Nonlinear optical behaviour of bis (cytosinium) tartarate monohydrate single crystal
A nonlinear optical single crystal of bis (cytosinium) tartarate monohydrate (BCTM) was grown by slow evaporation method at room temperature. Single crystal X-ray diffraction study revealed their cell parameters and corresponding space group. Different functional groups were identified by using FTIR...
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| Format: | Article |
| Language: | English |
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Elsevier
2022-12-01
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| Series: | Chemical Physics Impact |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2667022422000524 |
| _version_ | 1811325836924551168 |
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| author | P. Jaikumar T. Balakrishnan C. Indumathi T.C. Sabari Girisun K. Ramamurthi |
| author_facet | P. Jaikumar T. Balakrishnan C. Indumathi T.C. Sabari Girisun K. Ramamurthi |
| author_sort | P. Jaikumar |
| collection | DOAJ |
| description | A nonlinear optical single crystal of bis (cytosinium) tartarate monohydrate (BCTM) was grown by slow evaporation method at room temperature. Single crystal X-ray diffraction study revealed their cell parameters and corresponding space group. Different functional groups were identified by using FTIR spectral analysis. Phase purity of the grown crystal was analysed by chemical etching and powder X-ray diffraction studies. The mechanical strength of the grown crystal was estimated using Vickers microhardness test. The thermal stability of the grown crystal was investigated by TGA-DTA studies. The optical absorption study was carried out in the wavelength range of 190–1100 nm. The dielectric response of the grown crystal was studied as a function of frequency at different temperatures. Second harmonic generation efficiency (SHG) was measured by Kurtz and Perry powder technique. The Z-scan pattern clearly evidenced that the BCTM exhibits sequential two photon absorption induced reverse saturable absorption. |
| first_indexed | 2024-04-13T14:39:34Z |
| format | Article |
| id | doaj.art-5b7a107b0d81440d92c8d3de5cc2b436 |
| institution | Directory Open Access Journal |
| issn | 2667-0224 |
| language | English |
| last_indexed | 2024-04-13T14:39:34Z |
| publishDate | 2022-12-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Chemical Physics Impact |
| spelling | doaj.art-5b7a107b0d81440d92c8d3de5cc2b4362022-12-22T02:42:56ZengElsevierChemical Physics Impact2667-02242022-12-015100114Nonlinear optical behaviour of bis (cytosinium) tartarate monohydrate single crystalP. Jaikumar0T. Balakrishnan1C. Indumathi2T.C. Sabari Girisun3K. Ramamurthi4PG & Research Department of Physics, National College (Autonomous), Affiliated to Bharathidasan University, Tiruchirappalli 620001, Tamil Nadu, India; Corresponding authors.Crystal Growth Laboratory, Department of Physics, Thanthai Periyar Government Arts and Science College (Autonomous), Affiliated to Bharathidasan University, Tiruchirappalli 620023, Tamil Nadu, India; Corresponding authors.PG and Research Department of Physics, Bishop Heber College (Autonomous), Affiliated to Bharathidasan University, Tiruchirappalli 620017, Tamil Nadu, IndiaNanophotonics Laboratory, Department of Physics, Bharathidasan University, Tiruchirappalli 620024, Tamil Nadu, IndiaSchool of Physics, Bharathidasan University, Tiruchirappalli 620024, Tamil Nadu, IndiaA nonlinear optical single crystal of bis (cytosinium) tartarate monohydrate (BCTM) was grown by slow evaporation method at room temperature. Single crystal X-ray diffraction study revealed their cell parameters and corresponding space group. Different functional groups were identified by using FTIR spectral analysis. Phase purity of the grown crystal was analysed by chemical etching and powder X-ray diffraction studies. The mechanical strength of the grown crystal was estimated using Vickers microhardness test. The thermal stability of the grown crystal was investigated by TGA-DTA studies. The optical absorption study was carried out in the wavelength range of 190–1100 nm. The dielectric response of the grown crystal was studied as a function of frequency at different temperatures. Second harmonic generation efficiency (SHG) was measured by Kurtz and Perry powder technique. The Z-scan pattern clearly evidenced that the BCTM exhibits sequential two photon absorption induced reverse saturable absorption.http://www.sciencedirect.com/science/article/pii/S2667022422000524Single crystal XRDThermal analysisSecond harmonic generationOptical limitingZ-Scan |
| spellingShingle | P. Jaikumar T. Balakrishnan C. Indumathi T.C. Sabari Girisun K. Ramamurthi Nonlinear optical behaviour of bis (cytosinium) tartarate monohydrate single crystal Chemical Physics Impact Single crystal XRD Thermal analysis Second harmonic generation Optical limiting Z-Scan |
| title | Nonlinear optical behaviour of bis (cytosinium) tartarate monohydrate single crystal |
| title_full | Nonlinear optical behaviour of bis (cytosinium) tartarate monohydrate single crystal |
| title_fullStr | Nonlinear optical behaviour of bis (cytosinium) tartarate monohydrate single crystal |
| title_full_unstemmed | Nonlinear optical behaviour of bis (cytosinium) tartarate monohydrate single crystal |
| title_short | Nonlinear optical behaviour of bis (cytosinium) tartarate monohydrate single crystal |
| title_sort | nonlinear optical behaviour of bis cytosinium tartarate monohydrate single crystal |
| topic | Single crystal XRD Thermal analysis Second harmonic generation Optical limiting Z-Scan |
| url | http://www.sciencedirect.com/science/article/pii/S2667022422000524 |
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