Catalytic Alkylation of Brown Coal and Peat
The alcohol alkylation of low-grade metamorphic coal and peat in the presence of mineral and organic acids was studied using FTIR, NMR, and GC-MS. The impact of the reaction conditions on the yield of extractable matter was investigated experimentally, and relevant regression equations were obtained...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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al-Farabi Kazakh National University
2012-02-01
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| Series: | Eurasian Chemico-Technological Journal |
| Online Access: | http://ect-journal.kz/index.php/ectj/article/view/366 |
| _version_ | 1828230978771877888 |
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| author | S. I. Zherebtsov Z. R. Ismagilov |
| author_facet | S. I. Zherebtsov Z. R. Ismagilov |
| author_sort | S. I. Zherebtsov |
| collection | DOAJ |
| description | The alcohol alkylation of low-grade metamorphic coal and peat in the presence of mineral and organic acids was studied using FTIR, NMR, and GC-MS. The impact of the reaction conditions on the yield of extractable matter was investigated experimentally, and relevant regression equations were obtained. Changes in the group and individual compositions of the wax fractions of bitumen in the process of brown coal and peat alkylation were studied. It was found that the esters of alkylated coal waxes consisted of native esters of fatty acids, and alkyl esters of these acids formed as a result of the alkylation reaction. Esterification and transesterification were predominant in the reactions of the bitumen fraction components. The positive effect of alcohol alkylation on the increase of the bitumen yield was found. |
| first_indexed | 2024-04-12T18:56:36Z |
| format | Article |
| id | doaj.art-5a31c1dd6b4c45c795251e90578ab967 |
| institution | Directory Open Access Journal |
| issn | 1562-3920 2522-4867 |
| language | English |
| last_indexed | 2024-04-12T18:56:36Z |
| publishDate | 2012-02-01 |
| publisher | al-Farabi Kazakh National University |
| record_format | Article |
| series | Eurasian Chemico-Technological Journal |
| spelling | doaj.art-5a31c1dd6b4c45c795251e90578ab9672022-12-22T03:20:18Zengal-Farabi Kazakh National UniversityEurasian Chemico-Technological Journal1562-39202522-48672012-02-01141455310.18321/ectj99366Catalytic Alkylation of Brown Coal and PeatS. I. Zherebtsov0Z. R. Ismagilov1Institute of coal chemistry and material science of the Siberian Branch of the Russian Academy of Sciences, Kemerovo, Russia, 650000Boreskov Institute of catalysis of the Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia, 630090The alcohol alkylation of low-grade metamorphic coal and peat in the presence of mineral and organic acids was studied using FTIR, NMR, and GC-MS. The impact of the reaction conditions on the yield of extractable matter was investigated experimentally, and relevant regression equations were obtained. Changes in the group and individual compositions of the wax fractions of bitumen in the process of brown coal and peat alkylation were studied. It was found that the esters of alkylated coal waxes consisted of native esters of fatty acids, and alkyl esters of these acids formed as a result of the alkylation reaction. Esterification and transesterification were predominant in the reactions of the bitumen fraction components. The positive effect of alcohol alkylation on the increase of the bitumen yield was found.http://ect-journal.kz/index.php/ectj/article/view/366 |
| spellingShingle | S. I. Zherebtsov Z. R. Ismagilov Catalytic Alkylation of Brown Coal and Peat Eurasian Chemico-Technological Journal |
| title | Catalytic Alkylation of Brown Coal and Peat |
| title_full | Catalytic Alkylation of Brown Coal and Peat |
| title_fullStr | Catalytic Alkylation of Brown Coal and Peat |
| title_full_unstemmed | Catalytic Alkylation of Brown Coal and Peat |
| title_short | Catalytic Alkylation of Brown Coal and Peat |
| title_sort | catalytic alkylation of brown coal and peat |
| url | http://ect-journal.kz/index.php/ectj/article/view/366 |
| work_keys_str_mv | AT sizherebtsov catalyticalkylationofbrowncoalandpeat AT zrismagilov catalyticalkylationofbrowncoalandpeat |