SYNTHESIS, CRYSTAL STRUCTURE, AND PROPERTIES OF COPPER(II) COMPLEXES WITH 1,4,7-TRIS(2-AMINOETHYL)-1,4,7-TRIAZACYCLONONANE
Three kinds of copper(II) complexes with 1,4,7-tris(2-aminoethyl)-1,4,7-triazacyclononane (taetacn), [Cu(taetacn)](ClO4)2 (1), [Cu(Htaetacn)](ClO4)3 (2), and [Cu(Htaetacn)](BF4)3 (3) were synthesized and characterized by elemental analyses, IR and UV-Vis spectroscopies. The spectral features are in...
| Main Authors: | , , , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Academy of Sciences of Moldova, Institute of Chemistry
2015-12-01
|
| Series: | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
| Subjects: | |
| Online Access: | http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold201510(2)_40-47_Mikuriya.pdf |
| _version_ | 1818765120478642176 |
|---|---|
| author | Masahiro Mikuriya Mayu Hamagawa Natsuki Tomioka Daisuke Yoshioka Naoko Uehara Rika Fujimori Hiroki Yamamoto Yoshinari Ando Shoichi Hori Taro Kuriyama Ryoji Mitsuhashi Makoto Handa |
| author_facet | Masahiro Mikuriya Mayu Hamagawa Natsuki Tomioka Daisuke Yoshioka Naoko Uehara Rika Fujimori Hiroki Yamamoto Yoshinari Ando Shoichi Hori Taro Kuriyama Ryoji Mitsuhashi Makoto Handa |
| author_sort | Masahiro Mikuriya |
| collection | DOAJ |
| description | Three kinds of copper(II) complexes with 1,4,7-tris(2-aminoethyl)-1,4,7-triazacyclononane (taetacn), [Cu(taetacn)](ClO4)2 (1), [Cu(Htaetacn)](ClO4)3 (2), and [Cu(Htaetacn)](BF4)3 (3) were synthesized and characterized by elemental analyses, IR and UV-Vis spectroscopies. The spectral features are in harmony with an octahedral geometry for 1 and a square-pyramidal coordination for 2 and 3. |
| first_indexed | 2024-12-18T08:13:02Z |
| format | Article |
| id | doaj.art-5b5c13866f194ad3ae9d4be8307ca995 |
| institution | Directory Open Access Journal |
| issn | 1857-1727 2345-1688 |
| language | English |
| last_indexed | 2024-12-18T08:13:02Z |
| publishDate | 2015-12-01 |
| publisher | Academy of Sciences of Moldova, Institute of Chemistry |
| record_format | Article |
| series | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
| spelling | doaj.art-5b5c13866f194ad3ae9d4be8307ca9952022-12-21T21:14:52ZengAcademy of Sciences of Moldova, Institute of ChemistryChemistry Journal of Moldova: General, Industrial and Ecological Chemistry1857-17272345-16882015-12-011024047SYNTHESIS, CRYSTAL STRUCTURE, AND PROPERTIES OF COPPER(II) COMPLEXES WITH 1,4,7-TRIS(2-AMINOETHYL)-1,4,7-TRIAZACYCLONONANEMasahiro Mikuriya0Mayu Hamagawa1Natsuki Tomioka2Daisuke Yoshioka3Naoko Uehara4Rika Fujimori5Hiroki Yamamoto6Yoshinari Ando7Shoichi Hori8Taro Kuriyama9Ryoji Mitsuhashi10Makoto Handa11Department of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, JapanDepartment of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, JapanDepartment of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, JapanDepartment of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, JapanDepartment of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, JapanDepartment of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, JapanDepartment of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, JapanDepartment of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, JapanDepartment of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, JapanDepartment of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, JapanDepartment of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, JapanDepartment