(Cation)2C2O4∙nSnPh2C2O4(n=1, 2; cation=Pr2NH2, MeNH3) AND SOME OF THEIR ADDUCTS: SYNTHESIS, INFRARED AND MOSSBAUER STUDIES
Three [SnPh2(C2O4)2]2- containing new adducts have been synthesized and characterized by elemental analyses, infrared and Mossbauer spectroscopy, the suggested structures being discrete, the SnPh2 residues octahedral cis or trans coordinated. A trans [SnPh2(C2O4)2]2- complex- anion has been evidence...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2014-11-01
|
| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| Subjects: | |
| Online Access: | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201403&vol=3&aid=4156 |
| _version_ | 1819179049420849152 |
|---|---|
| author | YAYA SOW LIBASSE DIOP |
| author_facet | YAYA SOW LIBASSE DIOP |
| author_sort | YAYA SOW |
| collection | DOAJ |
| description | Three [SnPh2(C2O4)2]2- containing new adducts have been synthesized and characterized by elemental analyses, infrared and Mossbauer spectroscopy, the suggested structures being discrete, the SnPh2 residues octahedral cis or trans coordinated. A trans [SnPh2(C2O4)2]2- complex- anion has been evidenced by spectroscopic methods for the first time in this work. The new complex-anion [SnPh2Cl(C2O4)2]3- with a seven coordinated tin centre has been reported in this paper and a two metallic components structure containing a tetranuclear and a mononuclear components with octahedral environments around the tin centers interacting with cations and involving OH groups leading to a supramolecular architecture has also been reported. The anion behaves as a mono- or a bichelating ligand. |
| first_indexed | 2024-12-22T21:52:16Z |
| format | Article |
| id | doaj.art-5b01b9b6ef7a4813b5cd19d07e4561d3 |
| institution | Directory Open Access Journal |
| issn | 1582-540X 1582-540X |
| language | English |
| last_indexed | 2024-12-22T21:52:16Z |
| publishDate | 2014-11-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj.art-5b01b9b6ef7a4813b5cd19d07e4561d32022-12-21T18:11:21ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X1582-540X2014-11-01153255259(Cation)2C2O4∙nSnPh2C2O4(n=1, 2; cation=Pr2NH2, MeNH3) AND SOME OF THEIR ADDUCTS: SYNTHESIS, INFRARED AND MOSSBAUER STUDIESYAYA SOW0LIBASSE DIOP1Université Cheikh Anta Diop, Faculté des Sciences et Technique, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal Université Cheikh Anta Diop, Faculté des Sciences et Technique, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal Three [SnPh2(C2O4)2]2- containing new adducts have been synthesized and characterized by elemental analyses, infrared and Mossbauer spectroscopy, the suggested structures being discrete, the SnPh2 residues octahedral cis or trans coordinated. A trans [SnPh2(C2O4)2]2- complex- anion has been evidenced by spectroscopic methods for the first time in this work. The new complex-anion [SnPh2Cl(C2O4)2]3- with a seven coordinated tin centre has been reported in this paper and a two metallic components structure containing a tetranuclear and a mononuclear components with octahedral environments around the tin centers interacting with cations and involving OH groups leading to a supramolecular architecture has also been reported. The anion behaves as a mono- or a bichelating ligand.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201403&vol=3&aid=4156a two metallic components structurecis and trans octahedral coordinated SnPh2 residuesH bondsmono and bichelating oxalatessupramolecular architecture |
| spellingShingle | YAYA SOW LIBASSE DIOP (Cation)2C2O4∙nSnPh2C2O4(n=1, 2; cation=Pr2NH2, MeNH3) AND SOME OF THEIR ADDUCTS: SYNTHESIS, INFRARED AND MOSSBAUER STUDIES Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry a two metallic components structure cis and trans octahedral coordinated SnPh2 residues H bonds mono and bichelating oxalates supramolecular architecture |
| title | (Cation)2C2O4∙nSnPh2C2O4(n=1, 2; cation=Pr2NH2, MeNH3) AND SOME OF THEIR ADDUCTS: SYNTHESIS, INFRARED AND MOSSBAUER STUDIES |
| title_full | (Cation)2C2O4∙nSnPh2C2O4(n=1, 2; cation=Pr2NH2, MeNH3) AND SOME OF THEIR ADDUCTS: SYNTHESIS, INFRARED AND MOSSBAUER STUDIES |
| title_fullStr | (Cation)2C2O4∙nSnPh2C2O4(n=1, 2; cation=Pr2NH2, MeNH3) AND SOME OF THEIR ADDUCTS: SYNTHESIS, INFRARED AND MOSSBAUER STUDIES |
| title_full_unstemmed | (Cation)2C2O4∙nSnPh2C2O4(n=1, 2; cation=Pr2NH2, MeNH3) AND SOME OF THEIR ADDUCTS: SYNTHESIS, INFRARED AND MOSSBAUER STUDIES |
| title_short | (Cation)2C2O4∙nSnPh2C2O4(n=1, 2; cation=Pr2NH2, MeNH3) AND SOME OF THEIR ADDUCTS: SYNTHESIS, INFRARED AND MOSSBAUER STUDIES |
| title_sort | cation 2c2o4∙nsnph2c2o4 n 1 2 cation pr2nh2 menh3 and some of their adducts synthesis infrared and mossbauer studies |
| topic | a two metallic components structure cis and trans octahedral coordinated SnPh2 residues H bonds mono and bichelating oxalates supramolecular architecture |
| url | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201403&vol=3&aid=4156 |
| work_keys_str_mv | AT yayasow cation2c2o4nsnph2c2o4n12cationpr2nh2menh3andsomeoftheiradductssynthesisinfraredandmossbauerstudies AT libassediop cation2c2o4nsnph2c2o4n12cationpr2nh2menh3andsomeoftheiradductssynthesisinfraredandmossbauerstudies |