics (Future Technologies) and Institute of Advanced Materials (IAM) Nanjing Tech University Nanjing ChinaSchool of Flexible Electronics (Future Technologies) and Institute of Advanced Materials (IAM) Nanjing Tech University Nanjing ChinaSchool of Flexible Electronics (Future Technologies) and Institute of Advanced Materials (IAM) Nanjing Tech University Nanjing ChinaAbstract Ultralong organic phosphorescence (UOP) materials have received considerable attention in the field of organic optoelectronics due to their long lifetime, high exciton utilization, large Stokes shift, and so on. Great advancements have been achieved through manipulating intermolecular interactions for high‐performance UOP materials in recent years. This review will discuss the influence of various intermolecular interactions, including π‐π interactions, n‐π interactions, halogen bonding, hydrogen bonding, coordinative bonding, and ionic bonding on phosphorescent properties at room temperature, respectively. We summarize the rule of manipulating intermolecular interactions for UOP materials with superior phosphorescent properties. This review will provide a guideline for developing new UOP materials with superior phosphorescent properties for potential applications in organic electronics and bioelectronics.https://doi.org/10.1002/agt2.320aggregationintermolecular interactionsmolecular stackingroom temperature phosphorescenceultralong organic phosphorescence
spellingShingle Suzhi Cai
Xiaokang Yao
Huili Ma
Huifang Shi
Zhongfu An
Manipulating intermolecular interactions for ultralong organic phosphorescence
Aggregate
aggregation
intermolecular interactions
molecular stacking
room temperature phosphorescence
ultralong organic phosphorescence
title Manipulating intermolecular interactions for ultralong organic phosphorescence
title_full Manipulating intermolecular interactions for ultralong organic phosphorescence
title_fullStr Manipulating intermolecular interactions for ultralong organic phosphorescence
title_full_unstemmed Manipulating intermolecular interactions for ultralong organic phosphorescence
title_short Manipulating intermolecular interactions for ultralong organic phosphorescence
title_sort manipulating intermolecular interactions for ultralong organic phosphorescence
topic aggregation
intermolecular interactions
molecular stacking
room temperature phosphorescence
ultralong organic phosphorescence
url https://doi.org/10.1002/agt2.320
work_keys_str_mv AT suzhicai manipulatingintermolecularinteractionsforultralongorganicphosphorescence
AT xiaokangyao manipulatingintermolecularinteractionsforultralongorganicphosphorescence
AT huilima manipulatingintermolecularinteractionsforultralongorganicphosphorescence
AT huifangshi manipulatingintermolecularinteractionsforultralongorganicphosphorescence
AT zhongfuan manipulatingintermolecularinteractionsforultralongorganicphosphorescence