Synthesis and Characterization of Tripodal Tetradentate Ligand Type NS3 and its Complexes with Re(V), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II)
This work represents the preparation of the starting material, 3-chloro-2-oxo-1,4-dithiacyclohexane (S) using a new method. This material was reacted with, 4-phenylthiosemicarbazide to give (H3NS3) as a tetradentate ligand H3L. New complex of rhenium (V) with this ligand of the formula [ReO(L)] was...
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| Format: | Article |
| Language: | Arabic |
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College of Science for Women, University of Baghdad
2009-03-01
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| Series: | Baghdad Science Journal |
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| Online Access: | http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/968 |
| _version_ | 1818754078822367232 |
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| author | Baghdad Science Journal |
| author_facet | Baghdad Science Journal |
| author_sort | Baghdad Science Journal |
| collection | DOAJ |
| description | This work represents the preparation of the starting material, 3-chloro-2-oxo-1,4-dithiacyclohexane (S) using a new method. This material was reacted with, 4-phenylthiosemicarbazide to give (H3NS3) as a tetradentate ligand H3L. New complex of rhenium (V) with this ligand of the formula [ReO(L)] was prepared. New complexes of the general formula [M(HL)] of this ligand when reacted with some metal ions where: M = Ni(II), Cu(II), Cd(II), Zn(II), Hg(II) have been reported.
The ligand and the complexes were characterized by infrared, ultraviolet–visible, mass, 1H nuclear magnetic resonance and atomic absorption spectroscopic techniques and by (HPLC), elemental analysis, and electrical conductivity. The proposed structure for H3L with Re (V) is square pyramidal, while Ni(II) complex was square planar geometry, and with the rest of metal ions are distorted tetrahedral. |
| first_indexed | 2024-12-18T05:17:32Z |
| format | Article |
| id | doaj.art-5aa0b89c302d415680a5709d055a87e2 |
| institution | Directory Open Access Journal |
| issn | 2078-8665 2411-7986 |
| language | Arabic |
| last_indexed | 2024-12-18T05:17:32Z |
| publishDate | 2009-03-01 |
| publisher | College of Science for Women, University of Baghdad |
| record_format | Article |
| series | Baghdad Science Journal |
| spelling | doaj.art-5aa0b89c302d415680a5709d055a87e22022-12-21T21:19:44ZaraCollege of Science for Women, University of BaghdadBaghdad Science Journal2078-86652411-79862009-03-016110.21123/bsj.6.1.173-187Synthesis and Characterization of Tripodal Tetradentate Ligand Type NS3 and its Complexes with Re(V), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II)Baghdad Science JournalThis work represents the preparation of the starting material, 3-chloro-2-oxo-1,4-dithiacyclohexane (S) using a new method. This material was reacted with, 4-phenylthiosemicarbazide to give (H3NS3) as a tetradentate ligand H3L. New complex of rhenium (V) with this ligand of the formula [ReO(L)] was prepared. New complexes of the general formula [M(HL)] of this ligand when reacted with some metal ions where: M = Ni(II), Cu(II), Cd(II), Zn(II), Hg(II) have been reported. The ligand and the complexes were characterized by infrared, ultraviolet–visible, mass, 1H nuclear magnetic resonance and atomic absorption spectroscopic techniques and by (HPLC), elemental analysis, and electrical conductivity. The proposed structure for H3L with Re (V) is square pyramidal, while Ni(II) complex was square planar geometry, and with the rest of metal ions are distorted tetrahedral.http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/968"Tetradentate ligand (NS3), Re(r) " |
| spellingShingle | Baghdad Science Journal Synthesis and Characterization of Tripodal Tetradentate Ligand Type NS3 and its Complexes with Re(V), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) Baghdad Science Journal "Tetradentate ligand (NS3), Re(r) " |
| title | Synthesis and Characterization of Tripodal Tetradentate Ligand Type NS3 and its Complexes with Re(V), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) |
| title_full | Synthesis and Characterization of Tripodal Tetradentate Ligand Type NS3 and its Complexes with Re(V), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) |
| title_fullStr | Synthesis and Characterization of Tripodal Tetradentate Ligand Type NS3 and its Complexes with Re(V), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) |
| title_full_unstemmed | Synthesis and Characterization of Tripodal Tetradentate Ligand Type NS3 and its Complexes with Re(V), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) |
| title_short | Synthesis and Characterization of Tripodal Tetradentate Ligand Type NS3 and its Complexes with Re(V), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) |
| title_sort | synthesis and characterization of tripodal tetradentate ligand type ns3 and its complexes with re v ni ii cu ii zn ii cd ii and hg ii |
| topic | "Tetradentate ligand (NS3), Re(r) " |
| url | http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/968 |
| work_keys_str_mv | AT baghdadsciencejournal synthesisandcharacterizationoftripodaltetradentateligandtypens3anditscomplexeswithrevniiicuiizniicdiiandhgii |