THE REDOX FEATURES OF COMPLEX FORMATION REACTIONS OF Hg(II), Ce(IV), Se(VI), Cr(VI), Mn(VII), V(V) WITH CARMOISINE

The activating effect of Mn(VII) ions on V(V), Se(VI) and Cr(VI) complexing ability with carmoisine was established with pH values that are typical of each ion separately, that allow to determinate them without heating of reaction mixture. It is shown that values of the chemical system redox potenti...

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Main Authors: A. N. Chebotaryov, E. V. Raboshvil, I. S. Efimova
Format: Article
Language:English
Published: Odessa I. I. Mechnikov National University 2014-12-01
Series:Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ
Subjects:
Online Access:http://heraldchem.onu.edu.ua/article/view/31887
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author A. N. Chebotaryov
E. V. Raboshvil
I. S. Efimova
author_facet A. N. Chebotaryov
E. V. Raboshvil
I. S. Efimova
author_sort A. N. Chebotaryov
collection DOAJ
description The activating effect of Mn(VII) ions on V(V), Se(VI) and Cr(VI) complexing ability with carmoisine was established with pH values that are typical of each ion separately, that allow to determinate them without heating of reaction mixture. It is shown that values of the chemical system redox potential and the medium acidity, which are optimal for each of the investigated metal ions, are critical and important factors that influence complex formation in the systems "M1-M2-CAN".
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spelling doaj.art-5ada5ec46f564abf9fc1ba7501c257662022-12-22T03:18:22ZengOdessa I. I. Mechnikov National UniversityVìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ2304-09472414-59632014-12-01174(44)616910.18524/2304-0947.2012.4(44).3188731887THE REDOX FEATURES OF COMPLEX FORMATION REACTIONS OF Hg(II), Ce(IV), Se(VI), Cr(VI), Mn(VII), V(V) WITH CARMOISINEA. N. Chebotaryov0E. V. Raboshvil1I. S. Efimova2Одеський національний університет імені І. І. МечниковаОдеський національний університет імені І. І. МечниковаОдеський національний університет імені І. І. МечниковаThe activating effect of Mn(VII) ions on V(V), Se(VI) and Cr(VI) complexing ability with carmoisine was established with pH values that are typical of each ion separately, that allow to determinate them without heating of reaction mixture. It is shown that values of the chemical system redox potential and the medium acidity, which are optimal for each of the investigated metal ions, are critical and important factors that influence complex formation in the systems "M1-M2-CAN".http://heraldchem.onu.edu.ua/article/view/31887редокс-реакціякармоазініони металу
spellingShingle A. N. Chebotaryov
E. V. Raboshvil
I. S. Efimova
THE REDOX FEATURES OF COMPLEX FORMATION REACTIONS OF Hg(II), Ce(IV), Se(VI), Cr(VI), Mn(VII), V(V) WITH CARMOISINE
Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ
редокс-реакція
кармоазін
іони металу
title THE REDOX FEATURES OF COMPLEX FORMATION REACTIONS OF Hg(II), Ce(IV), Se(VI), Cr(VI), Mn(VII), V(V) WITH CARMOISINE
title_full THE REDOX FEATURES OF COMPLEX FORMATION REACTIONS OF Hg(II), Ce(IV), Se(VI), Cr(VI), Mn(VII), V(V) WITH CARMOISINE
title_fullStr THE REDOX FEATURES OF COMPLEX FORMATION REACTIONS OF Hg(II), Ce(IV), Se(VI), Cr(VI), Mn(VII), V(V) WITH CARMOISINE
title_full_unstemmed THE REDOX FEATURES OF COMPLEX FORMATION REACTIONS OF Hg(II), Ce(IV), Se(VI), Cr(VI), Mn(VII), V(V) WITH CARMOISINE
title_short THE REDOX FEATURES OF COMPLEX FORMATION REACTIONS OF Hg(II), Ce(IV), Se(VI), Cr(VI), Mn(VII), V(V) WITH CARMOISINE
title_sort redox features of complex formation reactions of hg ii ce iv se vi cr vi mn vii v v with carmoisine
topic редокс-реакція
кармоазін
іони металу
url http://heraldchem.onu.edu.ua/article/view/31887
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