Cobalt-catalyzed branched selective hydroallylation of terminal alkynes
Selectively generating “skipped” dienes, where two carbon–carbon double bonds are separated by a saturated carbon center, is an interesting problem in organic chemistry, with few reliable, catalytic methods currently available. Here, the authors report branched selective hydroallylation of terminal...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-08-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-32291-3 |
| Summary: | Selectively generating “skipped” dienes, where two carbon–carbon double bonds are separated by a saturated carbon center, is an interesting problem in organic chemistry, with few reliable, catalytic methods currently available. Here, the authors report branched selective hydroallylation of terminal alkynes with allylic bromides to form skipped dienes, via cobalt catalysis. |
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| ISSN: | 2041-1723 |