Stannate-Based Materials as Anodes in Lithium-Ion and Sodium-Ion Batteries: A Review
Binary metal oxide stannate (M<sub>2</sub>SnO<sub>4</sub>; M = Zn, Mn, Co, etc.) structures, with their high theoretical capacity, superior lithium storage mechanism and suitable operating voltage, as well as their dual suitability for lithium-ion batteries (LIBs) and sodium-...
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| Format: | Article |
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MDPI AG
2023-06-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/28/13/5037 |
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| author | You-Kang Duan Zhi-Wei Li Shi-Chun Zhang Tong Su Zhi-Hong Zhang Ai-Jun Jiao Zhen-Hai Fu |
| author_facet | You-Kang Duan Zhi-Wei Li Shi-Chun Zhang Tong Su Zhi-Hong Zhang Ai-Jun Jiao Zhen-Hai Fu |
| author_sort | You-Kang Duan |
| collection | DOAJ |
| description | Binary metal oxide stannate (M<sub>2</sub>SnO<sub>4</sub>; M = Zn, Mn, Co, etc.) structures, with their high theoretical capacity, superior lithium storage mechanism and suitable operating voltage, as well as their dual suitability for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs), are strong candidates for next-generation anode materials. However, the capacity deterioration caused by the severe volume expansion problem during the insertion/extraction of lithium or sodium ions during cycling of M<sub>2</sub>SnO<sub>4</sub>-based anode materials is difficult to avoid, which greatly affects their practical applications. Strategies often employed by researchers to address this problem include nanosizing the material size, designing suitable structures, doping with carbon materials and heteroatoms, metal–organic framework (MOF) derivation and constructing heterostructures. In this paper, the advantages and issues of M<sub>2</sub>SnO<sub>4</sub>-based materials are analyzed, and the strategies to solve the issues are discussed in order to promote the theoretical work and practical application of M<sub>2</sub>SnO<sub>4</sub>-based anode materials. |
| first_indexed | 2024-03-11T01:34:07Z |
| format | Article |
| id | doaj.art-5b4cd0e64c06444fafccb675d14973b0 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-11T01:34:07Z |
| publishDate | 2023-06-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-5b4cd0e64c06444fafccb675d14973b02023-11-18T17:07:14ZengMDPI AGMolecules1420-30492023-06-012813503710.3390/molecules28135037Stannate-Based Materials as Anodes in Lithium-Ion and Sodium-Ion Batteries: A ReviewYou-Kang Duan0Zhi-Wei Li1Shi-Chun Zhang2Tong Su3Zhi-Hong Zhang4Ai-Jun Jiao5Zhen-Hai Fu6Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, ChinaKey Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, ChinaKey Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, ChinaKey Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, ChinaKey Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, ChinaKey Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, ChinaKey Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, ChinaBinary metal oxide stannate (M<sub>2</sub>SnO<sub>4</sub>; M = Zn, Mn, Co, etc.) structures, with their high theoretical capacity, superior lithium storage mechanism and suitable operating voltage, as well as their dual suitability for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs), are strong candidates for next-generation anode materials. However, the capacity deterioration caused by the severe volume expansion problem during the insertion/extraction of lithium or sodium ions during cycling of M<sub>2</sub>SnO<sub>4</sub>-based anode materials is difficult to avoid, which greatly affects their practical applications. Strategies often employed by researchers to address this problem include nanosizing the material size, designing suitable structures, doping with carbon materials and heteroatoms, metal–organic framework (MOF) derivation and constructing heterostructures. In this paper, the advantages and issues of M<sub>2</sub>SnO<sub>4</sub>-based materials are analyzed, and the strategies to solve the issues are discussed in order to promote the theoretical work and practical application of M<sub>2</sub>SnO<sub>4</sub>-based anode materials.https://www.mdpi.com/1420-3049/28/13/5037stannate-based anodescomposition and structure designenergy storage mechanismelectrochemical performances |
| spellingShingle | You-Kang Duan Zhi-Wei Li Shi-Chun Zhang Tong Su Zhi-Hong Zhang Ai-Jun Jiao Zhen-Hai Fu Stannate-Based Materials as Anodes in Lithium-Ion and Sodium-Ion Batteries: A Review Molecules stannate-based anodes composition and structure design energy storage mechanism electrochemical performances |
| title | Stannate-Based Materials as Anodes in Lithium-Ion and Sodium-Ion Batteries: A Review |
| title_full | Stannate-Based Materials as Anodes in Lithium-Ion and Sodium-Ion Batteries: A Review |
| title_fullStr | Stannate-Based Materials as Anodes in Lithium-Ion and Sodium-Ion Batteries: A Review |
| title_full_unstemmed | Stannate-Based Materials as Anodes in Lithium-Ion and Sodium-Ion Batteries: A Review |
| title_short | Stannate-Based Materials as Anodes in Lithium-Ion and Sodium-Ion Batteries: A Review |
| title_sort | stannate based materials as anodes in lithium ion and sodium ion batteries a review |
| topic | stannate-based anodes composition and structure design energy storage mechanism electrochemical performances |
| url | https://www.mdpi.com/1420-3049/28/13/5037 |
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