Cellulose fiber network as reinforcement of thermoplastic paraffin films

Abstract The incorporation of natural fibers into polymer matrices poses challenges due to physicochemical incompatibility, which is typically addressed through precursor modification or the use of compatibilizers. Here, we introduce a novel type of composite that overcomes this challenge by utilizi...

Full description

Bibliographic Details
Main Authors: Matheus Fernandes Flores, Luciano Cordeiro, Antonio Aprigio da Silva Curvelo
Format: Article
Language:English
Published: Associação Brasileira de Polímeros 2023-08-01
Series:Polímeros
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282023000200407&lng=en&tlng=en
_version_ 1797739613141336064
author Matheus Fernandes Flores
Luciano Cordeiro
Antonio Aprigio da Silva Curvelo
author_facet Matheus Fernandes Flores
Luciano Cordeiro
Antonio Aprigio da Silva Curvelo
author_sort Matheus Fernandes Flores
collection DOAJ
description Abstract The incorporation of natural fibers into polymer matrices poses challenges due to physicochemical incompatibility, which is typically addressed through precursor modification or the use of compatibilizers. Here, we introduce a novel type of composite that overcomes this challenge by utilizing a network of fine, porous cellulosic sheets inter-diffused with a commercial paraffin films. This approach physically adheres the fiber network to the matrix, preserving its structure. Microscopy images confirm the formation of the proposed microstructure, and mechanical testing reveals a gradual increase in modulus and strength with the incorporation of cellulose. The maximum incorporation achieved was 7.6% (w/w) of cellulosic fibers, resulting in a 167% increase (1.67 times improved) in composite stiffness. Moreover, these composites exhibit ductility, with an average deformation of 410 ± 38%, corresponding to 20% reduction in relation to pure matrix. Our findings demonstrate the potential of this approach for developing sustainable materials with improved mechanical properties.
first_indexed 2024-03-12T13:59:44Z
format Article
id doaj.art-5a3d5c02ee4f4c248d8ec54987083e64
institution Directory Open Access Journal
issn 1678-5169
language English
last_indexed 2024-03-12T13:59:44Z
publishDate 2023-08-01
publisher Associação Brasileira de Polímeros
record_format Article
series Polímeros
spelling doaj.art-5a3d5c02ee4f4c248d8ec54987083e642023-08-22T07:43:10ZengAssociação Brasileira de PolímerosPolímeros1678-51692023-08-0133210.1590/0104-1428.20230022Cellulose fiber network as reinforcement of thermoplastic paraffin filmsMatheus Fernandes Floreshttps://orcid.org/0000-0003-1701-9827Luciano Cordeirohttps://orcid.org/0000-0002-9054-3652Antonio Aprigio da Silva Curvelohttps://orcid.org/0000-0003-0377-7707Abstract The incorporation of natural fibers into polymer matrices poses challenges due to physicochemical incompatibility, which is typically addressed through precursor modification or the use of compatibilizers. Here, we introduce a novel type of composite that overcomes this challenge by utilizing a network of fine, porous cellulosic sheets inter-diffused with a commercial paraffin films. This approach physically adheres the fiber network to the matrix, preserving its structure. Microscopy images confirm the formation of the proposed microstructure, and mechanical testing reveals a gradual increase in modulus and strength with the incorporation of cellulose. The maximum incorporation achieved was 7.6% (w/w) of cellulosic fibers, resulting in a 167% increase (1.67 times improved) in composite stiffness. Moreover, these composites exhibit ductility, with an average deformation of 410 ± 38%, corresponding to 20% reduction in relation to pure matrix. Our findings demonstrate the potential of this approach for developing sustainable materials with improved mechanical properties.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282023000200407&lng=en&tlng=ennatural fiberscompositesnetwork reinforcementpaperpolymer matrices
spellingShingle Matheus Fernandes Flores
Luciano Cordeiro
Antonio Aprigio da Silva Curvelo
Cellulose fiber network as reinforcement of thermoplastic paraffin films
Polímeros
natural fibers
composites
network reinforcement
paper
polymer matrices
title Cellulose fiber network as reinforcement of thermoplastic paraffin films
title_full Cellulose fiber network as reinforcement of thermoplastic paraffin films
title_fullStr Cellulose fiber network as reinforcement of thermoplastic paraffin films
title_full_unstemmed Cellulose fiber network as reinforcement of thermoplastic paraffin films
title_short Cellulose fiber network as reinforcement of thermoplastic paraffin films
title_sort cellulose fiber network as reinforcement of thermoplastic paraffin films
topic natural fibers
composites
network reinforcement
paper
polymer matrices
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282023000200407&lng=en&tlng=en
work_keys_str_mv AT matheusfernandesflores cellulosefibernetworkasreinforcementofthermoplasticparaffinfilms
AT lucianocordeiro cellulosefibernetworkasreinforcementofthermoplasticparaffinfilms
AT antonioaprigiodasilvacurvelo cellulosefibernetworkasreinforcementofthermoplasticparaffinfilms