Release of aluminium and thallium ions from uncoated food contact materials made of aluminium alloys into food and food simulant.

In order to investigate the release of aluminium ions from food contact materials, three different types of uncoated aluminium menu trays for single use were tested with the foodstuffs sauerkraut juice, apple sauce and tomato puree, as well as with the food simulants 5 g/L citric acid solution and a...

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Main Authors: Stefan Sander, Oliver Kappenstein, Ingo Ebner, Kai-Andre Fritsch, Roman Schmidt, Karla Pfaff, Andreas Luch
Format: Article
Language:English
Published: Public Library of Science (PLoS) 2018-01-01
Series:PLoS ONE
Online Access:http://europepmc.org/articles/PMC6056035?pdf=render
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author Stefan Sander
Oliver Kappenstein
Ingo Ebner
Kai-Andre Fritsch
Roman Schmidt
Karla Pfaff
Andreas Luch
author_facet Stefan Sander
Oliver Kappenstein
Ingo Ebner
Kai-Andre Fritsch
Roman Schmidt
Karla Pfaff
Andreas Luch
author_sort Stefan Sander
collection DOAJ
description In order to investigate the release of aluminium ions from food contact materials, three different types of uncoated aluminium menu trays for single use were tested with the foodstuffs sauerkraut juice, apple sauce and tomato puree, as well as with the food simulants 5 g/L citric acid solution and artificial tap water. To mimic a consumer relevant exposure scenario, the aluminium trays were studied using time and temperature gradients according to the Cook & Chill method, also taking into account storage time at elevated temperatures during the delivery period. The release of aluminium was found to exceed the specific release limit (SRL) of 5 mg aluminium per kilogram of food specified by the Council of Europe by up to six times. Furthermore, a release of thallium was also detected unexpectedly. Kinetic studies showed a comparable behaviour in the release of aluminium, manganese and vanadium as components of the aluminium alloy itself. In contrast, thallium could be identified as a surface contaminant or impurity because of an entirely different kinetic curve. Kinetic studies also allowed activation energy calculations. Additional camping saucepans were tested as an article for repeated use. In three subsequent release experiments with citric acid (5 g/L), artificial tap water and tomato puree as benchmark foodstuffs, the results were comparable to those of the uncoated wrought alloy aluminium trays.
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spelling doaj.art-5a128423524d4e898b012d6a00768fe22022-12-21T23:00:00ZengPublic Library of Science (PLoS)PLoS ONE1932-62032018-01-01137e020077810.1371/journal.pone.0200778Release of aluminium and thallium ions from uncoated food contact materials made of aluminium alloys into food and food simulant.Stefan SanderOliver KappensteinIngo EbnerKai-Andre FritschRoman SchmidtKarla PfaffAndreas LuchIn order to investigate the release of aluminium ions from food contact materials, three different types of uncoated aluminium menu trays for single use were tested with the foodstuffs sauerkraut juice, apple sauce and tomato puree, as well as with the food simulants 5 g/L citric acid solution and artificial tap water. To mimic a consumer relevant exposure scenario, the aluminium trays were studied using time and temperature gradients according to the Cook & Chill method, also taking into account storage time at elevated temperatures during the delivery period. The release of aluminium was found to exceed the specific release limit (SRL) of 5 mg aluminium per kilogram of food specified by the Council of Europe by up to six times. Furthermore, a release of thallium was also detected unexpectedly. Kinetic studies showed a comparable behaviour in the release of aluminium, manganese and vanadium as components of the aluminium alloy itself. In contrast, thallium could be identified as a surface contaminant or impurity because of an entirely different kinetic curve. Kinetic studies also allowed activation energy calculations. Additional camping saucepans were tested as an article for repeated use. In three subsequent release experiments with citric acid (5 g/L), artificial tap water and tomato puree as benchmark foodstuffs, the results were comparable to those of the uncoated wrought alloy aluminium trays.http://europepmc.org/articles/PMC6056035?pdf=render
spellingShingle Stefan Sander
Oliver Kappenstein
Ingo Ebner
Kai-Andre Fritsch
Roman Schmidt
Karla Pfaff
Andreas Luch
Release of aluminium and thallium ions from uncoated food contact materials made of aluminium alloys into food and food simulant.
PLoS ONE
title Release of aluminium and thallium ions from uncoated food contact materials made of aluminium alloys into food and food simulant.
title_full Release of aluminium and thallium ions from uncoated food contact materials made of aluminium alloys into food and food simulant.
title_fullStr Release of aluminium and thallium ions from uncoated food contact materials made of aluminium alloys into food and food simulant.
title_full_unstemmed Release of aluminium and thallium ions from uncoated food contact materials made of aluminium alloys into food and food simulant.
title_short Release of aluminium and thallium ions from uncoated food contact materials made of aluminium alloys into food and food simulant.
title_sort release of aluminium and thallium ions from uncoated food contact materials made of aluminium alloys into food and food simulant
url http://europepmc.org/articles/PMC6056035?pdf=render
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