of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, JapanThree kinds of copper(II) complexes with 1,4,7-tris(2-aminoethyl)-1,4,7-triazacyclononane (taetacn), [Cu(taetacn)](ClO4)2 (1), [Cu(Htaetacn)](ClO4)3 (2), and [Cu(Htaetacn)](BF4)3 (3) were synthesized and characterized by elemental analyses, IR and UV-Vis spectroscopies. The spectral features are in harmony with an octahedral geometry for 1 and a square-pyramidal coordination for 2 and 3.http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold201510(2)_40-47_Mikuriya.pdfcopper(II) complexmagnetic propertiesmacrocyclic ligand |
| spellingShingle | Masahiro Mikuriya Mayu Hamagawa Natsuki Tomioka Daisuke Yoshioka Naoko Uehara Rika Fujimori Hiroki Yamamoto Yoshinari Ando Shoichi Hori Taro Kuriyama Ryoji Mitsuhashi Makoto Handa SYNTHESIS, CRYSTAL STRUCTURE, AND PROPERTIES OF COPPER(II) COMPLEXES WITH 1,4,7-TRIS(2-AMINOETHYL)-1,4,7-TRIAZACYCLONONANE Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry copper(II) complex magnetic properties macrocyclic ligand |
| title | SYNTHESIS, CRYSTAL STRUCTURE, AND PROPERTIES OF COPPER(II) COMPLEXES WITH 1,4,7-TRIS(2-AMINOETHYL)-1,4,7-TRIAZACYCLONONANE |
| title_full | SYNTHESIS, CRYSTAL STRUCTURE, AND PROPERTIES OF COPPER(II) COMPLEXES WITH 1,4,7-TRIS(2-AMINOETHYL)-1,4,7-TRIAZACYCLONONANE |
| title_fullStr | SYNTHESIS, CRYSTAL STRUCTURE, AND PROPERTIES OF COPPER(II) COMPLEXES WITH 1,4,7-TRIS(2-AMINOETHYL)-1,4,7-TRIAZACYCLONONANE |
| title_full_unstemmed | SYNTHESIS, CRYSTAL STRUCTURE, AND PROPERTIES OF COPPER(II) COMPLEXES WITH 1,4,7-TRIS(2-AMINOETHYL)-1,4,7-TRIAZACYCLONONANE |
| title_short | SYNTHESIS, CRYSTAL STRUCTURE, AND PROPERTIES OF COPPER(II) COMPLEXES WITH 1,4,7-TRIS(2-AMINOETHYL)-1,4,7-TRIAZACYCLONONANE |
| title_sort | synthesis crystal structure and properties of copper ii complexes with 1 4 7 tris 2 aminoethyl 1 4 7 triazacyclononane |
| topic | copper(II) complex magnetic properties macrocyclic ligand |
| url | http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold201510(2)_40-47_Mikuriya.pdf |
| work_keys_str_mv | AT masahiromikuriya synthesiscrystalstructureandpropertiesofcopperiicomplexeswith147tris2aminoethyl147triazacyclononane AT mayuhamagawa synthesiscrystalstructureandpropertiesofcopperiicomplexeswith147tris2aminoethyl147triazacyclononane AT natsukitomioka synthesiscrystalstructureandpropertiesofcopperiicomplexeswith147tris2aminoethyl147triazacyclononane AT daisukeyoshioka synthesiscrystalstructureandpropertiesofcopperiicomplexeswith147tris2aminoethyl147triazacyclononane AT naokouehara synthesiscrystalstructureandpropertiesofcopperiicomplexeswith147tris2aminoethyl147triazacyclononane AT rikafujimori synthesiscrystalstructureandpropertiesofcopperiicomplexeswith147tris2aminoethyl147triazacyclononane AT hirokiyamamoto synthesiscrystalstructureandpropertiesofcopperiicomplexeswith147tris2aminoethyl147triazacyclononane AT yoshinariando synthesiscrystalstructureandpropertiesofcopperiicomplexeswith147tris2aminoethyl147triazacyclononane AT shoichihori synthesiscrystalstructureandpropertiesofcopperiicomplexeswith147tris2aminoethyl147triazacyclononane AT tarokuriyama synthesiscrystalstructureandpropertiesofcopperiicomplexeswith147tris2aminoethyl147triazacyclononane AT ryojimitsuhashi synthesiscrystalstructureandpropertiesofcopperiicomplexeswith147tris2aminoethyl147triazacyclononane AT makotohanda synthesiscrystalstructureandpropertiesofcopperiicomplexeswith147tris2aminoethyl147triazacyclononane |