The Study of Chemiluminescence of Acridinium Ester in Presence of Rhodamin B as a Fluorescer

The reaction of hydrogen peroxide and  pheny -9-acridinecarboxylate in the presence of rhodamin B as a fluorophore leads to the emission of either bright blue light  or bright red light, depending on the structure of fluorescer and reaction conditions. The light emitter responsible for the Chemi Lum...

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Main Authors: Mohammad Javad Chaichi, Zahra Va'ezi, Morteza Hosseini, Saman Hosseinkhani, Mojtaba Shamsipur
Format: Article
Language:English
Published: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 2011-03-01
Series:Iranian Journal of Chemistry & Chemical Engineering
Subjects:
Online Access:http://www.ijcce.ac.ir/article_6361_51b14cb71d8e366024a397107d29198c.pdf
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author Mohammad Javad Chaichi
Zahra Va'ezi
Morteza Hosseini
Saman Hosseinkhani
Mojtaba Shamsipur
author_facet Mohammad Javad Chaichi
Zahra Va'ezi
Morteza Hosseini
Saman Hosseinkhani
Mojtaba Shamsipur
author_sort Mohammad Javad Chaichi
collection DOAJ
description The reaction of hydrogen peroxide and  pheny -9-acridinecarboxylate in the presence of rhodamin B as a fluorophore leads to the emission of either bright blue light  or bright red light, depending on the structure of fluorescer and reaction conditions. The light emitter responsible for the Chemi Luminescence (CL) reaction is acridone and that the blue light produced with out the fluorescers is  a result of direct CL. The intensity and kinetic parameters for the CL systems were evaluated from fitting of the resulting intensity-time plots. The CL systems were investigated as concentration dependent of fluorescer, hydrogen peroxide, acridinium ester and sodium hydroxide as a catalyst.
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spelling doaj.art-5b5f0f7caafa4bb8bae28f93288724a92022-12-22T00:55:59ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering1021-99861021-99862011-03-0130189966361The Study of Chemiluminescence of Acridinium Ester in Presence of Rhodamin B as a FluorescerMohammad Javad Chaichi0Zahra Va'ezi1Morteza Hosseini2Saman Hosseinkhani3Mojtaba Shamsipur4Department of Chemistry, Mazandaran University, Babolsar, I.R. IRANDepartment of Chemistry, Mazandaran University, Babolsar, I.R. IRANDepartment of Chemistry, Islamic Azad University, Savadkooh Branch, Savadkooh, I.R. IRANDepartment of Biochemistry, Tarbiat Modaress University, Tehran, I.R. IRANDepartment of Chemistry, Razi University, Kermanshah, I.R. IRANThe reaction of hydrogen peroxide and  pheny -9-acridinecarboxylate in the presence of rhodamin B as a fluorophore leads to the emission of either bright blue light  or bright red light, depending on the structure of fluorescer and reaction conditions. The light emitter responsible for the Chemi Luminescence (CL) reaction is acridone and that the blue light produced with out the fluorescers is  a result of direct CL. The intensity and kinetic parameters for the CL systems were evaluated from fitting of the resulting intensity-time plots. The CL systems were investigated as concentration dependent of fluorescer, hydrogen peroxide, acridinium ester and sodium hydroxide as a catalyst.http://www.ijcce.ac.ir/article_6361_51b14cb71d8e366024a397107d29198c.pdfchemiluminescenceacridinium esterrhodamin blucigeninhydrogen peroxide
spellingShingle Mohammad Javad Chaichi
Zahra Va'ezi
Morteza Hosseini
Saman Hosseinkhani
Mojtaba Shamsipur
The Study of Chemiluminescence of Acridinium Ester in Presence of Rhodamin B as a Fluorescer
Iranian Journal of Chemistry & Chemical Engineering
chemiluminescence
acridinium ester
rhodamin b
lucigenin
hydrogen peroxide
title The Study of Chemiluminescence of Acridinium Ester in Presence of Rhodamin B as a Fluorescer
title_full The Study of Chemiluminescence of Acridinium Ester in Presence of Rhodamin B as a Fluorescer
title_fullStr The Study of Chemiluminescence of Acridinium Ester in Presence of Rhodamin B as a Fluorescer
title_full_unstemmed The Study of Chemiluminescence of Acridinium Ester in Presence of Rhodamin B as a Fluorescer
title_short The Study of Chemiluminescence of Acridinium Ester in Presence of Rhodamin B as a Fluorescer
title_sort study of chemiluminescence of acridinium ester in presence of rhodamin b as a fluorescer
topic chemiluminescence
acridinium ester
rhodamin b
lucigenin
hydrogen peroxide
url http://www.ijcce.ac.ir/article_6361_51b14cb71d8e366024a397107d29198c.pdf
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