Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR)
Conductive carbon black (CCB), carbon nanotubes (CNT) and its hybrids are introduced into the natural rubber (NR) matrix aiming to explore the effect of filler ratio on the transport properties. Solvent transport of NR is found to decrease for hybrid filler systems as compared to single filler incor...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
Budapest University of Technology
2023-10-01
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Series: | eXPRESS Polymer Letters |
Subjects: | |
Online Access: | http://www.expresspolymlett.com/letolt.php?file=EPL-0012569&mi=cd |
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author | Vakkoottil Sivadasan Abhisha Krishanagegham Sidharathan Sisanth Sabu Thomas Ranimol Stephen |
author_facet | Vakkoottil Sivadasan Abhisha Krishanagegham Sidharathan Sisanth Sabu Thomas Ranimol Stephen |
author_sort | Vakkoottil Sivadasan Abhisha |
collection | DOAJ |
description | Conductive carbon black (CCB), carbon nanotubes (CNT) and its hybrids are introduced into the natural rubber (NR) matrix aiming to explore the effect of filler ratio on the transport properties. Solvent transport of NR is found to decrease for hybrid filler systems as compared to single filler incorporated systems. Kinetic parameters of solvent transport behavior of filled NR systems are analyzed using various kinetic models. Upon the computation of kinetic parameters of transport data, it is found that the Peppas-Sahlin model is in good agreement with experimental observations, which suggests that the transport mechanism is diffusion controlled. Rubber–filler interaction parameters are computed and analyzed from the swelling experiments using Kraus, Cunneen-Russel, and Lorenz-Park equations |
first_indexed | 2024-03-12T17:02:53Z |
format | Article |
id | doaj.art-5bcbab7085424130884b2ffcc1d7e83f |
institution | Directory Open Access Journal |
issn | 1788-618X |
language | English |
last_indexed | 2024-03-12T17:02:53Z |
publishDate | 2023-10-01 |
publisher | Budapest University of Technology |
record_format | Article |
series | eXPRESS Polymer Letters |
spelling | doaj.art-5bcbab7085424130884b2ffcc1d7e83f2023-08-07T08:45:43ZengBudapest University of TechnologyeXPRESS Polymer Letters1788-618X2023-10-0117101070108010.3144/expresspolymlett.2023.80Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR)Vakkoottil Sivadasan AbhishaKrishanagegham Sidharathan SisanthSabu ThomasRanimol StephenConductive carbon black (CCB), carbon nanotubes (CNT) and its hybrids are introduced into the natural rubber (NR) matrix aiming to explore the effect of filler ratio on the transport properties. Solvent transport of NR is found to decrease for hybrid filler systems as compared to single filler incorporated systems. Kinetic parameters of solvent transport behavior of filled NR systems are analyzed using various kinetic models. Upon the computation of kinetic parameters of transport data, it is found that the Peppas-Sahlin model is in good agreement with experimental observations, which suggests that the transport mechanism is diffusion controlled. Rubber–filler interaction parameters are computed and analyzed from the swelling experiments using Kraus, Cunneen-Russel, and Lorenz-Park equationshttp://www.expresspolymlett.com/letolt.php?file=EPL-0012569&mi=cdrubberpolymer compositesnanomaterials crosslinking curing elastomer filler natural rubber vulcanizationcarbon black |
spellingShingle | Vakkoottil Sivadasan Abhisha Krishanagegham Sidharathan Sisanth Sabu Thomas Ranimol Stephen Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR) eXPRESS Polymer Letters rubber polymer composites nanomaterials crosslinking curing elastomer filler natural rubber vulcanization carbon black |
title | Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR) |
title_full | Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR) |
title_fullStr | Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR) |
title_full_unstemmed | Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR) |
title_short | Kinetic studies on the transport behavior of hybrid filler incorporated natural rubber (NR) |
title_sort | kinetic studies on the transport behavior of hybrid filler incorporated natural rubber nr |
topic | rubber polymer composites nanomaterials crosslinking curing elastomer filler natural rubber vulcanization carbon black |
url | http://www.expresspolymlett.com/letolt.php?file=EPL-0012569&mi=cd |
work_keys_str_mv | AT vakkoottilsivadasanabhisha kineticstudiesonthetransportbehaviorofhybridfillerincorporatednaturalrubbernr AT krishanageghamsidharathansisanth kineticstudiesonthetransportbehaviorofhybridfillerincorporatednaturalrubbernr AT sabuthomas kineticstudiesonthetransportbehaviorofhybridfillerincorporatednaturalrubbernr AT ranimolstephen kineticstudiesonthetransportbehaviorofhybridfillerincorporatednaturalrubbernr |