The crystal structure of 2-[(tert-butyldiphenylsilyl)oxy]-1,2-diphenylethan-1-one
The title compound, C30H30O2Si, was synthesized and structurally characterized in order to determine the influence of the bulky silyl protecting group on the conformation of the benzoin moiety, with a view to directing the stereochemistry of the borohydride reduction of the benzoin. The crystal stru...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2019-04-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314619004784 |
| _version_ | 1818579011729620992 |
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| author | Martin J. Di Grandi Brett Taylor Peter W. R. Corfield |
| author_facet | Martin J. Di Grandi Brett Taylor Peter W. R. Corfield |
| author_sort | Martin J. Di Grandi |
| collection | DOAJ |
| description | The title compound, C30H30O2Si, was synthesized and structurally characterized in order to determine the influence of the bulky silyl protecting group on the conformation of the benzoin moiety, with a view to directing the stereochemistry of the borohydride reduction of the benzoin. The crystal structure shows a benzoin O—C—C—O torsion angle of 38.34 (1)°, not greatly different from that found in benzoin itself. In the crystal, a weak C—H...O hydrogen bond between the carbonyl group and a phenyl H atom of a symmetry-related molecule forms chains along [100]. |
| first_indexed | 2024-12-16T06:54:55Z |
| format | Article |
| id | doaj.art-5a300a8f0ba140e79ff34cc17617426c |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-16T06:54:55Z |
| publishDate | 2019-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-5a300a8f0ba140e79ff34cc17617426c2022-12-21T22:40:19ZengInternational Union of CrystallographyIUCrData2414-31462019-04-0144x19047810.1107/S2414314619004784lh4045The crystal structure of 2-[(tert-butyldiphenylsilyl)oxy]-1,2-diphenylethan-1-oneMartin J. Di Grandi0Brett Taylor1Peter W. R. Corfield2Department of Chemistry, Fordham University, 441 East Fordham Road, Bronx, NY 10458, USADepartment of Chemistry, Fordham University, 441 East Fordham Road, Bronx, NY 10458, USADepartment of Chemistry, Fordham University, 441 East Fordham Road, Bronx, NY 10458, USAThe title compound, C30H30O2Si, was synthesized and structurally characterized in order to determine the influence of the bulky silyl protecting group on the conformation of the benzoin moiety, with a view to directing the stereochemistry of the borohydride reduction of the benzoin. The crystal structure shows a benzoin O—C—C—O torsion angle of 38.34 (1)°, not greatly different from that found in benzoin itself. In the crystal, a weak C—H...O hydrogen bond between the carbonyl group and a phenyl H atom of a symmetry-related molecule forms chains along [100].http://scripts.iucr.org/cgi-bin/paper?S2414314619004784crystal structurebenzoinsilyl derivativebulky groupconformation |
| spellingShingle | Martin J. Di Grandi Brett Taylor Peter W. R. Corfield The crystal structure of 2-[(tert-butyldiphenylsilyl)oxy]-1,2-diphenylethan-1-one IUCrData crystal structure benzoin silyl derivative bulky group conformation |
| title | The crystal structure of 2-[(tert-butyldiphenylsilyl)oxy]-1,2-diphenylethan-1-one |
| title_full | The crystal structure of 2-[(tert-butyldiphenylsilyl)oxy]-1,2-diphenylethan-1-one |
| title_fullStr | The crystal structure of 2-[(tert-butyldiphenylsilyl)oxy]-1,2-diphenylethan-1-one |
| title_full_unstemmed | The crystal structure of 2-[(tert-butyldiphenylsilyl)oxy]-1,2-diphenylethan-1-one |
| title_short | The crystal structure of 2-[(tert-butyldiphenylsilyl)oxy]-1,2-diphenylethan-1-one |
| title_sort | crystal structure of 2 tert butyldiphenylsilyl oxy 1 2 diphenylethan 1 one |
| topic | crystal structure benzoin silyl derivative bulky group conformation |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314619004784 |
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