Poly[bis(acetone-κO)bis{μ3-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato-κ4O:O,O′:O′}sodium(I)chromium(III)]
The title compound, [CrNa(C16H9ClN2O2)2(C3H6O)2]n, is an azo-CrIII complex polymer that is used as a charge-control agent in electrophotography. The monomeric unit is composed of octahedral CrIII and NaI units, and is characterized by twofold rotation symmetry. The CrIII atom is chelated by two N an...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808000433 |
| _version_ | 1798017720600494080 |
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| author | Jin Mizuguchi Yohei Sato Shinpei Ito |
| author_facet | Jin Mizuguchi Yohei Sato Shinpei Ito |
| author_sort | Jin Mizuguchi |
| collection | DOAJ |
| description | The title compound, [CrNa(C16H9ClN2O2)2(C3H6O)2]n, is an azo-CrIII complex polymer that is used as a charge-control agent in electrophotography. The monomeric unit is composed of octahedral CrIII and NaI units, and is characterized by twofold rotation symmetry. The CrIII atom is chelated by two N and four O atoms from two [(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholate ligands. The ligand anion exists in the cis form. The NaI atom is coordinated by two phenoxy O atoms from a neighboring CrIII unit, two naphthoxy O atoms from another neighboring CrIII unit and two O atoms from acetone molecules. The dinuclear complex forms a one-dimensional polymer running along the c axis. |
| first_indexed | 2024-04-11T16:11:48Z |
| format | Article |
| id | doaj.art-5a9d049068c6473289bf096abdd49c6a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:11:48Z |
| publishDate | 2008-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-5a9d049068c6473289bf096abdd49c6a2022-12-22T04:14:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m333m33410.1107/S1600536808000433Poly[bis(acetone-κO)bis{μ3-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato-κ4O:O,O′:O′}sodium(I)chromium(III)]Jin MizuguchiYohei SatoShinpei ItoThe title compound, [CrNa(C16H9ClN2O2)2(C3H6O)2]n, is an azo-CrIII complex polymer that is used as a charge-control agent in electrophotography. The monomeric unit is composed of octahedral CrIII and NaI units, and is characterized by twofold rotation symmetry. The CrIII atom is chelated by two N and four O atoms from two [(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholate ligands. The ligand anion exists in the cis form. The NaI atom is coordinated by two phenoxy O atoms from a neighboring CrIII unit, two naphthoxy O atoms from another neighboring CrIII unit and two O atoms from acetone molecules. The dinuclear complex forms a one-dimensional polymer running along the c axis.http://scripts.iucr.org/cgi-bin/paper?S1600536808000433 |
| spellingShingle | Jin Mizuguchi Yohei Sato Shinpei Ito Poly[bis(acetone-κO)bis{μ3-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato-κ4O:O,O′:O′}sodium(I)chromium(III)] Acta Crystallographica Section E |
| title | Poly[bis(acetone-κO)bis{μ3-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato-κ4O:O,O′:O′}sodium(I)chromium(III)] |
| title_full | Poly[bis(acetone-κO)bis{μ3-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato-κ4O:O,O′:O′}sodium(I)chromium(III)] |
| title_fullStr | Poly[bis(acetone-κO)bis{μ3-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato-κ4O:O,O′:O′}sodium(I)chromium(III)] |
| title_full_unstemmed | Poly[bis(acetone-κO)bis{μ3-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato-κ4O:O,O′:O′}sodium(I)chromium(III)] |
| title_short | Poly[bis(acetone-κO)bis{μ3-1-[(5-chloro-2-oxidophenyl)diazenyl]-2-naphtholato-κ4O:O,O′:O′}sodium(I)chromium(III)] |
| title_sort | poly bis acetone 954 o bis 956 3 1 5 chloro 2 oxidophenyl diazenyl 2 naphtholato 954 4o o o 8242 o 8242 sodium i chromium iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808000433 |
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