trans-Carbonylchloridobis(tri-p-tolylphosphine)rhodium(I) acetone solvate
The title compound, [RhCl(C21H21P)2(CO)]·C3H6O, was precipitated in trace yield from a reaction of RhCl(cod)(THP) with P(p-tol)3 in a 1:1 acetone-d6/CD3OD solution under a hydrogen atmosphere [p-tol = p-tolyl, THP = tris(hydroxymethyl)phosphine, P(CH2OH)3, and cod = 1,5-cyclooctadiene]. The...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808003528 |
| _version_ | 1818487277564723200 |
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| author | Brian R. James Brian O. Patrick Fabio Lorenzini |
| author_facet | Brian R. James Brian O. Patrick Fabio Lorenzini |
| author_sort | Brian R. James |
| collection | DOAJ |
| description | The title compound, [RhCl(C21H21P)2(CO)]·C3H6O, was precipitated in trace yield from a reaction of RhCl(cod)(THP) with P(p-tol)3 in a 1:1 acetone-d6/CD3OD solution under a hydrogen atmosphere [p-tol = p-tolyl, THP = tris(hydroxymethyl)phosphine, P(CH2OH)3, and cod = 1,5-cyclooctadiene]. The complex displays a square-planar geometry around the RhI atom. The complex molecules and the acetone molecules are linked into a chain along the a axis by intermolecular C—H...Cl and C—H...O hydrogen bonds. |
| first_indexed | 2024-12-10T16:35:45Z |
| format | Article |
| id | doaj.art-5b0fe29fa60d4fb4b4114c90230e4d27 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T16:35:45Z |
| publishDate | 2008-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-5b0fe29fa60d4fb4b4114c90230e4d272022-12-22T01:41:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-03-01643m464m46510.1107/S1600536808003528trans-Carbonylchloridobis(tri-p-tolylphosphine)rhodium(I) acetone solvateBrian R. JamesBrian O. PatrickFabio LorenziniThe title compound, [RhCl(C21H21P)2(CO)]·C3H6O, was precipitated in trace yield from a reaction of RhCl(cod)(THP) with P(p-tol)3 in a 1:1 acetone-d6/CD3OD solution under a hydrogen atmosphere [p-tol = p-tolyl, THP = tris(hydroxymethyl)phosphine, P(CH2OH)3, and cod = 1,5-cyclooctadiene]. The complex displays a square-planar geometry around the RhI atom. The complex molecules and the acetone molecules are linked into a chain along the a axis by intermolecular C—H...Cl and C—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536808003528 |
| spellingShingle | Brian R. James Brian O. Patrick Fabio Lorenzini trans-Carbonylchloridobis(tri-p-tolylphosphine)rhodium(I) acetone solvate Acta Crystallographica Section E |
| title | trans-Carbonylchloridobis(tri-p-tolylphosphine)rhodium(I) acetone solvate |
| title_full | trans-Carbonylchloridobis(tri-p-tolylphosphine)rhodium(I) acetone solvate |
| title_fullStr | trans-Carbonylchloridobis(tri-p-tolylphosphine)rhodium(I) acetone solvate |
| title_full_unstemmed | trans-Carbonylchloridobis(tri-p-tolylphosphine)rhodium(I) acetone solvate |
| title_short | trans-Carbonylchloridobis(tri-p-tolylphosphine)rhodium(I) acetone solvate |
| title_sort | trans carbonylchloridobis tri p tolylphosphine rhodium i acetone solvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808003528 |
| work_keys_str_mv | AT brianrjames transcarbonylchloridobistriptolylphosphinerhodiumiacetonesolvate AT brianopatrick transcarbonylchloridobistriptolylphosphinerhodiumiacetonesolvate AT fabiolorenzini transcarbonylchloridobistriptolylphosphinerhodiumiacetonesolvate |