Facile Nanostructured Substrate Preparation Using Gold Nanocuboids for SERS

In the present work, we report a practical fabrication method of gold-aluminium substrates for surface en‐ hanced Raman spectroscopy. A commercial aluminium- foil was used to fabricate SERS substrates by depositing gold nanocuboids and faceted particles onto their surfaces using the drop-drying meth...

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Main Authors: Pablo Genaro Martínez-Torres, Monica Monserrat Martínez-García, Pablo Eduado Cardoso-Ávila, Juan Luis Pichardo-Molina
Format: Article
Language:English
Published: Hindawi - SAGE Publishing 2015-04-01
Series:Nanomaterials and Nanotechnology
Subjects:
Online Access:http://www.intechopen.com/journals/nanomaterials_and_nanotechnology/facile-nanostructured-substrate-preparation-using-gold-nanocuboids-for-sers
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author Pablo Genaro Martínez-Torres
Monica Monserrat Martínez-García
Pablo Eduado Cardoso-Ávila
Juan Luis Pichardo-Molina
author_facet Pablo Genaro Martínez-Torres
Monica Monserrat Martínez-García
Pablo Eduado Cardoso-Ávila
Juan Luis Pichardo-Molina
author_sort Pablo Genaro Martínez-Torres
collection DOAJ
description In the present work, we report a practical fabrication method of gold-aluminium substrates for surface en‐ hanced Raman spectroscopy. A commercial aluminium- foil was used to fabricate SERS substrates by depositing gold nanocuboids and faceted particles onto their surfaces using the drop-drying method. The gold nanoparticles were characterized by ultraviolet-visible spectroscopy, while the size and morphology were determined by field emission scanning electron microscopy. The perform‐ ance of the substrates was investigated using Rhoda‐ mine 6G in a water solution where a volume of 3 μl was placed on the surfaces of the SERS substrates, and the Raman spectra were immediately acquired using diode laser excitation at 785 nm. The estimated analytical enhancement factor of the gold-aluminium substrates was 1.8 x 106, using a solution of Rhodamine 6G with a concentration of 1 x 109 (0.4796 ppb). We show that our SERS substrates can be easily fabricated, and that they are reproducible and have suitable surface uniformity, thus allowing one to analyse Rhodamine 6G not only as a dry sample, but also in a solution.
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spelling doaj.art-5a3be9543d644328b3219b54bbf8d4ac2023-11-02T03:35:47ZengHindawi - SAGE PublishingNanomaterials and Nanotechnology1847-98042015-04-01512http://dx.doi.org/10.5772/6050048383Facile Nanostructured Substrate Preparation Using Gold Nanocuboids for SERSPablo Genaro Martínez-TorresMonica Monserrat Martínez-GarcíaPablo Eduado Cardoso-ÁvilaJuan Luis Pichardo-MolinaIn the present work, we report a practical fabrication method of gold-aluminium substrates for surface en‐ hanced Raman spectroscopy. A commercial aluminium- foil was used to fabricate SERS substrates by depositing gold nanocuboids and faceted particles onto their surfaces using the drop-drying method. The gold nanoparticles were characterized by ultraviolet-visible spectroscopy, while the size and morphology were determined by field emission scanning electron microscopy. The perform‐ ance of the substrates was investigated using Rhoda‐ mine 6G in a water solution where a volume of 3 μl was placed on the surfaces of the SERS substrates, and the Raman spectra were immediately acquired using diode laser excitation at 785 nm. The estimated analytical enhancement factor of the gold-aluminium substrates was 1.8 x 106, using a solution of Rhodamine 6G with a concentration of 1 x 109 (0.4796 ppb). We show that our SERS substrates can be easily fabricated, and that they are reproducible and have suitable surface uniformity, thus allowing one to analyse Rhodamine 6G not only as a dry sample, but also in a solution.http://www.intechopen.com/journals/nanomaterials_and_nanotechnology/facile-nanostructured-substrate-preparation-using-gold-nanocuboids-for-sersAl-foilgold nanoparticlesSERS substratesRhodamine 6Gliquid detection
spellingShingle Pablo Genaro Martínez-Torres
Monica Monserrat Martínez-García
Pablo Eduado Cardoso-Ávila
Juan Luis Pichardo-Molina
Facile Nanostructured Substrate Preparation Using Gold Nanocuboids for SERS
Nanomaterials and Nanotechnology
Al-foil
gold nanoparticles
SERS substrates
Rhodamine 6G
liquid detection
title Facile Nanostructured Substrate Preparation Using Gold Nanocuboids for SERS
title_full Facile Nanostructured Substrate Preparation Using Gold Nanocuboids for SERS
title_fullStr Facile Nanostructured Substrate Preparation Using Gold Nanocuboids for SERS
title_full_unstemmed Facile Nanostructured Substrate Preparation Using Gold Nanocuboids for SERS
title_short Facile Nanostructured Substrate Preparation Using Gold Nanocuboids for SERS
title_sort facile nanostructured substrate preparation using gold nanocuboids for sers
topic Al-foil
gold nanoparticles
SERS substrates
Rhodamine 6G
liquid detection
url http://www.intechopen.com/journals/nanomaterials_and_nanotechnology/facile-nanostructured-substrate-preparation-using-gold-nanocuboids-for-sers
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AT pabloeduadocardosoavila facilenanostructuredsubstratepreparationusinggoldnanocuboidsforsers
AT juanluispichardomolina facilenanostructuredsubstratepreparationusinggoldnanocuboidsforsers